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| CAS No.: | 556-56-9 |
|---|---|
| Name: | ALLYL IODIDE |
| Article Data: | 66 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H5I |
| Molecular Weight: | 167.977 |
| Synonyms: | Propene,3-iodo- (6CI,7CI,8CI);2-Propenyl iodide;3-Iodo-1-propene;3-Iodopropene;3-Iodopropylene;Allyl iodide;NSC 18588; |
| EINECS: | 209-130-4 |
| Density: | 1.826 g/cm3 |
| Melting Point: | -99 °C |
| Boiling Point: | 103 °C at 760 mmHg |
| Flash Point: | 25.5 °C |
| Solubility: | Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water. |
| Appearance: | clear orange, red or red-brown liquid |
| Hazard Symbols: |
 C
|
| Risk Codes: | 10-34 |
| Safety: | 7-26-45 |
| PSA: | 0.00000 |
| LogP: | 1.60740 |
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| Conditions | Yield |
|---|---|
| With diphosphorus tetraiodide at 85℃; under 0.01 Torr; for 0.0833333h; Product distribution; various alcohols; other conditions of the reaction; | 86% |
| With diphosphorus tetraiodide at 85℃; under 0.01 Torr; for 0.0833333h; | 86% |
| With Silphos; iodide In acetonitrile for 0.166667h; Heating; | 78% |
| Conditions | Yield |
|---|---|
| With iodine In chloroform at 25℃; for 4h; | A 80% B 85% |
| Conditions | Yield |
|---|---|
| at 25℃; for 8h; | A n/a B 78% |
- 106-95-6
allyl bromide
A
- 556-56-9
allyl iodid
B
- 818-92-8
3-fluoropropene
C
- 140899-21-4
allyl trifluoromethyl ether
| Conditions | Yield |
|---|---|
| With tertamethylammonium iodide In N,N-dimethyl-formamide at 60℃; for 72h; | A n/a B n/a C 72% |
| Conditions | Yield |
|---|---|
| With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; sodium iodide In acetone Reflux; | 70% |
- 76065-43-5
allyldiphenyltelluronium bromide
A
- 556-56-9
allyl iodid
B
- 29135-65-7
dibromo-diphenyl-λ4-tellane
| Conditions | Yield |
|---|---|
| With iodine(I) bromide at 0℃; for 4h; | A n/a B 65% |
| Conditions | Yield |
|---|---|
| With iodine(I) bromide at 0℃; for 4h; | A n/a B 65% |
- 2700-81-4
rubidium trifluoromethoxylate
- 106-95-6
allyl bromide
A
- 556-56-9
allyl iodid
B
- 818-92-8
3-fluoropropene
C
- 140899-21-4
allyl trifluoromethyl ether
| Conditions | Yield |
|---|---|
| rubidium iodide In N,N-dimethyl-formamide at 60℃; for 61h; | A n/a B n/a C 61% |
- 19206-69-0
allyl diphenyl phosphate
- 556-56-9
allyl iodid
| Conditions | Yield |
|---|---|
| With sodium iodide In N,N-dimethyl-formamide for 3h; Ambient temperature; | 47% |
- 16770-74-4
2-propenyl nitrate
- 556-56-9
allyl iodid
| Conditions | Yield |
|---|---|
| With acetone; sodium iodide |
- Total:24 Page 1 of 1 1
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Chemistry
Product Name: Allyl iodide (CAS NO.556-56-9)
Molecular Formula: C3H5I
Molecular Weight: 167.98g/mol
Mol File: 556-56-9.mol
Einecs: 209-130-4
Appearance: Clear orange, red or red-brown liquid
Melting Point: -99 °C
Boiling point: 103 °C at 760 mmHg
Storage Temperature: 2-8°C
Flash Point: 25.5 °C
Density: 1.837 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.554
Surface Tension: 29.5 dyne/cm
Enthalpy of Vaporization: 32.79 kJ/mol
Vapour Pressure: 38 mmHg at 25°C
XLogP3-AA: 2.1
H-Bond Donor: 0
H-Bond Acceptor: 0
Product Categories: Omega-Functional Alkanols, Carboxylic Acids, Amines and Halides; Omega-Unsaturated Halides
Toxicity Data With Reference
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
| 1. | mmo-sat 1 µmol/plate | BCPCA6 Biochemical Pharmacology. 29 (1980),993. | ||
| 2. | dns-hmn:hlas 50 µmol/L | CALEDQ Cancer Letters (Shannon, Ireland). 20 (1983),263. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Information of Allyl iodide (CAS NO.556-56-9):
Hazard Codes: C.gif){kind=small}
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Risk Statements: 10-34
10: Flammable
34: Causes burns
Safety Statements: 7-26-45
7: Keep container tightly closed
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
Standards and Recommendations
DOT Classification: 3; Label: Flammable Liquid, Corrosive
Specification
Allyl iodide ,its CAS NO. is 556-56-9,the synonyms is 1-Propene,3-iodo- ; 2-Propene, 1-iodo ; 2-Propenyliodide ; 3-Iodo-1-propen ; 3-Iodo-prop-1-ene ; 3-iodo-propen ; 3-Iodpropen ; 3-Jod-1-propen .