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| CAS No.: | 602-38-0 | |||
|---|---|---|---|---|
| Name: | 1,8-Dinitronaphthalene | |||
| Article Data: | 56 | |||
| Molecular Structure: | ||||
|
|
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| Formula: | C10H6 N2 O4 | |||
| Molecular Weight: | 218.169 | |||
| Synonyms: | 1,8-Dinitronaphthalene;NSC 6323 | |||
| EINECS: | 210-016-1 | |||
| Density: | 1.481g/cm3 | |||
| Melting Point: | 171 - 172 C (97 %) | |||
| Boiling Point: | 389.8°C at 760 mmHg | |||
| Flash Point: | 200.3°C | |||
| Solubility: | 0.1 g/100ml AUTOIGNITION | Yellow Crystalline Powder | ||
| Hazard Symbols: | UN NO. | |||
| Risk Codes: | 11-36/37/38 | |||
| Transport Information: | 25kgs | |||
| PSA: | 91.64000 | |||
| LogP: | 3.70260 | |||
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- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
| Conditions | Yield |
|---|---|
| With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction; | 81% |
- 91-20-3
naphthalene
A
- 86-57-7
1-Nitronaphthalene
B
- 602-38-0
1,8-dinitronaphthalene
C
- 605-71-0
1,5-dinitronaphthalene
| Conditions | Yield |
|---|---|
| With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst; | A 78.5% B 10.6% C 6.2% |
| With nitric acid In acetic acid at 64.84℃; for 3h; Catalytic behavior; Solvent; | A 22.5% B 42.5% C 32.6% |
| With phosphotungstic acid; nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst; | A 31.5% B 36.7% C 28.5% |
| With nitric acid In dichloromethane for 12h; Reflux; regioselective reaction; |
| Conditions | Yield |
|---|---|
| With nitric acid at 64.84℃; for 3h; Catalytic behavior; Reagent/catalyst; | A 49.2% B 48.5% |
| With nitric acid | |
| With nitric acid Erwaermen des Reaktionsgemischs mit konz. Schwefelsaeure; |
| Conditions | Yield |
|---|---|
| With sulfuric acid; nitric acid | |
| With Nitrogen dioxide |
| Conditions | Yield |
|---|---|
| With sulfuric acid; potassium nitrate at 0℃; | |
| With sulfuric acid; nitric acid at 0 - 35℃; | |
| With sulfuric acid; nitric acid |
| Conditions | Yield |
|---|---|
| With nitric acid | |
| With sulfuric acid; nitric acid at 0℃; Trennung der beiden Isomere durch Umkrystallisieren aus Pyridin; | |
| With sulfuric acid; nitric acid at 0℃; |
- 90765-71-2
1-amino-4,5-dinitronaphthalene
- 602-38-0
1,8-dinitronaphthalene
| Conditions | Yield |
|---|---|
| With sulfuric acid; acetic acid Diazotization.Behandlung der Diazoniumsalz-Loesung mit Cu2O und Aethanol; |
- 91-20-3
naphthalene
A
- 602-38-0
1,8-dinitronaphthalene
B
- 24824-25-7
1,7‑dinitronaphthalene
C
- 607-46-5
1,6-dinitronaphthalene
D
- 605-71-0
1,5-dinitronaphthalene
| Conditions | Yield |
|---|---|
| With cupric nitrate trihydrate supported on K 10 montmorillonite clay; nitric acid; acetic anhydride In tetrachloromethane for 3h; Ambient temperature; Yield given. Yields of byproduct given; |
- 91-20-3
naphthalene
A
- 86-57-7
1-Nitronaphthalene
B
- 602-38-0
1,8-dinitronaphthalene
C
- 606-37-1
2,4-dinitronaphthalene
D
- 581-89-5
2-nitronaphthalene
E
- 605-71-0
1,5-dinitronaphthalene
| Conditions | Yield |
|---|---|
| With Nitrogen dioxide; ozone In dichloromethane at -25℃; for 0.0833333h; Product distribution; Mechanism; other methylnaphthalenes; also with HNO3/Ac2O system and with methanesulfonic acid; var. temp. and reaction times; |
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Chemistry
Chemical Name: 1,8-Dinitronaphthalene
IUPAC NAME: 1,8-Dinitronaphthalene
CAS No.: 602-38-0
EINECS: 210-016-1
RTECS: QJ4552000
RTECS Class: Mutagen
Molecular Formula: C10H6N2O4
Molecular Weight: 218.17 g/mol
Melting Point: 161 °C
Density: 1.481 g/cm3
Flash Point: 200.3 °C
Boiling Point: 389.8 °C at 760 mmHg
Following is the structure of 1,8-Dinitronaphthalene (CAS No.602-38-0):
The chemical synonymous of 1,8-Dinitronaphthalene (CAS No.602-38-0) are 1,8-Dinitro-Naphthalen ; 1,8-Dinitronaphthalene ; Labotest-Bb Lt00436938 ; 1,8-Dinitronaphthalene, Contains Variable Amounts Of Water, 97% ; Naphthalene, 1,8-Dinitro- ; 1,8-Dinitronaphthalene,85%
Toxicity Data With Reference
| 1. | mmo-sat 100 µg/plate | MUREAV Mutation Research. 91 (1981),321. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Suspected carcinogen. Mutation data reported. When heated to decomposition it emits toxic vapors of NOx.
Attention:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Standards and Recommendations
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans