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598-73-2

Basic Information
CAS No.: 598-73-2
Name: BROMOTRIFLUOROETHYLENE
Article Data: 14
Molecular Structure:
Molecular Structure of 598-73-2 (BROMOTRIFLUOROETHYLENE)
Formula: C2Br F3
Molecular Weight: 160.921
Synonyms: Ethene,bromotrifluoro- (9CI); Ethylene, bromotrifluoro- (6CI,7CI,8CI);1,1,2-Trifluoro-2-bromoethylene; 1,2,2-Trifluoro-2-bromoethylene;1-Bromo-1,2,2-trifluoroethylene; Bromotrifluoroethene; Bromotrifluoroethylene;HBFC 1113B1; Trifluorobromoethylene; Trifluorovinyl bromide
Density: 1.909g/cm3
Boiling Point: 10.6°Cat760mmHg
Flash Point: °C
Hazard Symbols: F,Xi
Risk Codes: 11
Safety: A poison. A flammable gas. Ignites spontaneously in air. Incompatible with powerful oxidizers, O2. When heated to decomposition it emits highly toxic fumes of Br, F, and COCF2.
PSA: 0.00000
LogP: 2.41640
Synthetic route
354-04-1

1,2-dibromo-1,1,2-trifluoroethane

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
With potassium hydroxide
With potassium hydroxide
With potassium hydroxide; water at 76℃;
With pyrographite; potassium nitrate at 20 - 400℃; for 6h; Reagent/catalyst; Temperature; Inert atmosphere;
421-06-7

2-bromo-1,1,1-trifluoroethane

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
Irradiation; radiation > 237 nm;
117113-33-4

3-bromo-3-(trifluoromethyl)diazirine

A

421-06-7

2-bromo-1,1,1-trifluoroethane

B

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
Irradiation;
Irradiation; radiation > 330 nm;
75-82-1

1,2-dibromo-1,1-difluoroethane

AgF

AgF

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
at 120℃;
trifluorodibromoethane

trifluorodibromoethane

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
With ethanol; potassium acetate; potassium carbonate
With sodium ethanolate
56184-59-9

(pentafluoro ethyl) magnesiumbromide

A

430-85-3

1,1-dibromo-2,2-difluoroethylene

B

598-73-2

1-bromo-1,2,2-trifluoroethene

C

359-37-5

Iodotrifluoroethylene

Conditions
ConditionsYield
In diethyl ether thermal decompn. on warming from -40°C to 20°C;
In diethyl ether thermal decompn. on warming from -40°C to 20°C;
22687-88-3

(1,2-dibromotrifluoroethyl)pentafluorosulfur(VI)

A

640723-20-2, 2699-79-8, 12769-73-2

fluorosulfonyl fluoride

B

598-73-2

1-bromo-1,2,2-trifluoroethene

C

1186-51-2

(trifluoroethenyl)pentafluorosulfur(VI)

Conditions
ConditionsYield
With Cu with Cu powder, 188°C;
1375484-85-7

N(C4H9)4(1+)*CF2CFBF3(1-)=N(C4H9)4[CF2CFBF3]

A

598-73-2

1-bromo-1,2,2-trifluoroethene

B

1375485-13-4

[Bu4N][CF2BrCFBrBF3]

Conditions
ConditionsYield
With bromine In dichloromethane at 20℃; for 66h;
1375484-85-7

N(C4H9)4(1+)*CF2CFBF3(1-)=N(C4H9)4[CF2CFBF3]

A

354-55-2

bromopentafluoroethane

B

598-73-2

1-bromo-1,2,2-trifluoroethene

Conditions
ConditionsYield
With bromine trifluoride; bromine In 1,1,1,3,3-pentafluorobutane at -15℃; for 0.25h;
116-14-3

polytetrafluoroethylene

A

598-73-2

1-bromo-1,2,2-trifluoroethene

B

685-63-2

hexafluoro-1,3-butadiene

Conditions
ConditionsYield
Stage #1: polytetrafluoroethylene With magnesium; zinc(II) chloride at 60℃; under 3800.26 Torr; Inert atmosphere; Autoclave;
Stage #2: With copper(ll) bromide In benzene-d6 at 20℃; for 0.166667h; Inert atmosphere; Sealed tube;
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Chemistry

IUPAC Name: 1-Bromo-1,2,2-trifluoroethene  
Molecular Formula: BrF3C2
Molecular Weight: 160.94g/mol
Density: 1.909g/cm3
Boiling Point: 10.6°C at 760mmHg
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2
Index of Refraction: 1.374
Molar Refractivity: 19.28 cm3
Molar Volume: 84.2 cm3
Polarizability: 7.64 ×10-24cm3
Surface Tension: 17.3 dyne/cm
Enthalpy of Vaporization: 24.79 kJ/mol
Vapour Pressure: 1260 mmHg at 25°C 
The Cas Register Number of Bromo trifluoroethylene is 598-73-2 .The chemical synonyms of  Bromo trifluoroethylene (CAS NO.10043-09-1) are Bromotrifluoroethylene ; Bromotrifluoroethylene monomer ; Trifiuorobromoethylene ; Bromotrifluoro-ethen ; Bromotrifluoroethene ; Bromotrifluoro-ethene ; Bromotrifluoro-ethylen ; C2BrF3 .The molecular structure of Bromo trifluoroethylene (CAS NO.10043-09-1) is  .

Uses

 Bromo trifluoroethylene (CAS NO.10043-09-1) can be used in organic synthesis.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LCLo inhalation 279ppm/4H (279ppm)   CRC Critical Reviews in Toxicology. Vol. 21, Pg. 149, 1990.
 

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison. A flammable gas. Ignites spontaneously in air. Incompatible with powerful oxidizers, O2. When heated to decomposition it emits highly toxic fumes of Br, F, and COCF2.
Hazard Codes: FlammableF,IrritantXi
Risk Statements: 11
R11:Highly flammable. 
Safety Statements: 16-33
R16:Explosive when mixed with oxidizing substances.
R33:Danger of cumulative effects.  
RIDADR: 2419
Hazard Note: Flammable
TSCA: T
HazardClass: 2.1