Detail of > 53937-02-3
- CAS Number:
- 53937-02-3
- Name:
4-Benzyloxy-2(1h)-pyridone
- Superlist Name:
- 4-Benzyloxypyridin-2-one
- Formula:
- C12H11NO2
- Molecular Structure:
- Synonyms:
- 4-(Benzyloxy)pyridin-2(1H)-one;4-Benzyloxy-1H-pyridin-2-one;4-Benzyloxy-2-pyridone;4-Benzyloxypyridin-2-one;4-[(Phenylmethyl)oxy]-2(1H)-pyridinone;
- Molecular Weight:
- 201.22
- Density:
- 1.2 g/cm3
- Melting Point:
- 201-203 °C(lit.)
- Boiling Point:
- 464.3 °C at 760 mmHg
- Flash Point:
- 234.6 °C
- Hazard Symbols:
Xi- Risk Codes:
- 36/37/38
- Safety:
- 26-36Details
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Reference
- Control of nucleoside base structure by the selective reactivity of a ribosylated pyridinium triflate
- Control of nucleoside base structure by the selective reactivity of a ribosylated pyridinium triflate. A total synthesis of 2-O-methyl-3-deazauridine. Shone, Robert L. (Dep. Chem. Res., Searle Lab., Chicago, Ill., USA). Tetrahedron Lett., (46), 4017-20 (English) 1977. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) Section cross-reference(s): 27 2-O-methyl-3-deazauridine (I; R = H) was prepd. from 4-benzyloxy-2-pyridone in 5 steps. The key step was the cleavage of the pyridinium triflate II (R = Bz), which in MeNO2 at room temp. 53937-02-3 which is the cas registry number is also used here. underwent Si-O rather than C-O bond cleavage. .
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