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5837-78-5

Basic Information
CAS No.: 5837-78-5
Name: Ethyl tiglate
Article Data: 39
Molecular Structure:
Molecular Structure of 5837-78-5 (Ethyl tiglate)
Formula: C7H12O2
Molecular Weight: 128.171
Synonyms: 2-Butenoicacid, 2-methyl-, ethyl ester, (E)-;Crotonic acid, 2-methyl-, ethyl ester, (E)-(8CI);Tiglic acid, ethyl ester (6CI,7CI);(E)-2-Methyl-2-butenoic acid ethylester;Ethyl tiglate;Ethyl a-methylcrotonate;NSC 55278;
EINECS: 227-425-6
Density: 0.909 g/cm3
Melting Point: -62.68°C (estimate)
Boiling Point: 148.2 °C at 760 mmHg
Flash Point: 44.4 °C
Solubility: Slightly soluble in water
Appearance: liquid
Hazard Symbols: R10:;
Risk Codes: 10
Safety: 16-27-36/37/39
Transport Information: UN 3272 3/PG 3
PSA: 26.30000
LogP: 1.51570
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Chemistry

IUPAC Name:  Ethyl (E)-2-methylbut-2-enoate (5837-78-5)
Synonyms: Rarechem al bi 0126 ; Tiglic acid ethyl ester ; (E)-2-Methyl-2-butenoicacidethylester ; 2-Butenoic acid, 2-methyl-, ethyl ester, (E)- ; 2-Methyl-,ethylester,(E)-2-butenoicaci ; 2-Methyl-,ethylester,(E)-2-Butenoicacid ; 2-Methyl-,ethylester,(E)-crotonicaci ; 2-Methyl-trans-but-2-enoicacidethylester
CAS: 5837-78-5
MF: C7H12O2
MW: 128.17
MS:
EINECS: 227-425-6
Product Categories: Aromatic Esters
Mol File: 5837-78-5.mol
Surface Tension: 26.1 dyne/cm 
Density: 0.909 g/cm
Flash Point: 44.4 °C 
Enthalpy of Vaporization: 38.51 kJ/mol 
Boiling Point: 148.2 °C at 760 mmHg
Vapour Pressure: 4.27 mmHg at 25°C
FEMA : 2460
Refractive index:  n20/D 1.435(lit.)
Storage temp:  Flammables area
Merck : 14,9433
BRN : 1720895
Stability: Stable. Flammable. Incompatible with strong oxidizing agents, strong bases
Appearance:Tiglic acid, ethyl ester (6ci,7ci) (5837-78-5) is liquid.

Uses

GB 2760-1996 requireTiglic acid, ethyl ester (6ci,7ci) (5837-78-5) for the use of food with the spices.

Production

In the presence of the acid Ti,ethanol and concentrated sulfuric acid, Tiglic acid, ethyl ester (6ci,7ci) (5837-78-5) can formed by direct esterification.

 

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin > 5gm/kg (5000mg/kg)   Food and Chemical Toxicology. Vol. 26, Pg. 321, 1988.
rat LD50 oral > 5gm/kg (5000mg/kg)   Food and Chemical Toxicology. Vol. 26, Pg. 321, 1988

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Risk Statements:  10
10:  Flammable
Safety Statements:  16-27-36/37/39
16:  Keep away from sources of ignition - No smoking
27:  Take off immediately all contaminated clothing
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection
RIDADR : UN 3272 3/PG 3
WGK Germany:  2
RTECS:  EM9252700
HazardClass:  3
PackingGroup : III
tiglic acid, ethyl ester (6ci,7ci)