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544-17-2

Basic Information
CAS No.: 544-17-2
Name: Calcium formate
Article Data: 69
Molecular Structure:
Molecular Structure of 544-17-2 (Calcium formate)
Formula: C2H2CaO4
Molecular Weight: 130.113
Synonyms: Feed Grad Calcium Formate;Calcium Formate, technical grade;calcium diformate;
EINECS: 208-863-7
Density: 2.02 g/cm3
Melting Point: 300 °C
Boiling Point: 100.6 °C at 760 mmHg
Flash Point: 29.9 °C
Solubility: Soluble in water
Appearance: white to almost white fine crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-37/39
PSA: 52.60000
LogP: 0.51920
Synthetic route
201230-82-2

carbon monoxide

calcium oxide

544-17-2

calcium diformate

Conditions
ConditionsYield
In water heating suspension of 240 g pure CaCO3 in 1 l H2O with CO for few hours in Fe shaker autoclave at 20-45 at and 160°C, until there is no redn. of pressure; after cooling, diln. with hot H2O, filtration; pptn. of Ca(OH)2 with CO2; filtration;; vaporization of filtrate; pptn.;;92%
In water heating suspension of 240 g pure CaCO3 in 1 l H2O with CO for few hours in Fe shaker autoclave at 20-45 at and 160°C, until there is no redn. of pressure; after cooling, diln. with hot H2O, filtration; pptn. of Ca(OH)2 with CO2; filtration;; vaporization of filtrate; pptn.;;92%
544-17-2

calcium diformate

201230-82-2

carbon monoxide

544-17-2

calcium diformate

Conditions
ConditionsYield
With calcium hydroxide at 180℃; under 36775.4 Torr; Product distribution; temperatures from 100 to 200 deg C, pressure from 30 to 60 kg/cm2, effect of Ca(OH)2 concentration, optimal conditions for maximum yield achievement;
With methylamine; calcium hydroxide at 165 - 170℃; Temperature; Reagent/catalyst;
64-18-6

formic acid

calcium carbonate

544-17-2

calcium diformate

Conditions
ConditionsYield
In water
In not given
In formic acid addn. of excessive, fresh pptd. CaCO3 to diluted formic acid; first at ambient temp., then heating; filtration;; vaporization of filtrate; solving of residue on water bath with water; storage on a warm place; crystn. of H2O free calcium formate;;
124-38-9

carbon dioxide

544-17-2

calcium diformate

Conditions
ConditionsYield
With water; hydrogen; palladium; calcium carbonate
With borax; water; hydrogen; palladium
With borax; water; hydrogen; palladium
With water; hydrogen; palladium; calcium carbonate
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    Product name: Calcium Formate CAS No.:544-17-2 Molecule Formula:C2H2CaO4 Molecule Weight:130.11 Purity: 98% Package: 25kg/drum Description:White or light yellow crystalline powder Manufacture Standards:Enterprise Standard TESTING

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    Calcium formate

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    Calcium formate Chemical Properties Melting point 300 °C density 2,02 g/cm3 solubility H2O: 1 M at 20 °C, clear, colorless form orthorhombic crystals Specific Gravity 2.02 PH 6.0-8.0 (25℃, 1M in H2O) Water Solubility

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Chemistry

Molecule structure of Calcium formate (CAS NO.544-17-2):

IUPAC Name: Calcium diformate 
Molecular Weight: 130.11288 g/mol
Molecular Formula: C2H2CaO4 
Density: 2.02 g/cm3
Melting Point: 300 °C
Flash Point: 29.9 °C
Enthalpy of Vaporization: 22.69 kJ/mol
Boiling Point: 100.6 °C at 760 mmHg
Vapour Pressure: 36.5 mmHg at 25 °C 
Water Solubility: 1 M at 20 °C, clear, colorless 
H-Bond Acceptor: 4
Exact Mass: 129.9579
MonoIsotopic Mass: 129.9579
Topological Polar Surface Area: 80.3
Heavy Atom Count: 7
Canonical SMILES: C(=O)[O-].C(=O)[O-].[Ca+2]
InChI: InChI=1S/2CH2O2.Ca/c2*2-1-3;/h2*1H,(H,2,3);/q;;+2/p-2
InChIKey: CBOCVOKPQGJKKJ-UHFFFAOYSA-L
EINECS: 208-863-7
Product Categories: INORGANIC & ORGANIC CHEMICALS

Uses

 Calcium formate (CAS NO.544-17-2) can be used as acidity agent instead of lemon acid and fumaric acid, and as anticorrodant and mildew preventive to substitute Calcium propionate. It is applicable to the feed stuffs for all kinds of animals, preventing diarrhea and helping digestion, especially to kid pigs. Also, Calcium formate is a good kind of growth regulator of crops.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 154mg/kg (154mg/kg)   Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969.
 
mouse LD50 oral 1920mg/kg (1920mg/kg)   Zeitschrift fuer Ernaehrungswissenschaft. Vol. 9, Pg. 332, 1969.
 
rat LD50 oral 2650mg/kg (2650mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 9, 1972.

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-37/39 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S37/39:Wear suitable gloves and eye/face protection.
WGK Germany: 1
RTECS: LQ5600000
TSCA: Yes

Specification

 Calcium formate (CAS NO.544-17-2) is also named as Calcium diformate ; Calcium formate (Ca(HCO2)2) ; Calcoform ; Formic acid, calcium salt ; HSDB 5019 ; Mravencan vapenaty ; Mravencan vapenaty [Czech] ; Formic acid, calcium salt ; Formic acid, calcium salt (2:1) . Calcium formate (CAS NO.544-17-2) is white to almost white fine crystalline powder.