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CAS No.: | 5911-08-0 |
---|---|
Name: | Cylopropylmethyl chloride |
Article Data: | 35 |
Molecular Structure: | |
Formula: | C4H7Cl |
Molecular Weight: | 90.5526 |
Synonyms: | (Chloromethyl)cyclopropane;Chlorocyclopropylmethane;Cyclopropanemethyl chloride;Cyclopropylcarbinylchloride;Cyclopropylchloromethane;a-(Chloromethyl)cyclopropane; |
EINECS: | 227-632-1 |
Density: | 1.056 g/cm3 |
Melting Point: | -91 °C |
Boiling Point: | 87.6 °C at 760 mmHg |
Flash Point: | 29 °F |
Solubility: | Not miscible in water. |
Appearance: | COA |
Hazard Symbols: | F, Xi |
Risk Codes: | 11-36/37/38 |
Safety: | 16-26-36/37/39 |
Transport Information: | UN 1993 3/PG 2 |
PSA: | 0.00000 |
LogP: | 1.63520 |
Conditions | Yield |
---|---|
With phenylphosphorus tetrachloride In chloroform at 0℃; for 0.0833333h; | 98% |
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine at 0 - 20℃; for 3.25h; | 95% |
With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at -10 - 25℃; for 5h; Solvent; Temperature; | 94% |
tetrachloromethane
tri(cyclopropylmethyl)phosphite
A
3-butenyl chloride
B
Phosphoric acid tricyclopropylmethyl ester
C
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester
D
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
In toluene at 80℃; Further byproducts given; | A 16% B 2% C 80% D 64% |
Cyclopropylmethanol
A
3-butenyl chloride
B
chlorocyclobutane
C
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
A 15% B 18% C 80% |
cyclopropylmethyl
A
3-butenyl chloride
B
1,3-dichlorobutane
C
1,2,4-trichlorobutane
D
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
With chlorine In benzene Rate constant; Product distribution; Irradiation; other chlorinating agents; | A 10.3% B 6.2% C 19.1% D 34.4% |
methylcyclopropane
A
3-butenyl chloride
B
1,3-dichlorobutane
C
1,2,4-trichlorobutane
D
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
With chlorine In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; Irradiation; | A 10.3% B 6.2% C 19.1% D 34.4% |
With tert-butylhypochlorite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; for 2.5h; Irradiation; | A 17% B 3.2% C 6.5% D 24.2% |
Conditions | Yield |
---|---|
With phosphorus pentachloride | |
With hydrogenchloride |
Conditions | Yield |
---|---|
With chlorine Irradiation; | |
With chlorine at -196.1℃; Quantum yield; Irradiation; var. magnetic field; |
chlorocyclobutane
potassium acetate
acetic acid
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
at 100℃; Rate constant; Solvolyse und Isomerisierung; |
Conditions | Yield |
---|---|
Cu catalyst |
3,4-dichlorobut-1-ene
chloro(cyclopropyl)methane
Conditions | Yield |
---|---|
(i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH; Multistep reaction; |
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IUPAC Name:chloromethylcyclopropane
Molecular Formula:C4H7Cl
Molecular Weight:90.551380 g/mol
Appearance:colorless liquid
Melting Point:-91°C
Boiling Point:87-89 °C(lit.)
Flash Point:29 °F
Water Solubility:1165 mg/L at 25 °C
Density:0.98 g/mL at 25 °C(lit.)
Refractive index:n20/D 1.435(lit.)
BRN:635697
EINECS:227-632-1
Synonyms of Cylopropylmethyl chloride(5911-08-0):
CYCLOPROPYLMETHYL CHLORIDE;(CHLOROMETHYL)CYCLOPROPANE;Cyclopropane, (chloromethyl)-;Cyclopropane,(chloromethyl);Cylopropylmethylchloride;Cyclopropylmethychloride;Cyclopropylmethyl Chloride, Pract.;CPMCl
Categories of Cylopropylmethyl chloride(5911-08-0):
Cycloalkanes;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
First Aid Measures of Cylopropylmethyl chloride(5911-08-0):
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Storage of Cylopropylmethyl chloride(5911-08-0):
Keep away from heat, sparks, and flame. Flammables-area.