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CAS No.: | 5921-80-2 |
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Name: | Butane, 1,1-dibutoxy- |
Article Data: | 31 |
Molecular Structure: | |
Formula: | C12H26 O2 |
Molecular Weight: | 202.337 |
Synonyms: | Butyraldehyde,dibutyl acetal (6CI,7CI,8CI); 1,1-Dibutoxybutane; Lageracetal |
Density: | 0.844g/cm3 |
Boiling Point: | 215.8°C at 760 mmHg |
Flash Point: | 51°C |
PSA: | 18.46000 |
LogP: | 3.74600 |
Conditions | Yield |
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With hydrogenchloride In diethyl ether at 20℃; for 0.333333h; | 91% |
With sulfur dioxide In benzene for 6h; Heating; | 54% |
With hydrogenchloride at 25℃; Gleichgewicht und Geschwindigkeit der Reaktion; |
Conditions | Yield |
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With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; C18H17N2O2P In tetrahydrofuran at 130℃; for 24h; Inert atmosphere; Schlenk technique; | 74% |
With tetrabutylammonium tetrafluoroborate (electrolysis); | |
With Ru(PPh3)2(NCCH3)2(η2-SO4) at 118℃; for 48h; Inert atmosphere; chemoselective reaction; | 47 %Chromat. |
meso-galactaric acid
butan-1-ol
A
lageracetal
B
(2E,4E)-hexa-2,4-dienedioic acid dibutyl ester
Conditions | Yield |
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With per-rhenic acid In water at 170℃; for 7.5h; Time; Inert atmosphere; | A n/a B 71% |
Conditions | Yield |
---|---|
With per-rhenic acid In water at 170℃; for 15h; | A 50% B 47% |
Conditions | Yield |
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With hydrogenchloride unter Abdestillieren von Acetaldehyd; |
Conditions | Yield |
---|---|
With tert-Butyl peroxybenzoate; copper(l) chloride In benzene |
2-methyl-propan-1-ol
butyraldehyde
butan-1-ol
A
lageracetal
B
n-butyraldehyde diisobutyl acetal
C
1-butoxy-1-isobutoxy butane
Conditions | Yield |
---|---|
hydrogenchloride In dichloromethane Heating; |
butan-1-ol
A
3-methyl-1,4-heptanediol
B
lageracetal
C
octane-4,5-diol
D
2-ethyl-1,3-hexane diol
Conditions | Yield |
---|---|
With hydrogen; mercury under 760 Torr; Heating; Irradiation; Yield given. Yields of byproduct given; |
n-Butyl nitrite
4-tert-Butylaniline
A
tert-butylbenzene
B
lageracetal
C
4-tert-butyl-2-nitrophenol
D
4-tert-butylphenyl-n-butyl-ether
E
4-(tert-butyl)chlorobenzene
F
1,2-bis(4-(tert-butyl)phenyl)diazene
Conditions | Yield |
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With tetrachloromethane for 0.5h; Product distribution; other time, other temp., also without CCl4; |
Conditions | Yield |
---|---|
With tetrachloromethane; 4-chloro-aniline at 60℃; for 1h; |