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4680-78-8

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Basic Information
CAS No.: 4680-78-8
Name: ACID GREEN 3
Molecular Structure:
Molecular Structure of 4680-78-8 (ACID GREEN 3)
Formula: C37H36 N2 O6 S2 . Na
Molecular Weight: 691.86
Synonyms: Benzenemethanaminium,N-ethyl-N-[4-[[4-[ethyl[(3-sulfophenyl)methyl]amino]phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo-,hydroxide, inner salt, sodium salt; Benzenemethanaminium,N-ethyl-N-[4-[[4-[ethyl[(3-sulfophenyl)methyl]amino]phenyl]phenylmethylene]-2,5-cyclohexadien-1-ylidene]-3-sulfo-,inner salt, sodium salt (9CI); C.I. Acid Green 3 (6CI,7CI); C.I. Acid Green 3,sodium salt (8CI);4-[4-(N-Ethyl-p-sulfobenzylamino)diphenylmethylene]-[1-(N-ethyl-N-p-sulfoniumbenzyl)-D2,5-cyclohexadienimine]monosodium salt; A.F. Green No. 1; Acid Green; Acid Green 2G; Acid Green B;Acid Green G; Acid Green G (Polish); Acid Green S; Acid Leather Green 3G; AcidLeather Green F; Acid green 3; Acidal Green G; Acilan Green B; Amacid Green B; BrilliantGreen 3EMBL; Bucacid Guinea Green BA; C.I. 42085; C.I. Food Green 1; CalcocidGreen G; FD and C Green No. 1; Fenazo Green L; Guinea Green B; Guinea Green BA;Guinea green; Hidacid Emerald Green; Hispacid Green GB; Japan Green 1; JapanGreen 402; Japan Green No. 1; Japan Green No. 402; Kiton Green F; Kiton GreenFC; Leather Green B; Merantine Green G; NSC 5016; NSC 8684; Naphthalene GreenG; Naphthalene Lake Green G; Naphthalene Leather Green G; Neran Brilliant GreenG; Pontacyl Green B; Pontacyl Green BL; Sulpho Green 2B; Triacid Green G;Vondacid Green L
Melting Point: 255oC (dec.)(lit.)
Solubility: Soluble in water
Safety: Questionable carcinogen with experimental tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of SOx, Na2O, and NOx.
PSA: 137.41000
LogP: 8.28440
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Chemistry

Chemical Name: Acid GREEN 3
IUPAC NAME: Sodium 3-[[N-ethyl-4-[[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]-phenylmethyl]anilino]methyl]benzenesulfonate
CAS No.: 4680-78-8
EINECS: 225-132-8
RTECS: BQ4375000
Molecular Formula: C37H35N2NaO6S2
Molecular Weight: 690.8 g/mol
Melting Point: 255 °C (dec.)(lit.)
Following is the structure of FD&C GREEN No. 1 (CAS No.:4680-78-8):


The chemical synonymous of FD&C GREEN No. 1 (CAS No.:4680-78-8) are CALCOCID GREEN G ; GUINEA GREEN B ; CI 42085 ; ACID GREEN G ; ACID GREEN B ; ACID GREEN 2G ; ACID GREEN 3 ; ACID GREEN L

Toxicity Data With Reference

1.    

mma-sat 320 µg/plate

     MUREAV    Mutation Research. 89 (1981),21.
2.    

ihl-rat TCLo:100 mg/m3/13W-I:NEO,REP

     GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 7 (2)(1963),54.
3.    

orl-rat LD:>3 g/kg

     GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 7 (2)(1963),54.

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 16 (1978),p. 199.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. Community Right-To-Know List.

Safety Profile

Questionable carcinogen with experimental tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of SOx, Na2O, and NOx.