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Detail of "54659-85-7"

  • CAS Number:
  • 54659-85-7
  • Name:
  • Phenol,4-methyl-2-(1-oxido-2H-benzotriazol-2-yl)-

  • Molecular Structure:
  • Formula:
  • C13H11 N3 O2
  • Synonyms:
  • Phenol,2-(2H-benzotriazol-2-yl)-4-methyl-, N-oxide; p-Cresol,2-(2H-benzotriazol-2-yl)-, N-oxide (7CI); 2-(2-Hydroxy-5-methylphenyl)benzotriazoleN-oxide; 2-(2'-Hydroxy-5'-methylphenyl)benzotriazole-N-oxide

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CAS No.54659-85-7 2(2’-Hydroxy-5’-methylphenyl)benzotriazole,N-Oxide

Chemical Name: 2(2’-Hydroxy-5’-methylphenyl)benzotriazole,N-Oxide CAS: [54659-85-7] Specification: Appearance: yellow M.P. (℃): 138-140 Assay (%): 98min. Loss on drying (%): 1max. Ash (%): 0.2max. Packaging: 25-50Kgs net in PP-PW bag. Use: Intermediates

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Reference

Reduction of 2-(2'-hydroxy-5'-methylphenyl)-o-benzotriazole N-oxide on Raney nickel in the liquid phase
Reduction of 2-(2'-hydroxy-5'-methylphenyl)-o-benzotriazole N-oxide on Raney nickel in the liquid phase. Lefedova, O. V.; Gostikin, V. P.; Smirnov, R. P. (Ivanov. Khim.-Tekhnol. Inst., Ivanovo, USSR). Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 54659-85-7 is also in the experiment., 27(1), 39-43 (Russian) 1984. CODEN: IVUKAR. ISSN: 0579-2991. DOCUMENT TYPE: Journal CA Section: 28 (Heterocyclic Compounds (More Than One Hetero Atom)) Section cross-reference(s): 41 Redn. of the title compd. (I) in aq. Me2CHOH or aq. alkali gave intermediates formed in parallel reactions, one of which gave O-C6H4(NH2)2 and 4,2-Me(H2N)C6H3OH as final products, while the other gave the parent benzotriazole. .
Hydroxyarylbenzotriazoles and their N-oxides
Hydroxyarylbenzotriazoles and their N-oxides. Jancis, Elmar H. (Uniroyal, Inc., USA).In this study, 88778-23-8 and 54659-85-7 are also used. Can. CA 1155856 A1 25 Oct 1983, 23 pp. (English). (Canada). CODEN: CAXXA4. CLASS: IC: C07D249-20; C08K005-34. APPLICATION: CA 75-238884 3 Nov 1975. DOCUMENT TYPE: Patent CA Section: 37 (Plastics Manufacture and Processing) Section cross-reference(s): 28 Benzotriazole derivs., useful as light stabilizers for polyolefins, are prepd. by hydrogenation of nitrophenylazo derivs. in alk. medium. Thus, 12.7 g 2-(2'-nitrophenylazo)-p-cresol [1435-71-8], 22 mL 6N NaOH, 100 mL water, and 0.3 g 5% Pd on charcoal were hydrogenated 1 h at room temp. at 50 psig. a 92.5% yield of 2-(2'-hydroxy-5'-methylphenyl)benzotriazole-1-oxide [54659-85-7] was obtained. .
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