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Detail of "5693-62-9"

  • CAS Number:
  • 5693-62-9
  • Name:
  • o-Methylvalerolactim

  • Molecular Structure:
  • Formula:
  • C6H11NO
  • Molecular Weight:
  • 113.16
  • Synonyms:
  • 1-Aza-2-methoxy-1-cyclohexene;2,3,4,5-Tetrahydro-6-methoxypyridine;2-Methoxy-3,4,5,6-tetrahydropyridine;3,4,5,6-Tetrahydro-2-methoxypyridine;6-Methoxy-2,3,4,5-tetrahydropyridine;o-Methyl-d-valerolactim;o-Methylpentanolactim;Valerolactim, o-methyl-;Pyridine,2,3,4,5-tetrahydro-6-methoxy-;
  • Density:
  • 1.02 g/cm3
  • Boiling Point:
  • 147.3 °C at 760 mmHg
  • Flash Point:
  • 37.8 °C

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Reference

Synthesis of heterocycles
Synthesis of heterocycles. 194. Quinolizines and indolizines. 10. Synthesis of 2-hydroxy-6,7,8,9-tetrahydroquinolizin-4-one-1-carboxylate. Kappe, Thomas; Hariri, Mehdi; Soliman, Farid S. G. (Inst. Org. Chem., Univ. Graz, Graz, Austria). Arch. Pharm. (Weinheim, Ger.), 309(8), 684-6 (German) 1976. CODEN: ARPMAS. 5693-62-9 and 15997-31-6 are also in the experiment. DOCUMENT TYPE: Journal CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 31 Tetrahydroquinolizinones I (R = Me, Et), central moieties of quinolizine alkaloids, were prepd. in 57 and 43% yields by keeping piperidine II with (RO2CCH2)2CO and NEt3 in a closed flask 14 days at 25.degree.. Sapon. of I (R = Me) gave 92% I (R = H) and hydrogenation of I (R = Me) over 10% Pd/C gave 5% III. .
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