Detail of "543-24-8"

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CAS Number:
543-24-8
Name:
Glycine,N-acetyl-
Superlist Name:
N-Acetylglycine
Molecular Structure:
Formula:
C₄H₇NO₃
Molecular Weight:
117.10
Synonyms:
Aceturicacid (6CI);2-(Acetylamino)acetic acid;2-Acetamidoacetic acid;Acetamidoacetic acid;Acetylaminoaceticacid;Acetylglycine;Acetylglycocoll;Ethanoylaminoethanoic acid;NSC 7605;Ac-Gly-OH;
EINECS:
208-839-6
Density:
1.231 g/cm³
Melting Point:
207-209 °C(lit.)
Boiling Point:
405.1 °C at 760 mmHg
Flash Point:
198.8 °C
Solubility:
2.7 g/100 mL (15 °C) in water
Appearance:
white to light yellow crystal powder
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety:
22-24/25-36-26 Details
particular:
particular

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Reference

Surfactant: Surfactant. Horikawa, Kazuo; Masuyama, Shinroku; Yasuhara, Toki; Imamura, Tamao (Taiyo Kagaku Kogyo Co., Ltd.; Osaka City, Japan). Japan. JP 51024488 B4 24 Jul 1976 Showa, 5 pp. (Japanese). (Japan). CODEN: JAXXAD. CLASS: IC: C07C103-48. APPLICATION: JP 69-102698 20 Dec 1969. DOCUMENT TYPE: Patent CA Section: 46 (Surface Active Agents and Detergents) Section cross-reference(s): 23 A fatty acid monoester of glycerol was esterfied with an acetylated amino acid to prep. hydrophilic, pleasant-smelling surfactants useful in foods, cosmetics, etc. Thus, glycine [56-40-6] was treated with Ac2O [108-24-7] in water to prep. 26657-96-5 and 56-40-6 which are cas registry numbers of chemicals are mentioned. N-acetylglycine [543-24-8] which was added to molten glycerol monopalmitate [26657-96-5] contg. AcONa to prep. a waxy surfactant with acid value 21, OH value 158, and N content 3.3%. .

Nitrosamide carcinogenesis: nitrosation of amide linkages and facile decomposition of resulting nitrosamides: Nitrosamide carcinogenesis: nitrosation of amide linkages and facile decomposition of resulting nitrosamides. Chow, Y. L.; Dhaliwal, S. S.; Polo, J. (Dep. Chem., Simon Fraser Univ., Burnaby, BC V5A1S6, Can.). IARC Sci. Publ., 57(N-Nitroso Compd: Occurrence, Biol. Eff. Relevance Hum. Cancer), 317-25 (English) 1984. CODEN: IARCCD. ISSN: 0300-5038. DOCUMENT TYPE: Journal CA Section: 4 (Toxicology) Nitrite ions interact readily with N-methylacetamide [79-16-3] and N-acetylglycine [543-24-8] in aq. buffer soln. of pH <4 to give the transient nitrosamides, N-nitroso-N-methylacetamide [7417-67-6] and N-nitroso-N-acetylglycine [97795-13-6]. These nitrosamides could not be isolated under these conditions because they decomp. rapidly, as demonstrated by UV spectroscopic traces. The gas chromatog. identification of the products indicates that diazo esters and diazoalkanes are the intermediates in these decompns. The kinetic anal. of the nitrosation in buffered soln. shows that the rate consts. are proportional to the H ion concn. in the pH <4 range. Evidence in support of the participation of a carboxylate group in the nitrosation of N-acetylglycine is discussed. Possible implications of the presence of nitrite in carcinogenesis in digestive tracts are discussed on the basis of facile formation and decompn. of nitrosamides and the intermediacy of diazo compds.

Detail of "543-24-8"

Glycine,N-acetyl-

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Reference