CAS No.563-63-3,Silver acetate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	563-63-3
Name:	Silver acetate
Article Data:	42

Formula:	C₂H₃AgO₂
Molecular Weight:	166.913
Synonyms:	Aceticacid, silver(1+) salt (8CI,9CI);Silver acetate (6CI,7CI);Silver acetate(AgOAc);Silver monoacetate;Silver(1+) acetate;Silver(I) acetate;
EINECS:	209-254-9
Density:	3.25 g/cm³
Melting Point:	decomposes [STR93]
Boiling Point:	117.1°C at 760 mmHg
Flash Point:	40°C
Solubility:	10.2 g/L (20 °C) in water
Appearance:	Off-white/brown crystalline powder
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-36/37/39
Transport Information:	UN 1759
PSA:	26.30000
LogP:	0.01380

Synthetic route

: 64-19-7
acetic acid

: 20667-12-3
silver(l) oxide

: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
at 50℃; for 0.0833333h;	99%
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;
In acetic acid crystn. on evapn. of the soln.;;
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;;

: 127-09-3
sodium acetate

: silver nitrate

: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
With acetic acid In water at 23℃;	91%
With acetic acid In water addn. of satd. aq. soln. of sodium acetate to satd. aq. soln. of AgNO3 contg. few drops of acetic acid in the dark; filtration, washing the residue with water, methanol, hexane, drying in vac.;	90%
In water soln. of AgNO3 in water was added to soln. of NaCH3CO2 in water; filtered in air, washed with water, EtOH, Et2O, dried in vacuo; elem. anal.;	64%

: 1308661-15-5
Pd[(μ-O2CMe)2Ag(HO2CMe)2]2

: 5144-89-8
1,10-phenanthroline hydrate

: 35679-81-3
(1,10-phenanthroline)-palladium(II) acetate

B: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.;	A 75% B n/a

...Expand

: 1308661-15-5
Pd[(μ-O2CMe)2Ag(HO2CMe)2]2

: 75-65-0
tert-butyl alcohol

A: palladium(II) pivalate

B: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (3:1 molar ratio), mixt. stirred at room temp. for 1.5 h; ppt. filtered off, concd., crystd., dried, elem. anal.;	A 70% B n/a

...Expand

: 53897-55-5
2,4,6-trimethyl-[1,3,5]dioxathiane

moist silver oxide: moist silver oxide

A: 563-63-3
silver(I) acetate

B silver formate: silver formate

C silver sulfide: silver sulfide

Conditions

Conditions	Yield
bei der Oxydation;

...Expand

: 849585-22-4
LACTIC ACID

: 7732-18-5
water

Ag2O: Ag2O

A: 124-38-9
carbon dioxide

B: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
at 100℃;

...Expand

: 141-53-7
sodium formate

: 108-24-7
acetic anhydride

: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
In acetic anhydride boiling, pptn.;; recrystn. from glacial acetic acid;;

: diammine silver(I) acetate

: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
With aldehyde In water
With aldehyde In water

: diammine silver(I) acetate

A: 7664-41-7
ammonia

B: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
In water in the air;
In water in the air;

: silver perchlorate

: 563-63-3
silver(I) acetate

Conditions

Conditions	Yield
With trimethylamine acetate triacetatesolvate In not given addition of AgClO4 to a solution of the triacetatesolvate of trimethylamine acetate;;

Raw Materials

71-50-1

141-53-7

64-19-7

108-24-7

Downstream Products

853-23-6

75-27-4

105-60-2

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

ACGIH TLV: TWA 0.01 mg(Ag)/m³

Specification

The Silver(I) acetate, with the CAS registry number 563-63-3, is also known as Acetic acid, silver(1+) salt. It belongs to the product category of Organic-metal Salt. Its EINECS registry number is 209-254-9. This chemical's molecular formula is C₂H₃AgO₂ and molecular weight is 166.91222. Its IUPAC name is called silver acetate.

Physical properties of Silver(I) acetate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 165.918397; (5)MonoIsotopic Mass: 165.918397; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 25.5; (10)Covalently-Bonded Unit Count: 2.

Preparation: this chemical can be prepared by AgO and CH₃COOH.

Uses of Silver(I) acetate: It can be used as a pesticide. It also produces a repulsive taste when combined with cigarette smoke, so it is used in chewing gum and lozenges to aid the cessation of smoking.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(=O)[O-].[Ag+]
(2)InChI: InChI=1S/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
(3)InChIKey: CQLFBEKRDQMJLZ-UHFFFAOYSA-M

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	34mg/kg (34mg/kg)	BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Drug and Chemical Toxicology. Vol. 6, Pg. 267, 1983.