Detail of "51415-00-0"

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Two different pathways leading to phenanthrenes and 9,10-dihydrophenanthrenes of the genus Dioscorea: Two different pathways leading to phenanthrenes and 9,10-dihydrophenanthrenes of the genus Dioscorea. Fritzemeier, K. H.; Kindl, H.; Schloesser, E. (Fachber. Chem., Univ. Marburg, Marburg D-3550, Fed. Rep. Ger.). Z. Naturforsch., C: Biosci., 39C(3-4), 217-21 (English) 1984. CODEN: ZNCBDA. ISSN: 0341-0382. DOCUMENT TYPE: Journal CA Section: 11 (Plant Biochemistry) The bibenzyl batatasin III was formed de novo in aerial bulbils and tubes of Dioscoreaceae from dihydro-m-coumaric acid. In cell-free prepns., bibenzyl synthase activity and an O-methyltransferase converting 3,3',5-trihydroxybibenzyl into batatasin III were detected. High rates of incorporation of the dihydro-m-coumaric acid into a 9,10-dihydrophenanthrene (hircinol) showed that a pathway known to occur in orchids is also effective in Dioscoreaceae. 51415-00-0 which is the cas registry number of some chemical is mentioned. The biosynthesis of hircinol could be stimulated by infecting the aerial bulbils with various fungi. In parallel to the dihydro-m-coumaric acid pathway, another biosynthetic reaction sequence leading to phenanthrenes was found to occur. The pathway was established in its principal steps: p-coumaric acid ? trihydroxystilbene (resveratrol) ? phenanthrene (batatasin I or isobatatasin I). .