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57-71-6

Basic Information
CAS No.: 57-71-6
Name: 2,3-Butanedione monoxime
Article Data: 7
Molecular Structure:
Molecular Structure of 57-71-6 (2,3-Butanedione monoxime)
Formula: C4H7NO2
Molecular Weight: 101.105
Synonyms: 2,3-Butanedioneoxime (6CI);2,3-Butanedione, monooxime (8CI,9CI);2,3-Butadione monooxime;2,3-Butanedione 3-monoxime;2,3-Butanedione monoxime;2,3-Butanedione-2-monoxime;2-Hydroxyimino-3-butanone;2-Oximino-3-butanone;3-(Hydroxyimino)-2-butanone;3-Oximino-2-butanone;3-Oxo-2-butanone oxime;Biacetyl monooxime;Biacetyl monoxime;DAM;DAM (oxime);Diacetyl monooxime;Diacetyl monoxime;Isonitrosoethyl methyl ketone;NSC 116103;NSC 660;RA 53;
EINECS: 200-348-5
Density: 1.07 g/cm3
Melting Point: 75-78 °C(lit.)
Boiling Point: 185.5 °C at 760 mmHg
Flash Point: 66 °C
Solubility: 5 g/100 mL (20 ºC)
Appearance: white crystals
Hazard Symbols: HarmfulXn
Risk Codes: 36/37/38-20/21/22
Safety: 22-24/25-36/37/39-26
PSA: 49.66000
LogP: 0.42550
Raw Materials
110-46-3
78-93-3
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Chemistry

Product Name:2,3-Butanedione monoxime
The MF of 2,3-Butanedione monoxime(57-71-6) is C4H7NO2.

                                                            
The MW of 2,3-Butanedione monoxime(57-71-6) is 101.1.
Synonyms:ISONITROSOETHYL METHYL KETONE;DAM;BIACETYL MONOOXIME;DIACETYL MONOOXIME;BIACETYL MONOXIME;DIACETYL MONOXIME;BDM;2,3-BUTANEDIONE, MONO-OXIME
EINECS: 200-348-5
Mol File: 57-71-6.mol
Density: 1.07 g/cm
MP:75-78 °C(lit.)
BP:185-186 °C(lit.)
Fp:185-186°C
Water Solubility:5 g/100 mL (20 oC)
BRN:605582 
CAS DataBase Reference:57-71-6(CAS DataBase Reference)
NIST Chemistry Reference:57-71-6(NIST)
EPA Substance Registry System:57-71-6(EPA Substance)

Uses

It is used as pharmaceutical intermediates, analytical reagent.

Toxicity Data With Reference

1.   

ipr-mus LD50:51 mg/kg

   JPMSAE    Journal of Pharmaceutical Sciences. 53 (1964),1143.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic vapors of NOx.
Hazard Codes:Xn
Risk Statements:36/37/38-20/21/22
R36/37/38:Irritating to eyes, respiratory system and skin ;
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed ;
Safety Statements:22-24/25-36/37/39-26
S22:Do not breathe dust ;
S24/25:Avoid contact with skin and eyes ;
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection ;
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice ;
WGK Germany:3
RTECS:EK3150000
HS Code:29280090

Specification

The 2,3-Butanedione monoxime(57-71-6) is stable but incompatible with strong oxidizing agents.Hazardous decomposition products are Nitrogen oxides, carbon monoxide, carbon dioxide.