CAS No.56401-20-8,ALPHA-D-GLUCOSE-1-PHOSPHATE NA2-SALT Suppliers

Products Categories

Pharmaceutical (38)
Organic Chemicals (10)
Reagent (8)
Others (7)

Basic Information

Molecular Structure:
CAS No.:	56401-20-8
Name:	ALPHA-D-GLUCOSE-1-PHOSPHATE NA2-SALT
Article Data:	2

Formula:	C6H13 O9 P . 2 Na
Molecular Weight:	304.101
Synonyms:	a-D-Glucopyranosyl phosphatedisodium salt; a-D-Glucose-1-phosphatedisodium salt
Density:	1.9g/cm³
Melting Point:	138°C
Boiling Point:	603°Cat760mmHg
Flash Point:	318.5°C
Solubility:	Soluble in water.
PSA:	181.61000
LogP:	-2.29230

Synthetic route

: 83-87-4, 604-68-2, 604-69-3, 2152-77-4, 4026-35-1, 4163-59-1, 4163-60-4, 4163-61-5, 4163-65-9, 4257-94-7, 4257-96-9, 16299-15-3, 19186-39-1, 19189-55-0, 25878-60-8, 25941-03-1, 32445-48-0, 32445-49-1, 32445-53-7, 32445-54-8, 34685-58-0, 34685-59-1, 43168-42-9, 43168-44-1, 43169-22-8, 43169-25-1, 66966-07-2, 70749-17-6, 80184-01-6, 93221-01-3, 93221-02-4, 99630-88-3, 109215-53-4, 115792-70-6, 115792-73-9, 139894-92-1, 139973-25-4, 144071-49-8, 147648-81-5
D-glucose pentaacetate

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

Conditions

Conditions	Yield
Stage #1: D-glucose pentaacetate With phosphoric acid In melt at 50℃; under 1.20012 Torr; for 3h; Inert atmosphere; Schlenk technique; Sealed tube; Stage #2: With lithium hydroxide In melt; water at 0 - 20℃; Inert atmosphere; Schlenk technique; Sealed tube; Stage #3: In water Inert atmosphere; Schlenk technique; Sealed tube;	41%

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 1-O-phosphate-α-D-glucopyranuronic acid trisodium salt

Conditions

Conditions	Yield
With sodium hypochlorite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; tetrabutyl ammonium fluoride; sodium hydrogencarbonate; sodium bromide In water; ethyl acetate at 0℃; for 2.5h;	69%
With sodium hypochlorite; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; sodium hydroxide In water at 0℃; for 1.5h; pH=9;

: 366-18-7
[2,2]bipyridinyl

: copper(II) nitrate trihydrate

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: [Cu4(μ-OH)(α-D-glucose-1-phosphate)2(2,2'-bipyridyl)4(H2O)2](NO3)3*10H2O

Conditions

Conditions	Yield
In not given Cu salt reacted with Na compd. in presence of 2,2'-bipyridyl; crystals obtained; elem. anal.;	63%

...Expand

: 366-18-7
[2,2]bipyridinyl

: copper(II) nitrate trihydrate

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 7732-18-5
water

: [Cu4(μ-OH)(μ-α-D-glucose-1-phosphate(2-))2(2,2'-bipyridyl)4(H2O)2](NO3)3*10H2O

Conditions

Conditions	Yield
In water Cu salt and bipyridine added to aq. soln. of Na salt of ligand; stirred at room temp. for 1 h; concd. under reduced pressure; evapd. slowly for ca. 1-2 d; filtered; crystals washed with EtOH and Et2O; dried under vac.; elem. anal.;	63%

...Expand

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 187161-22-4
C25H44O20S

: 187161-17-7
methyl O-β-D-glucopyranosyl-(1->4)-O-β-D-glucopyranosyl-(1->3)-S-β-D-glucopyranosyl-(1->4)-O-(4-thio-β-D-glucopyranosyl)-(1->4)-β-D-glucopyranoside

Conditions

Conditions	Yield
With ethylenediaminetetraacetic acid; DL-dithiothreitol; cellodextrin phosphorylase; glucose catalase; glucose oxidase In water at 25℃; for 24h;	56%

: 366-18-7
[2,2]bipyridinyl

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 7732-18-5
water

: 7789-45-9
copper(ll) bromide

: [Cu4(μ-OH)(μ-α-D-glucose-1-phosphate(2-))2(2,2'-bipyridyl)4(H2O)2]Br3*10H2O

Conditions

Conditions	Yield
In water Cu salt and bipyridine added to aq. soln. of Na salt of ligand; stirred at room temp. for 1 h; concd. under reduced pressure; evapd. slowly for ca. 1-2 d; filtered; crystals washed with EtOH and Et2O; dried under vac.; elem. anal.;	45%

...Expand

: 6401-81-6, 17659-52-8, 19141-16-3, 20702-55-0, 52485-13-9, 69429-19-2, 80446-86-2, 80446-87-3, 94799-30-1, 94799-74-3, 113158-51-3, 118396-93-3, 121153-20-6, 133267-59-1, 1109-28-0, 142185-35-1
maltotriose

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 59-56-3, 2240-08-6, 2255-14-3, 2520-52-7, 6799-01-5, 10456-01-6, 14048-34-1, 15978-07-1, 19993-19-2, 20299-62-1, 40591-51-3, 62057-78-7, 77280-79-6, 78341-19-2
mannose-1-phosphate

A α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.094), Mn = 7900: α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.094), Mn = 7900

B amylose: amylose

Conditions

Conditions	Yield
With thermostable α-glucan phosphorylase from Aquifex aeolicus VF5; magnesium chloride In aq. buffer at 40℃; for 168h; pH=8.5; Enzymatic reaction;	A 44.6% B n/a

...Expand

: 6401-81-6, 17659-52-8, 19141-16-3, 20702-55-0, 52485-13-9, 69429-19-2, 80446-86-2, 80446-87-3, 94799-30-1, 94799-74-3, 113158-51-3, 118396-93-3, 121153-20-6, 133267-59-1, 1109-28-0, 142185-35-1
maltotriose

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 59-56-3, 2240-08-6, 2255-14-3, 2520-52-7, 6799-01-5, 10456-01-6, 14048-34-1, 15978-07-1, 19993-19-2, 20299-62-1, 40591-51-3, 62057-78-7, 77280-79-6, 78341-19-2
mannose-1-phosphate

α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.18), Mn = 3970: α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.18), Mn = 3970

Conditions

Conditions	Yield
With thermostable α-glucan phosphorylase from Aquifex aeolicus VF5; magnesium chloride In aq. buffer at 40℃; for 168h; pH=8.5; Enzymatic reaction;	40.3%

...Expand

: 6401-81-6, 17659-52-8, 19141-16-3, 20702-55-0, 52485-13-9, 69429-19-2, 80446-86-2, 80446-87-3, 94799-30-1, 94799-74-3, 113158-51-3, 118396-93-3, 121153-20-6, 133267-59-1, 1109-28-0, 142185-35-1
maltotriose

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: 59-56-3, 2240-08-6, 2255-14-3, 2520-52-7, 6799-01-5, 10456-01-6, 14048-34-1, 15978-07-1, 19993-19-2, 20299-62-1, 40591-51-3, 62057-78-7, 77280-79-6, 78341-19-2
mannose-1-phosphate

α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.15), Mn = 6600: α(1→4)-linked mannoglucan composed of Glc/Man units (1 : 0.15), Mn = 6600

Conditions

Conditions	Yield
With thermostable α-glucan phosphorylase from Aquifex aeolicus VF5; magnesium chloride In aq. buffer at 40℃; for 168h; pH=8.5; Enzymatic reaction;	40.1%

...Expand

: [Cu2(μ-OH)(m-xylenediamine bis(Kemp's triacid imide)(2-))(4-methyl-1,10-phenanthroline)2]NO3*1.5CH2Cl2*CH3OH

: 56401-20-8
α-D-Glucopyranoside 1-(disodium phosphate)

: [Cu2(μ-α-D-glycose 1-phosphate)(m-xylenediamine bis(Kemp's triacid imide)(2-))(4-methyl-1,10-phenanthroline)2]*6H2O

Conditions

Conditions	Yield
In methanol; water soln. sodium salt ligand in aq. MeOH was added to soln. Cu complex in MeOH and stirred for 12 h; solvent was evapd. in vacuo, residue was extd. with MeOH and filtered, Et2O was added; elem. anal.;	38%