CAS No.5878-19-3,2-Propanone, 1-methoxy- Suppliers

Detail of "5878-19-3"

CAS Number:

5878-19-3

Name:

2-Propanone, 1-methoxy-

Superlist Name:

Methoxyacetone

Molecular Structure:

Formula:

C₄H₈O₂

Molecular Weight:

88.12

Synonyms:

2-Propanone,methoxy- (7CI);1-Methoxy-2-propanone;1-Methoxyacetone;Methoxy-2-propanone;Methoxyacetone;Methoxymethyl methyl ketone;Methyl methoxymethyl ketone;a-Methoxyacetone;a-Methoxypropanone;

EINECS:

227-549-0

Density:

0.898 g/cm³

Boiling Point:

118.9 °C at 760 mmHg

Flash Point:

25 °C

Solubility:

Miscible with water

Appearance:

Clear pale yellow to yellow liquid

Risk Codes:

Safety:

16 Details

Transport Information:

UN 1224

Reference

Synthesis and antiinflammatory activity of cis-4,5,6,7,8,8a,9-hexahydro-: Synthesis and antiinflammatory activity of cis-4,5,6,7,8,8a,9-hexahydro-.alpha.-methyl-5H-fluorene-2-acetic acid. Sprague, P. W.; Heikes, J. E. (Squibb Inst. Med. Res., Princeton, N. J., USA). J. Med. Chem., 20(5), 726-8 (English) 1977. CODEN: JMCMAR. DOCUMENT TYPE: Journal CA Section: 1 (Pharmacodynamics) Section cross-reference(s): 26 Title compd. 62490-57-7 and 62490-94-2 are also in the experiment. I [62490-98-6] was prepd. from 7-bromo-1,2,3,4,4a,9a-hexahydro-9-fluorenone [62490-91-9] by hydrogenolysis, dehydration, and redn. to cis-7-bromo-1,2,3,4,4a,9a-hexahydrofluorene [62490-92-0], followed by reaction with BuLi and methoxyacetone [5878-19-3], acid rearrangement, and oxidn. by the Ellison procedure. I had antiinflammatory activity comparable to the unsatd. parent .alpha.-methylfluorene-2-acetic acid [36950-96-6] in the reversal passive Arthus test and the carrageenin-induced rat paw edema assay. .

Vapor phase carbonylation of organic halo compounds: Vapor phase carbonylation of organic halo compounds. Yasuda, Kensei; Shinoda, Kiyonori (Toyama Natl. Coll. Technol., Toyama 939, Japan). Bull. Chem. Soc. Jpn., 65(1), 289-91 (English) 1992. CODEN: BCSJA8. ISSN: 0009-2673. DOCUMENT TYPE: Journal CA Section: 23 (Aliphatic Compounds) Section cross-reference(s): 45, 51 RCH2X (R = e.There are some commonly used reagents with their cas registry numbers 109-68-2 and 5878-19-3 in this article.g., MeO2C, X = halo), s-C4H9X, and C6H5X were methoxycarbonylated with carbon monoxide and methanol into Me carboxylates RCH2CO2Me in the presence of rhodium trichloride/potassium iodide supported on activated charcoal. The reactivity decreased in the order: X = I > Br > Cl. .

Detail of "5878-19-3"

2-Propanone, 1-methoxy-

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Reference