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5470-66-6

Basic Information
CAS No.: 5470-66-6
Name: 4-Nitro-2-picoline N-oxide
Article Data: 35
Molecular Structure:
Molecular Structure of 5470-66-6 (4-Nitro-2-picoline N-oxide)
Formula: C6H6N2O3
Molecular Weight: 154.125
Synonyms: 2-Picoline,4-nitro-, 1-oxide (6CI,7CI,8CI);2-Methyl-4-nitropyridine N-oxide;4-Nitro-2-methylpyridine 1-oxide;4-Nitro-2-methylpyridine N-oxide;2-Methyl-4-nitropyridine 1-oxide;4-Nitro-a-picoline N-oxide;NSC 27962;
EINECS: -0
Density: 1.363 g/cm3
Melting Point: 155-159 °C(lit.)
Boiling Point: 404.01 °C at 760 mmHg
Flash Point: 198.138 °C
Appearance: Yellow solid
Hazard Symbols: HarmfulXn, IrritantXi
Risk Codes: 20/21/22-36/37/38-40
Safety: 22-26-36
Transport Information: UN 2811
PSA: 71.28000
LogP: 1.85490
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Chemistry

Molecular Formula: C6H6N2O3
Molecular Weight: 154.123440 g/mol 
Density: 1.36 g/cm
Flash Point: 198.1 °C
Storage temp: 2-8°C
Melting Point: 155-159 °C(lit.)
Chemical Properties: yellow to light orange Solid
Product Name: 4-Nitro-2-picoline N-oxide
IUPAC Name
: 2-methyl-4-nitro-1-oxidopyridin-1-ium     
Enthalpy of Vaporization: 62.99 kJ/mol 
Boiling Point: 404 °C at 760 mmHg 
Vapour Pressure: 2.28E-06 mmHg at 25°C 
Synonyms of 2-Methyl-4-Nitropyridin-1-oxide (CAS NO.470-66-6): 2-methyl-4-nitro-pyridin1-oxide ; 2-Picoline, 4-nitro-, 1-oxide ; 4-Nitro-2-methylpyridine 1-oxide ; 4-Nitro-a-picoline N-oxide ; Pyridine, 2-methyl-4-nitro-, 1-oxide ; 4-Nitro-2-methylpyridine-N-oxide ; 4-Nitro-2-picoline N-oxide ; 4-Nitropyridin-2-picoline-N-oxide                
Following is the molecular structure of 2-Methyl-4-Nitropyridin-1-oxide (CAS NO.470-66-6):

Toxicity Data With Reference

1.    

mmo-sat 1 µmol/plate

    GANNA2    Gann. Japanese Journal of Cancer Research. 70 (1979),799.
2.    

mmo-esc 500 µmol/L

    GANNA2    Gann. Japanese Journal of Cancer Research. 70 (1979),799.
3.    

dnd-mus:fbr 50 µmol/L

    CNREA8    Cancer Research. 35 (1975),521.

Safety Profile

Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Safety Information of 2-Methyl-4-Nitropyridin-1-oxide (CAS NO.5470-66-6):
Hazard Codes: Xn,Xi 
Xn  Harmful ;Xi  Irritant
Risk Statements: 20/21/22-36/37/38-40 
20/21/22: Harmful by inhalation, in contact with skin and if swallowed 
36/37/38: Irritating to eyes, respiratory system and skin 
40: Limited evidence of a carcinogenic effect 
Safety Statements: 22-26-36 
22: Do not breathe dust 
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36: Wear suitable protective clothing 
RIDADR: 2811
WGK Germany: 3 
RTECS: UT5710000
HazardClass: 6.1
PackingGroup: III