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6118-51-0

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Basic Information
CAS No.: 6118-51-0
Name: EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE
Article Data: 123
Molecular Structure:
Molecular Structure of 6118-51-0 (EXO-3,6-EPOXY-1,2,3,6-TETRAHYDROPHTHALIC ANHYDRIDE)
Formula: C8H6 O4
Molecular Weight: 166.133
Synonyms: 4,7-Epoxyisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydro-, (3aa,4b,7b,7aa)-; 7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, exo- (8CI);(exo,exo)-7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride;5,6-Dehydronorcantharidin; 7-Oxabicyclo[2.2.1]hept-5-ene-2,3-exo-dicarboxylicanhydride; NSC 144085; exo-3,6-Epoxy-1,2,3,6-tetrahydrophthalic acid anhydride;exo-3,6-Epoxy-1,2,3,6-tetrahydrophthalic anhydride;exo-7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid anhydride;exo-7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride;exo-cis-3,6-Endoxo-D4-tetrahydrophthalic anhydride
Density: 1.54g/cm3
Melting Point: 118oC
Boiling Point: 372°Cat760mmHg
Flash Point: 172.2°C
Solubility: Hydrolyzes in water.
Hazard Symbols: Xi
Risk Codes: R36/37/38;
Safety: 10355
PSA: 52.60000
LogP: -0.36060
Related products
Synthetic route
110-00-9

furan

108-31-6

maleic anhydride

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

Conditions
ConditionsYield
In neat (no solvent, solid phase) for 1h; Diels-Alder Cycloaddition; Milling;100%
In toluene at 110℃; for 24h; Diels-Alder Cycloaddition; Reflux; stereospecific reaction;100%
at 25℃; for 16h; Diels-Alder reaction;98%
110-00-9

furan

108-31-6

maleic anhydride

A

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

B

51112-81-3

endo, cis-7-oxabicyclo<2.2.1>hept-5-ene-2,3-dicarboxylic acid

Conditions
ConditionsYield
With trans-1,2-bis(4-pyridyl)ethylene In neat (no solvent, solid phase) for 25h; Milling;A 93%
B 7%
With trans-1,2-bis(4-pyridyl)ethylene In neat (no solvent, solid phase) for 25h; Milling; UV-irradiation;A 35%
B 65%
...Expand
110-00-9

furan

108-31-6

maleic anhydride

60-29-7

diethyl ether

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

Conditions
ConditionsYield
In diethyl ether at 38℃; for 1h;85.75%
...Expand
110-00-9

furan

108-31-6

maleic anhydride

A

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

B

6766-44-5

7-oxabicyclo<2.2.1>heptene-exo-2,3-dicarboxylic anhydride

Conditions
ConditionsYield
In acetone at 20℃; under 760 Torr; for 282h; Kinetics; Product distribution; effect of high pressure: different pressures and times; rate constants; 40 deg C, deuteroacetonitrile;
In acetone at 20℃; under 735059 Torr; Thermodynamic data; Kinetics; Rate constant; other pressure, ΔV(excit);
With K10 montmorillonite at 0℃; for 3h; Yield given; Yields of byproduct given. Title compound not separated from byproducts;
In ethyl acetate at 20℃; Kinetics; Diels-Alder reaction;
In ethyl acetate at 20℃; Diels-Alder reaction;
...Expand
110-00-9

furan

108-31-6

maleic anhydride

60-29-7

diethyl ether

A

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

B

7-oxa-norborn-5-ene-2endo,3endo-dicarboxylic acid-anhydride

7-oxa-norborn-5-ene-2endo,3endo-dicarboxylic acid-anhydride

...Expand
110-00-9

furan

108-31-6

maleic anhydride

7732-18-5

water

A

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

B

7-oxa-norborn-5-ene-2endo,3endo-dicarboxylic acid-anhydride

7-oxa-norborn-5-ene-2endo,3endo-dicarboxylic acid-anhydride

Conditions
ConditionsYield
Product distribution; Einfluss der Reaktionsdauer auf die Ausbeute;
...Expand
110-00-9

furan

108-31-6

maleic anhydride

A

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

B

110-16-7

maleic acid

Conditions
ConditionsYield
With water for 1h; Diels-Alder Cycloaddition; Inert atmosphere; Darkness;A 68 %Spectr.
B n/a
...Expand
110-00-9

furan

108-30-5

succinic acid anhydride

6118-51-0

exo-3,6-epoxy-1,2,3,6-tetrahydrophthalic anhydride

Conditions
ConditionsYield
In ethyl acetate at 20℃;
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    Bide Pharmatech Ltd., founded in 2007, focuses on the field of organic chemistry by providing organic reagents, functional materials, biochemical reagents and bulk drug intermediat

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  • 4-[(E)-2-(4-quinolinyl)ethenyl]benzene-1,3-diamine

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    Founded in 2011, Amadis Chemical Company Limited is an innovative manufacturer of chemical products and technical service providers. Our business includes sales, manufacture, and s

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    Hengxun pharmaceutical is a leading manufacturer and supplier of chemicals in China. We develop, produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best qua

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    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The laboratory covers 600 m2 and the pilot plant covers 2000 m2. Kingorgchem i

    Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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  • (3aR,4S,7R,7aS)-rel-3a,4,7,7a-Tetrahydro-4,7-epoxyisobenzofuran-1,3-dione

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    For quick quotation, please send us the inquiry include CAS#, Structure, Chemical Name, quantity, purity, as well as any additional specifications you require, we will try to get back to you within 24 hours. Our Services Besides manufacturing,

    Established in 2008, ENAO Chemical Co., Ltd is a professional supplier of fine chemicals and pharmaceutical raw materials in China, with factories and warehouses in GuangDong, Qing

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

    Chemical Technology Co.,LTD is a professional enterprise which engaged in pharmaceutical intermediates, material intermediates production research and development.Company foc

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  • exo-7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride,

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    6118-51-0

    exo-7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride,

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    At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

    Share Chemical Co., Ltd. is an innovative chemical producer engaged in the production of organic specialty chemicals, pharmaceuticals, and fine chemicals of high purity for product

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    China (Mainland)  |  Contact Details

    Business Type:Other

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    Address:Hang Xing Road

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  • 4,7-Epoxyisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydro-, (3aR,4S,7R,7aS)-rel-

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    4,7-Epoxyisobenzofuran-1,3-dione,3a,4,7,7a-tetrahydro-, (3aR,4S,7R,7aS)-rel-

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    United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

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