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583-52-8

Basic Information
CAS No.: 583-52-8
Name: Potassium oxalate
Article Data: 139
Molecular Structure:
Molecular Structure of 583-52-8 (Potassium oxalate)
Formula: K2C2O4
Molecular Weight: 166.216
Synonyms: Ethanedioicacid, dipotassium salt (9CI);Oxalic acid, dipotassium salt (8CI);Dipotassiumoxalate;Oxa-Gel;Potassium oxalate;Potassium oxalate (K2C2O4);
EINECS: 209-506-8
Density: 2.13
Boiling Point: 365.1 °C at 760 mmHg
Flash Point: 188.8 °C
Solubility: 392g/L at 20℃
Appearance: Odorless white solid.
PSA: 80.26000
LogP: -3.51380
Synthetic route
590-29-4

potassium formate

583-52-8

potassium oxalate

Conditions
ConditionsYield
absence of O2, 440-450°C;95%
124-38-9

carbon dioxide

C45H63Cu3N6S(1-)*C12H24KO6(1+)

A

C45H63Cu3N6S

B

583-52-8

potassium oxalate

Conditions
ConditionsYield
In tetrahydrofuran-d8 at -80℃; for 0.5h; Catalytic behavior; Kinetics; Mechanism; Solvent; Temperature; Concentration;A n/a
B 95%
124-38-9

carbon dioxide

C45H63Cu3N6Se(1-)*C12H24KO6(1+)

A

C45H63Cu3N6Se

B

583-52-8

potassium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior; Solvent; Temperature;A n/a
B 95%
124-38-9

carbon dioxide

C57H87Cu3KN6O3S

A

C45H63Cu3N6S

B

583-52-8

potassium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior; Kinetics; Solvent; Temperature;A n/a
B 95%
124-38-9

carbon dioxide

C57H87Cu3KN6O3Se

A

C45H63Cu3N6Se

B

583-52-8

potassium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior;A n/a
B 95%
124-38-9

carbon dioxide

C45H63Cu3N6Se(1-)*C18H36KN2O6(1+)

A

C45H63Cu3N6Se

B

583-52-8

potassium oxalate

Conditions
ConditionsYield
In (2)H8-toluene at -80℃; for 0.5h; Catalytic behavior;A n/a
B 95%
590-29-4

potassium formate

A

583-52-8

potassium oxalate

B

584-08-7

potassium carbonate

Conditions
ConditionsYield
potassium hydroxide In solid byproducts: H2; 330 °C; with KOH (1:0.05) in N2 atmosphere, the heating rate 6 deg/min;A 93%
B n/a
in aluminium block at 460-500°C;A 79%
B n/a
With air In melt 460-500°C, in presence of air;A 79%
B 20%

potassium hydroxide

583-52-8

potassium oxalate

Conditions
ConditionsYield
With sawdust In not given oxidation at 240-250°C through 1-15 hours by air admission;80%
With sawdust In not given oxidation at 240-250°C through 1-15 hours by air admission;80%
With bran heating;
Hg(b),K(2) (X%)

Hg(b),K(2) (X%)

124-38-9

carbon dioxide

583-52-8

potassium oxalate

Conditions
ConditionsYield
In neat (no solvent) byproducts: K2CO3; 200°C;;72%
In neat (no solvent) heating 2 % K amalgam up to boiling point of Hg;;
In neat (no solvent) byproducts: K2CO3; optimum temp. at 225°C, presence of O2;; small amt. of K2C2O4;;
3705-50-8

2-amino-N,N-dimethyl-3-phenylpropanamide

98-95-3

nitrobenzene

A

583-52-8

potassium oxalate

B

582-25-2

Potassium benzoate

C

124-40-3

dimethyl amine

D

K2CO3; NH3

K2CO3; NH3

Conditions
ConditionsYield
With potassium tert-butylate In tert-butyl alcohol at 50℃; Mechanism; flow of oxygen gas;A 17%
B 35%
C 32%
D n/a
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    Molecular formula: K2C2O4 ? H2O. Molecular weight: 184.22. CAS NO.: 583-52-8 EINECS NO.: 209-506-8 Appearance: White crystalline powder. Organole…

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Chemistry

MF: C2K2O4
MW: 166.22
EINECS: 209-506-8
Synonyms:DI-POTASSIUM OXALATE; dipotassiumethanedioate; Ethanedioicacid, dipotassiumsalt; oxalicacid,dipotassiumsalt;potassiumneutraloxalate;potassiumoxalate(k2c2o4);Potassium Oxalate Anhydrous;Potassium oxalate
POTASSIUM OXALATE's structure:


Potassium oxalate(583-52-8) gives basic aqueous solutions. Reacts as a base to neutralize acids in reactions that generate heat, but less than is generated by neutralization of the bases in reactivity group 10. Can serve as a reducing agent in reactions that generate carbon dioxide.

Uses

Reagent in analytical chemistry, source of oxalic acid, bleaching and cleaning, removing stains from textiles, photography.

Toxicity Data With Reference

   

 

  
OrganismTest TypeRouteReported Dose (Normalized Dose)EffectSource
womenLDLooral1gm/kg (1000mg/kg)CARDIAC: ARRHYTHMIAS (INCLUDING CHANGES IN CONDUCTION)

VASCULAR: SHOCK

GASTROINTESTINAL: OTHER CHANGES
Medecine Legale et Dommage Corporel. Vol. 4, Pg. 178, 1971.

Consensus Reports

Potassium oxalate(583-52-8) is reported in EPA TSCA Inventory.

Safety Profile

Human systemic effects by ingestion: cardiac arrhythmias, shock, gastrointestinal changes. When heated to decomposition it emits acrid smoke and irritating vapors.

Standards and Recommendations

DOT Classification:  6.1; Label: KEEP AWAY FROM FOOD

Specification

1、Handling and Storage of Potassium oxalateStorage(583-52-8)
Store in a cool, dry place. Keep containers closed when not in use. Protect product from moisture. Product is sensitive to light.
Handling
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood. 
2、Fire Fighting Measures of Potassium oxalate(583-52-8)
Fire Fighting
 Fire-fighters should wear full protective clothing including self-contained breathing  apparatus. In case of fire use carbon dioxide, foam, powder or water spray. DO NOT use water in a jet (will spread product).
Fire Potential
Nonflammable.