CAS No.563-47-3,3-Chloro-2-methylpropene Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	563-47-3
Name:	3-Chloro-2-methylpropene
Article Data:	60

Formula:	C₄H₇Cl
Molecular Weight:	90.5526
Synonyms:	Propene,3-chloro-2-methyl- (6CI,8CI);1-Chloro-2-methyl-2-propene;2-(Chloromethyl)-1-propene;2-Methallyl chloride;2-Methyl-2-propenyl chloride;2-Methyl-3-chloro-1-propene;2-Methyl-3-chloropropene;2-Methylallyl chloride;3-Chloro-2-methyl-1-propene;1-Propene,3-chloro-2-methyl-;Isobutenyl chloride;Methallyl chloride;Methylallyl chloride;NSC 7303;b-Methallyl chloride;g-Chloroisobutylene;
EINECS:	209-251-2
Density:	0.897 g/cm³
Melting Point:	-80 °C
Boiling Point:	72.5 °C at 760 mmHg
Flash Point:	9 °F
Solubility:	0.5 g/L (20 °C) in water
Appearance:	clear liquid
Hazard Symbols:	F, C, N
Risk Codes:	11-20/22-34-43-51/53
Safety:	9-16-29-36/37/39-45-61-26
Transport Information:	UN 2554 3/PG 2
PSA:	0.00000
LogP:	1.80130

Synthetic route

: 513-42-8
3-hydroxy-2-methyl-1-propene

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine In sulfolane from 10 deg C to room temp.;	95.7%
With pyridine; bis(trichloromethyl) carbonate In tetrahydrofuran Ambient temperature;	65%
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine In sulfolane from 10 deg C to room temp., effect of reagents ratio and solvent volume discussed;

: 32670-93-2
2-methallyl diphenylphosphate

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
With lithium chloride In N,N-dimethyl-formamide for 0.166667h; Ambient temperature;	64%

: Pd(CH2CHCH2)(C6H3Cl2)(As(C6H5)3)

: 107-05-1
3-chloroprop-1-ene

A: 90220-53-4
CH2CHCH2C6H3Cl2

B: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
In dichloromethane O°C, AsPh3 was added, 24 h.;	A 55% B 20%
In dichloromethane O°C, AsPh3 was added, 1.33 h.;	A 22% B 2%
In dichloromethane O°C, AsPh3 was added, 0.67 h.;	A 10% B 0%
In dichloromethane O°C, AsPh3 was added, 0.33 h.;	A 6% B 0%

...Expand

: 78538-54-2
boric acid trimethallyl ester

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
With boron trichloride at 120℃;

: 628-56-8
isopropenylmethyl ether

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
With hydrogenchloride; copper(l) chloride at 30 - 50℃; under 89731.9 Torr;

: 36942-09-3
N,N-dichlorourea

: 64-19-7
acetic acid

: 115-11-7
isobutene

A: 57576-87-1
acetic acid-(chloro-tert-butyl ester)

B: 563-47-3
3-Chloro-2-methylpropene

...Expand

: 36942-09-3
N,N-dichlorourea

: 115-11-7
isobutene

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
With acetic acid
With trichloroacetic acid
With chloroacetic acid

: 473-29-0
N,N-Dichlorobenzenesulfonamide

: 60-29-7
diethyl ether

: 115-11-7
isobutene

: 107-07-3
2-chloro-ethanol

A: 55982-53-1
1-chloro-2-(2-chloroethoxy)-2-methylpropane

B: 563-47-3
3-Chloro-2-methylpropene

...Expand

: 115-11-7
isobutene

: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
Chlorierung;
With chlorine at 0 - 70℃;
With chlorine at 0℃;

: 115-11-7
isobutene

A: 513-37-1
2-methylprop-1-enyl chloride

B: 594-37-6
1,2-dichloro-2-methylpropane

C: 507-20-0
tertiary butyl chloride

D: 563-47-3
3-Chloro-2-methylpropene

Conditions

Conditions	Yield
at 80℃; Chlorierung;
With chlorine In tetrachloromethane at 20℃;	A n/a B 6 % Chromat. C n/a D 77 % Chromat.

...Expand

Raw Materials

13898-47-0

78538-54-2

513-42-8

594-37-6

507-40-4

628-56-8

115-11-7

60-29-7

Downstream Products

515-40-2

886-66-8

19549-94-1

144-19-4

Total:80 Page 1 of 3 1 2 3 Next>>

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Chemistry

The molecular structure of 3-Chloro-2-methylpropene (CAS NO.563-47-3):

IUPAC Name: 3-Chloro-2-methylprop-1-ene
Molecular Weight: 90.55138 g/mol
Molecular Formula: C₄H₇Cl
Density: 0.897 g/cm³
Melting Point: -80 °C
Boiling Point: 72.5 °C at 760 mmHg
Flash Point: 9 °F
Index of Refraction: 1.41
Molar Refractivity: 24.99 cm³
Molar Volume: 100.8 cm³
Surface Tension: 20.6 dyne/cm
Enthalpy of Vaporization: 30.08 kJ/mol
Vapour Pressure: 130 mmHg at 25 °C
Storage Temp.: refrigerator (+4 °C) + flammables area
Water Solubility: 0.5 g/L (20 °C)
XLogP3-AA: 2.1
Rotatable Bond Count: 1
Exact Mass: 90.023628
MonoIsotopic Mass: 90.023628
Canonical SMILES: CC(=C)CCl
InChI: InChI=1S/C4H7Cl/c1-4(2)3-5/h1,3H2,2H3
InChIKey: OHXAOPZTJOUYKM-UHFFFAOYSA-N
EINECS: 209-251-2
Product Categories: Industrial/Fine Chemicals

Uses

3-Chloro-2-methylpropene (CAS NO.563-47-3) is used to make plastics and pharmaceuticals. It is important organic intermediates. It also can be widely used in medicine, pesticides, perfume, synthetic materials.

Toxicity Data With Reference

1.	mmo-sat 6 µmol/plate	BCPCA6 Biochemical Pharmacology. 29 (1980),2611.
2.	dns-hmn:hla 1 mmol/L	CALEDQ Cancer Letters (Shannon, Ireland). 20 (1983),263.
3.	orl-rat TDLo:77,250 mg/kg/2Y-I:CAR	NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.
4.	orl-mus TDLo:51,500 mg/kg/2Y-I:CAR	NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.
5.	orl-rat TD:77,250 mg/kg/2Y-I:NEO,REP	NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986.

Consensus Reports

NTP 10th Report on Carcinogens. NTP Carcinogenesis Studies (gavage); Clear Evidence: mouse, rat NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-300 ,1986. . Reported in EPA TSCA Inventory.

Safety Profile

Hazard Codes: F, Corrosive C, Dangerous N
Risk Statements: 11-20/22-34-43-51/53
R11:Highly flammable.
R20/22:Harmful by inhalation and if swallowed.
R34:Causes burns.
R43:May cause sensitization by skin contact.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 9-16-29-36/37/39-45-61-26
S9:Keep container in a well-ventilated place.
S16:Keep away from sources of ignition.
S29:Do not empty into drains.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 2554 3/PG 2
WGK Germany: 2
RTECS: UC8050000
HazardClass: 3
PackingGroup: II
HS Code: 29032900
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO₂, dry chemical. When heated to decomposition it emits toxic fumes of Cl⁻. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

Standards and Recommendations

DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
DOT Classification: 3; Label: Flammable Liquid

Specification

3-Chloro-2-methylpropene (CAS NO.563-47-3) is also named as 1-Chloro-2-methyl-2-propene ; 2-Methallyl chloride ; 2-Methyl-2-propenyl chloride ; 2-Methyl-allylchlorid ; 2-Methyl-allylchlorid [German] ; 3-Chlor-2-methyl-prop-1-en ; 3-Chlor-2-methyl-prop-1-en [German] ; 3-Chloro-2-methyl-1-propene ; 3-Chloroisobutylene ; 3-Cloro-2-metil-prop-1-ene ; 3-Cloro-2-metil-prop-1-ene [Italian] ; 4-01-00-00803 (Beilstein Handbook Reference) ; AI3-14901 ; BRN 0878160 ; CCRIS 869 ; Chlorue de methallyle ; Chlorue de methallyle [French] ; Chlorure de methallyle ; Chlorure de methallyle [French] ; Cloruro di metallile ; Cloruro di metallile [Italian] ; HSDB 1149 ; Isobutenyl chloride ; MAC ; Methallyl chloride ; NCI-C54820 ; NSC 7303 ; Propene, 3-chloro-2-methyl- ; beta-Methylallyl chloride ; gamma-Chloroisobutylene . 3-Chloro-2-methylpropene (CAS NO.563-47-3) is clear liquid with a sharp penetrating odor. It is insoluble in water. It may be toxic by ingestion. Irritating to skin and eyes. It is highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. It is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. It is incompatible with strong bases.Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.