CAS No.6097-32-1,2-Propanone,1-(3,4-dichlorophenyl)- Suppliers

Detail of "6097-32-1"

CAS Number:

6097-32-1

Name:

Superlist Name:

Molecular Structure:

Formula:

C₉H₈Cl₂O

Molecular Weight:

203.0652

Synonyms:

2-Propanone,(3,4-dichlorophenyl)- (7CI);

EINECS:

229-511-9

Density:

1.27 g/cm³

Boiling Point:

271.3 °C at 760 mmHg

Flash Point:

112.5 °C

Appearance:

clear light yellow liquid

Safety:

Stereoselective preparation of methyl (Z)-cinnamates by Favorskii rearrangement: Stereoselective preparation of methyl (Z)-cinnamates by Favorskii rearrangement. Engler, Thomas A.; Falter, Wolfgang (Dep. Chem., Univ. Kansas, Lawrence, KS 66045, USA). Tetrahedron Lett.Several reagents such as 107468-13-3 is used here., 27(35), 4119-20 (English) 1986. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) 1,3-Dibromo-1-phenylacetones, readily prepd. by direct bromination of the parent phenylacetone, react with methanolic sodium methoxide to yield stereoselectively Me (Z)-cinnamates in good yield. E.g., 3-CF3C6H4CH2COMe in AcOH treated with Br gave 3-CF3C6H4CHBrCOCH2Br, which was debrominated by NaOMe in MeOH to give 79% (Z)- and (E)-3-CF3C6H4CH:CHCO2Me in ratio. .

Detail of "6097-32-1"