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| CAS No.: | 52888-80-9 |
|---|---|
| Name: | PROSULFOCARB |
| Article Data: | 5 |
| Molecular Structure: | |
|
|
|
| Formula: | C14H21 N O S |
| Molecular Weight: | 251.393 |
| Synonyms: | Carbamicacid, dipropylthio-, S-benzyl ester (7CI); Carbamothioic acid, dipropyl-,S-(phenylmethyl) ester (9CI); Arkade; Benzyl dipropylthiolcarbamate; Boxer;Boxer (ICI Agrochemicals); Defi; Prosulfocarb; R 15574; S-BenzylN,N-dipropylthiocarbamate; S-Benzyl dipropylthiocarbamate; S-Benzyldipropylthiolcarbamate; SC 0574 |
| Density: | 1.049g/cm3 |
| Melting Point: | <10℃ |
| Boiling Point: | 352.6°Cat760mmHg |
| Flash Point: | 167.1°C |
| Hazard Symbols: |
 Xn, N
|
| Risk Codes: | R22; R43; R51/53 |
| Safety: | Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx and SOx. |
| PSA: | 45.61000 |
| LogP: | 4.16180 |
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Chemistry
IUPAC Name: S-Benzyl N,N-dipropylcarbamothioate
Synonyms: Prosulfocarb ; S-benzyl dipropylthiocarbamate ; Boxer ; Defi ; Arkade ; Benzyldipropylthiolcarbamate ; Boxer(iciagrochemicals) ; Dipropyl-carbamothioicacis-(phenylmethyl)ester
CAS NO: 52888-80-9
Molecular Formula: C14H21NOS
Molecular Weight: 251.39
Molecular Structure: 
EINECS: 401-730-6
Mol File: 52888-80-9.mol
Index of Refraction: 1.541
Surface Tension: 40.3 dyne/cm
Density: 1.049 g/cm3
Flash Point: 167.1 °C
Enthalpy of Vaporization: 59.75 kJ/mol
Boiling Point: 352.6 °C at 760 mmHg
Vapour Pressure: 3.79E-05 mmHg at 25°C
Solubility: water solubility 13.2mg / L at 20 °C, S-(Phenylmethyl) dipropylcarbamothioate (CAS NO. 52888-80-9) is soluble in organic solvents.
Uses
S-(Phenylmethyl) dipropylcarbamothioate (CAS NO. 52888-80-9) is used for wheat weeding.
Production
Reaction of Dipropylamine and Carbon oxysulfide at affection of alkaline , and then reacts with Benzyl chloride,at last obtaining S-(Phenylmethyl) dipropylcarbamothioate (CAS NO. 52888-80-9).
Toxicity Data With Reference
| 1. | orl-rat LD50:1820 mg/kg | PEMNDP Pesticide Manual. 9 (1991),729. | ||
| 2. | ihl-rat LC50:>4700 mg/m3/4H | PEMNDP Pesticide Manual. 9 (1991),729. | ||
| 3. | skn-rbt LD50:>2 g/kg | PEMNDP Pesticide Manual. 9 (1991),729. |
Safety Profile
Moderately toxic by ingestion. When heated to decomposition it emits toxic vapors of NOx and SOx.Hazard Codes Xn,N
Risk Statements 22-43-51/53
R22:Harmful if swallowed.
R43:May cause sensitization by skin contact.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 24-37-61
S24:Avoid contact with skin.
S37:Wear suitable gloves.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 3082 9/PG 3
RTECS FD3835000
Specification
Air & Water Reactions :Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.
Reactivity Profile: S-(Phenylmethyl) dipropylcarbamothioate (CAS NO. 52888-80-9) is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.