Detail of "5325-97-3"

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Recoverable, Reusable, Highly Active, and Sulfur-Tolerant Polymer Incarcerated Palladium for Hydrogenation: Recoverable, Reusable, Highly Active, and Sulfur-Tolerant Polymer Incarcerated Palladium for Hydrogenation. Okamoto, Kuniaki; Akiyama, Ryo; Kobayashi, Shu (Graduate School of Pharmaceutical Sciences, University of Tokyo, Tokyo 113-0033, Japan). Journal of Organic Chemistry, 69(8), 2871-2873 (English) 2004 American Chemical Society. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 21 (General Organic Chemistry) A new type of immobilized palladium, PI (polymer incarcerated) Pd, prepd. from Pd(PPh3)4 and the copolymer has been developed. The excellent activity of PI Pd has been demonstrated in hydrogenation of various olefins, benzyl ethers, and nitro and arom. compds. PI Pd is tolerant under high pressure and high temp. There are some commonly used reagents like 5325-97-3 in this article. and can be recovered and reused several times without loss of activity even under harsh conditions. Moreover, PI Pd is highly resistant to poisoning by sulfur. .