CAS No.603-33-8,Triphenylbismuth Suppliers

Products Categories

Pharmaceutical (106)
Organic Chemicals (45)
Others (14)
Catalyst and Auxiliary (13)
Reagent (9)
Materials (7)
Food Additives (1)

Basic Information

Molecular Structure:
CAS No.:	603-33-8
Name:	Triphenylbismuth
Article Data:	194

Formula:	C₁₈H₁₅Bi
Molecular Weight:	440.298
Synonyms:	NSC 465;Triphenylbismuthine;
EINECS:	210-033-4
Density:	1.585 g/cm³
Melting Point:	78-80 °C
Boiling Point:	310 °C
Flash Point:	242 °C/14mm
Solubility:	insoluble in water
Appearance:	white to off-white crystalline powder
Hazard Symbols:	Xn
Risk Codes:	20/21/22
Safety:	24/25-36/37
PSA:	0.00000
LogP:	4.46040

Synthetic route

: 7787-58-8
bismuth(III) bromide

: 587-85-9
diphenylmercury(II)

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In diethyl ether byproducts: C6H5HgBr; 12h; distillation of ether phase;	100%

: BiO2SC6H5

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In not given byproducts: SO2; 4h at 216°C under 1E-2 - 1E-3 Torr;	100%

: 28719-55-3, 7065-17-0
dibromotriphenylbismuth

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In ethanol 1h reflux;	100%
With potassium hydroxide In water 5h reflux or shaking;
With ammonia In ethanol byproducts: sulfur;
With NH3 In ethanol byproducts: sulfur;

: 2023-48-5, 28719-53-1
triphenylbismuth difluoride

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In ethanol 1h reflux;	100%
in alkaline medium;
in alkaline medium;

: 28719-54-2, 507233-69-4, 594-30-9
triphenylbismuth dichloride

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In ethanol 1h reflux;	100%
With sodium hydrogensulfite In acetone at 0°C;	80%
With potassium hydroxide In ethanol 5h reflux or shaking;

: 42967-53-3
tetraphenylbismuth chloride

A: 603-33-8
triphenylbismuthane

B: 108-90-7
chlorobenzene

Conditions

Conditions	Yield
In not given decomposition at room temp.;	A 100% B 100%

: C6H5Bi(O2SC6H5)2

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In not given byproducts: SO2; 4h at 190°C under 1E-2 - 1E-3 Torr;	100%

: 3049-07-8
pentaphenylbismuth

: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
With isopropyl alcohol In not given byproducts: C6H6, acetone; at 20°C;	100%
In pyridine byproducts: benzene, arine=arin(germ.); decomposition in pyridine;	100%
With phenol In not given byproducts: C6H6, C6H5OH, diphenylether;	90%

: 38222-83-2
2,6-di-tert-butyl-4-methylpyridine

: 278172-59-1
methyltriphenylbismuthonium tetrafluoroborate

A: 67-56-1
methanol

B: 115-10-6
Dimethyl ether

C: 160142-36-9
2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

D: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
With H2O In chloroform-d1 water was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and mixt. was allowed to stand at room temp. for 33 h; detn. by NMR;	A 30% B 16% C 100% D 100%

...Expand

: 38222-83-2
2,6-di-tert-butyl-4-methylpyridine

: 278172-59-1
methyltriphenylbismuthonium tetrafluoroborate

: 67-63-0
isopropyl alcohol

A: 598-53-8
isopropyl methyl ether

B: 160142-36-9
2,6-di-tert-butyl-4-methylpyridinium tetrafluoroborate

C: 603-33-8
triphenylbismuthane

Conditions

Conditions	Yield
In chloroform-d1 alcohol was added to mixt. (Ph3BiMe)(BF4) and 2,6-di-tert-butyl-4-methylpyridine in CDCl3 and allowed to react at 23°C for 4-7 h; detn. by NMR;	A 82% B 100% C 100%

...Expand

Total:131 Page 1 of 4 1 2 3 4 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 603-33-8

Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

PURITY: 98.0% min
Bi CONTENT: 47.0 - 48.0%
METALLIC IMPURITY: 0.1% max

Specification

The Triphenylbismuthine, with its CAS registry number 603-33-8, is a kind of white to off-white crystalline powder. For being sensitive to moisture and insoluble in water, its product categories are including blocks; BuildingBlocks; Organometallics.

The physical properties of this chemical are as below: (1)#H bond acceptors: 0 ; (2)#H bond donors: 0 ; (3)#Freely Rotating Bonds: 3 ; (4)Polar Surface Area: 0; (5)Exact Mass: 440.097758; (6)MonoIsotopic Mass: 440.097758; (7)Heavy Atom Count: 19; (8)Complexity: 202; (9)Covalently-Bonded Unit Count: 1.

Use of this chemical is below: Triphenylbismuthine could react with piperidine to produce 1-phenyl-piperidine with the catalytic agent of Cu(OAc)₂ and the solvent of CH₂Cl₂. And in this reaction, the reaction time is 18 hour(s) and the yield is 56 % in the ambient temperature.

When you are dealing with this chemical, you should be careful. For being a kind of harmful chemical which may cause damage to health, it is dangerous to our body if by inhalation, in contact with skin and if swallowed. Therefore, you should wear suitable protective clothing and gloves and then avoid contact with skin and eyes.

In addition, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: C1=CC=C(C=C1)[Bi](C2=CC=CC=C2)C3=CC=CC=C3
(2)InChI: InChI=1S/3C6H5.Bi/c3*1-2-4-6-5-3-1;/h3*1-5H;
(3)InChIKey: ZHXAZZQXWJJBHA-UHFFFAOYSA-N

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
mouse	LD50	intravenous	180mg/kg (180mg/kg)	U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01712,
mouse	LDLo	intraperitoneal	250mg/kg (250mg/kg)	"Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 317, 1952.
mouse	LDLo	oral	320mg/kg (320mg/kg)	Archives of Environmental Contamination and Toxicology. Vol. 14, Pg. 111, 1985.