Detail of "4867-37-2"

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CAS Number:
4867-37-2
Name:
3-Chlorothioanisole
Molecular Structure:
Formula:
C₇H₇ClS
Molecular Weight:
158.64
Synonyms:
Sulfide,m-chlorophenyl methyl (6CI,7CI,8CI);3-(Methylthio)-1-chlorobenzene;3-Chlorophenyl methyl sulfide;Methyl 3-chlorophenylsulfide;Methyl m-chlorophenyl sulfide;NSC 133796;m-Chlorophenyl methylsulfide;m-Chlorothioanisole;
Density:
1.2 g/cm³
Boiling Point:
217.9 °C at 760 mmHg
Flash Point:
87.6 °C
Hazard Symbols:
Xi
Risk Codes:
22-36/37/38
Safety:
23-36/37-36-26 Details

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3-Chloro thioanisole

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Excited state electron transfer reactions of tris(2,2'-bipyridine)chromium(III) ion with organic sulfides: Excited state electron transfer reactions of tris(2,2'-bipyridine)chromium(III) ion with organic sulfides. Gnanaraj, G. Allen; Rajagopal, S.; Srinivasan, C. (Sch. Chem., Madurai Kamaraj Univ., Madurai 625 021, India). Proc. - Indian Acad. Sci., Chem. Sci., 104(1), 9-13 (English) 1992. CODEN: PIAADM. 623-13-2 and 4867-37-2 are also in the experiment. ISSN: 0253-4134. DOCUMENT TYPE: Journal CA Section: 67 (Catalysis, Reaction Kinetics, and Inorganic Reaction Mechanisms) Section cross-reference(s): 74 The quenching rate consts., kq, for the excited state electron transfer reactions of tris(2,2'-bipyridine)chromium(III) ion with several aryl Me sulfides (ArSMe) obtained by the luminescence quenching technique, are accelerated by electron releasing groups and retarded by electron withdrawing groups present in the aryl moiety of ArSMe. The plot of RT 1nkq vs. E1/2 values of different sulfides is linear, indicating the electron transfer nature of the reaction. Studies with alkyl Ph sulfides demonstrate the importance of the steric effect in these photoredox reactions. .