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| CAS No.: | 598-22-1 |
|---|---|
| Name: | Propionyl bromide |
| Article Data: | 12 |
| Molecular Structure: | |
|
|
|
| Formula: | C3H5BrO |
| Molecular Weight: | 136.976 |
| Synonyms: | Propanoylbromide (9CI);Propionylbromide (6CI,7CI,8CI);Propionic acid bromide;Propionyl bromide,95%; |
| EINECS: | 209-924-0 |
| Density: | 1.521 g/cm3 |
| Melting Point: | -40oC |
| Boiling Point: | 103.3 °C at 760 mmHg |
| Flash Point: | 52.2 °C |
| Appearance: | light yellow to brown liquid |
| Hazard Symbols: |
 C
|
| Risk Codes: | 10-14-34 |
| Safety: | 26-36/37/39-45 |
| Transport Information: | UN 2920 8/PG 2 |
| PSA: | 17.07000 |
| LogP: | 1.31790 |
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propionic acid
- 598-22-1
propanoyl bromide
| Conditions | Yield |
|---|---|
| With bromine; triphenylphosphine In dichloromethane for 0.25h; Ambient temperature; | 84% |
| With phosphorus; bromine | |
| With dibromo sulfoxide | |
| With lithium aluminium deuteride; sulfuric acid; hydrogen bromide Multistep reaction; | |
| With ethyl tribromoacetate; triphenylphosphine In dichloromethane at 20℃; for 3h; |
| Conditions | Yield |
|---|---|
| With trimethylsilyl bromide | 74% |
- 16844-98-7
trimethylsilyl propionate
- 598-22-1
propanoyl bromide
| Conditions | Yield |
|---|---|
| With dibromotriphenylphosphorane In dichloromethane for 0.166667h; Ambient temperature; |
- 15843-24-0
propionyl radical
- 598-22-1
propanoyl bromide
| Conditions | Yield |
|---|---|
| With Bromotrichloromethane In hexane at 22.9℃; Rate constant; |
- 598-22-1
propanoyl bromide
- 84092-82-0
N-deacetylcolchinyl methyl ether
- 851674-06-1
N-propionylcolchinol methyl ether
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at 20℃; for 1h; | 98% |
| Conditions | Yield |
|---|---|
| With aluminium trichloride In carbon disulfide for 2h; Heating; | 95% |
- 159547-29-2
2-[5-amino-2-(trifluoromethyl)phenyl]-4-[[2'-[N-(t-butoxycarbonyl)sulfamoyl]-3-fluorobiphenyl-4-yl]methyl]-5-n-butyl-2,4-dihydro-3H-1,2,4-triazol-3-one
- 598-22-1
propanoyl bromide
| Conditions | Yield |
|---|---|
| 95% |
| Conditions | Yield |
|---|---|
| With sodium hydrogencarbonate In water; benzene at 20℃; | 94% |
| Conditions | Yield |
|---|---|
| With aluminium trichloride In carbon disulfide for 2h; Heating; | 93% |
- 598-22-1
propanoyl bromide
- 159954-93-5
2-<5-amino-2-(trifluoromethyl)phenyl>-5-n-butyl-4-<<2'-(N-tert-butylsulfamoyl)biphenyl-4-yl>methyl>-2,4-dihydro-3H-1,2,4-triazol-3-one
- 159954-94-6
5-n-butyl-4-<<2'-(N-tert-butylsulfamoyl)biphenyl-4-yl>methyl>-2,4-dihydro-2-<5-(propionylamino)-2-(trifluoromethyl)phenyl>-3H-1,2,4-triazol-3-one
| Conditions | Yield |
|---|---|
| With pyridine; dmap Ambient temperature; | 90% |
| dmap | 67% |
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Chemistry
The molecular structure of Propionyl Bromide(CAS NO.598-22-1):
.png)
Empirical Formula: C3H5BrO
Molecular Weight: 136.9752
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 1
Index of Refraction: 1.449
Molar Refractivity: 23.7 cm3
Molar Volume: 88.3 cm3
Surface Tension: 31.1 dyne/cm
Density: 1.55 g/cm3
Flash Point: 52.2 °C
Enthalpy of Vaporization: 34.24 kJ/mol
Boiling Point: 103.3 °C at 760 mmHg
Vapour Pressure: 32.5 mmHg at 25°C
InChI
InChI=1/C3H5BrO/c1-2-3(4)5/h2H2,1H3
Smiles
C(=O)(Br)CC
EINECS: 209-924-0
Product Categories: Organics; Acid Halides; Carbonyl Compounds; Organic Building Blocks
Safety Profile
Hazard Codes: 
C
Risk Statements: 10-14-34
R10:Flammable.
R14 :Reacts violently with water.
R34:Causes burns.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2920 8/PG 2
WGK Germany: 3
HazardClass: 3.2
PackingGroup: III
Specification
Propionyl bromide , with CAS number of 598-22-1, can be called Propanoyl bromide;Propionic acid bromide;1-Bromo-1-propanone ; Propanoic acid bromide ; Propionyl bromide,95% ; Propionylbromide (6CI,7CI,8CI) . Chemical Properties of Propionyl Bromide(598-22-1) is a light yellow to brown liquid, fuming with moisture, so need to be stored in a dry, cool, well-ventilated area. Soluble in ether, decomposition with water or alcohol. Its main purpose is to make pharmaceutical intermediates for organic synthesis, obtained by the anhydrous acid reaction with bromine in the condition of red phosphorus.
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