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CAS No.: | 598-73-2 |
---|---|
Name: | BROMOTRIFLUOROETHYLENE |
Article Data: | 14 |
Molecular Structure: | |
Formula: | C2Br F3 |
Molecular Weight: | 160.921 |
Synonyms: | Ethene,bromotrifluoro- (9CI); Ethylene, bromotrifluoro- (6CI,7CI,8CI);1,1,2-Trifluoro-2-bromoethylene; 1,2,2-Trifluoro-2-bromoethylene;1-Bromo-1,2,2-trifluoroethylene; Bromotrifluoroethene; Bromotrifluoroethylene;HBFC 1113B1; Trifluorobromoethylene; Trifluorovinyl bromide |
Density: | 1.909g/cm3 |
Boiling Point: | 10.6°Cat760mmHg |
Flash Point: | °C |
Hazard Symbols: | F,Xi |
Risk Codes: | 11 |
Safety: | A poison. A flammable gas. Ignites spontaneously in air. Incompatible with powerful oxidizers, O2. When heated to decomposition it emits highly toxic fumes of Br−, F−, and COCF2. |
PSA: | 0.00000 |
LogP: | 2.41640 |
Conditions | Yield |
---|---|
With potassium hydroxide | |
With potassium hydroxide | |
With potassium hydroxide; water at 76℃; | |
With pyrographite; potassium nitrate at 20 - 400℃; for 6h; Reagent/catalyst; Temperature; Inert atmosphere; |
Conditions | Yield |
---|---|
Irradiation; radiation > 237 nm; |
3-bromo-3-(trifluoromethyl)diazirine
A
2-bromo-1,1,1-trifluoroethane
B
1-bromo-1,2,2-trifluoroethene
Conditions | Yield |
---|---|
Irradiation; | |
Irradiation; radiation > 330 nm; |
Conditions | Yield |
---|---|
at 120℃; |
1-bromo-1,2,2-trifluoroethene
Conditions | Yield |
---|---|
With ethanol; potassium acetate; potassium carbonate | |
With sodium ethanolate |
(pentafluoro ethyl) magnesiumbromide
A
1,1-dibromo-2,2-difluoroethylene
B
1-bromo-1,2,2-trifluoroethene
C
Iodotrifluoroethylene
Conditions | Yield |
---|---|
In diethyl ether thermal decompn. on warming from -40°C to 20°C; | |
In diethyl ether thermal decompn. on warming from -40°C to 20°C; |
(1,2-dibromotrifluoroethyl)pentafluorosulfur(VI)
A
fluorosulfonyl fluoride
B
1-bromo-1,2,2-trifluoroethene
C
(trifluoroethenyl)pentafluorosulfur(VI)
Conditions | Yield |
---|---|
With Cu with Cu powder, 188°C; |
N(C4H9)4(1+)*CF2CFBF3(1-)=N(C4H9)4[CF2CFBF3]
A
1-bromo-1,2,2-trifluoroethene
B
[Bu4N][CF2BrCFBrBF3]
Conditions | Yield |
---|---|
With bromine In dichloromethane at 20℃; for 66h; |
N(C4H9)4(1+)*CF2CFBF3(1-)=N(C4H9)4[CF2CFBF3]
A
bromopentafluoroethane
B
1-bromo-1,2,2-trifluoroethene
Conditions | Yield |
---|---|
With bromine trifluoride; bromine In 1,1,1,3,3-pentafluorobutane at -15℃; for 0.25h; |
polytetrafluoroethylene
A
1-bromo-1,2,2-trifluoroethene
B
hexafluoro-1,3-butadiene
Conditions | Yield |
---|---|
Stage #1: polytetrafluoroethylene With magnesium; zinc(II) chloride at 60℃; under 3800.26 Torr; Inert atmosphere; Autoclave; Stage #2: With copper(ll) bromide In benzene-d6 at 20℃; for 0.166667h; Inert atmosphere; Sealed tube; |
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IUPAC Name: 1-Bromo-1,2,2-trifluoroethene
Molecular Formula: BrF3C2
Molecular Weight: 160.94g/mol
Density: 1.909g/cm3
Boiling Point: 10.6°C at 760mmHg
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2
Index of Refraction: 1.374
Molar Refractivity: 19.28 cm3
Molar Volume: 84.2 cm3
Polarizability: 7.64 ×10-24cm3
Surface Tension: 17.3 dyne/cm
Enthalpy of Vaporization: 24.79 kJ/mol
Vapour Pressure: 1260 mmHg at 25°C
The Cas Register Number of Bromo trifluoroethylene is 598-73-2 .The chemical synonyms of Bromo trifluoroethylene (CAS NO.10043-09-1) are Bromotrifluoroethylene ; Bromotrifluoroethylene monomer ; Trifiuorobromoethylene ; Bromotrifluoro-ethen ; Bromotrifluoroethene ; Bromotrifluoro-ethene ; Bromotrifluoro-ethylen ; C2BrF3 .The molecular structure of Bromo trifluoroethylene (CAS NO.10043-09-1) is .
Bromo trifluoroethylene (CAS NO.10043-09-1) can be used in organic synthesis.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LCLo | inhalation | 279ppm/4H (279ppm) | CRC Critical Reviews in Toxicology. Vol. 21, Pg. 149, 1990. |
Reported in EPA TSCA Inventory.
A poison. A flammable gas. Ignites spontaneously in air. Incompatible with powerful oxidizers, O2. When heated to decomposition it emits highly toxic fumes of Br−, F−, and COCF2.
Hazard Codes: F,Xi
Risk Statements: 11
R11:Highly flammable.
Safety Statements: 16-33
R16:Explosive when mixed with oxidizing substances.
R33:Danger of cumulative effects.
RIDADR: 2419
Hazard Note: Flammable
TSCA: T
HazardClass: 2.1