Detail of "5009-27-8"

Reference

Direct formation of a tricyclic cycloheptanone-containing system by enolate condensation with a cyclopropanone derivative

Direct formation of a tricyclic cycloheptanone-containing system by enolate condensation with a cyclopropanone derivative. Carey, James T.; Knors, Christopher; Helquist, Paul (Dep. Chem., Univ. Notre Dame, Notre Dame, IN 46556, USA). J. Am. Chem.Several reagents such as 29926-33-8 is used here. Soc., 108(26), 8313-14 (English) 1986. CODEN: JACSAT. ISSN: 0002-7863. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) Section cross-reference(s): 75 Cyclopropanone hemiacetal I was treated with MeMgBr and then with Li cyclohexenolate II to give 14% cyclopropane adduct III and 67% tricyclic cycloheptanone IV. The structure of IV was detd. by 600 MHz 1H NMR spectroscopy and single-crystal x-ray diffraction. The pathway to IV was detd. by a no. of control reactions. .

Cyclopropanone hemiacetals

Cyclopropanone hemiacetals. Salaun, Jacques (Lab. Carbocycles, Univ. Paris-Sud, Orsay 91405, Fr.). Chem. Rev., 83(6), 619-32 (English) 1983. CODEN: CHREAY. ISSN: 0009-2665. DOCUMENT TYPE: Journal; General Review CA Section: 24 (Alicyclic Compounds) A review with >150 refs. 5009-27-8 is just another one chemical used in this study. .