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| CAS No.: | 615-05-4 |
|---|---|
| Name: | 2,4-DIAMINOANISOLE |
| Article Data: | 35 |
| Molecular Structure: | |
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| Formula: | C7H10 N2 O |
| Molecular Weight: | 138.169 |
| Synonyms: | m-Phenylenediamine,4-methoxy- (6CI,7CI,8CI); 1,3-Diamino-4-methoxybenzene;2,4-Diamino-1-methoxybenzene; 2,4-Diaminoanisole; 2,4-Diaminophenyl methylether; 3-Amino-4-methoxyaniline; 4-Methoxy-1,3-benzenediamine;4-Methoxy-1,3-phenylenediamine; 4-Methoxy-m-phenylenediamine; C.I. 76050; C.I.Oxidation Base 12; Furro L; Pelagol DA; Pelagol Grey L; Pelagol L;p-Methoxy-m-phenylenediamine |
| EINECS: | 210-406-1 |
| Density: | 1.17g/cm3 |
| Melting Point: | 66-68oC |
| Boiling Point: | 286.3oC at 760 mmHg |
| Flash Point: | 148.5°C |
| Hazard Symbols: |
 
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| Risk Codes: | R45;R22;R51/53;R68 |
| Safety: | Confirmed carcinogen. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also 2,4-DIAMINOANISOLE DIHYDROCHLORIDE; 2,4-DIAMINOANISOLE SULFATE. |
| Transport Information: | UN 3077 |
| PSA: | 61.27000 |
| LogP: | 2.02200 |
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Chemistry
Molecular Formula: C7H10N2O 
Formula Weight: 138.17
IUPAC Name: 4-Methoxybenzene-1,3-diamine
Synonyms: 4-Methoxy-m-phenylenediamin ; 1,3-Benzenediamine,-methoxy- ; 2,4-Diaminoanisole base ; 2,4-Diamineanisole ; 4-Mmpd ; 4-Methoxy-3-phenylenediamine
Flash Point of 2,4-Diaminoanisole (615-05-4): 164.6 °C
Boiling Point: 305.9 °C at 760 mmHg
Density of 2,4-Diaminoanisole (615-05-4): 1.17 g/cm3
Vapour Pressure: 0.000798 mmHg at 25°C
Index of Refraction: 1.619
Appearance: 2,4-Diaminoanisole (615-05-4) is a colorless solid (needles).
Uses
2,4-Diaminoanisole (615-05-4) is primarily used (along with salts such as 2,4-DIAMINOANISOLE sulfate ) as a component of hair & fur dye formulations.
Toxicity Data With Reference
| 1. | skn-rbt 12,500 µg/24H MLD | FCTXAV Food and Cosmetics Toxicology. 15 (1977),607. | ||
| 2. | mma-sat 5 µg/plate | MUREAV Mutation Research. 79 (1980),289. | ||
| 3. | dnd-hmn:fbr 50 µmol/L | MUREAV Mutation Research. 127 (1984),107. | ||
| 4. | dnd-rat:lvr 500 µmol/L | CBINA8 Chemico-Biological Interactions. 31 (1980),35. | ||
| 5. | sce-mus-ipr 12 mg/kg | MUREAV Mutation Research. 108 (1983),225. | ||
| 6. | orl-rat LD50:460 mg/kg | FCTXAV Food and Cosmetics Toxicology. 15 (1977),607. | ||
| 7. | ipr-rat LD50:116 mg/kg | BCPCA6 Biochemical Pharmacology. 30 (1981),2715. |
Consensus Reports
IARC Cancer Review: Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 27 (1982),p. 103.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.
Safety Profile
Confirmed carcinogen. Poison by intraperitoneal route. Moderately toxic by ingestion. Experimental reproductive effects. Human mutation data reported. A skin irritant. When heated to decomposition it emits toxic fumes of NOx. See also 2,4-DIAMINOANISOLE DIHYDROCHLORIDE; 2,4-DIAMINOANISOLE SULFATE.
Hazard Codes : T: Toxic .gif){kind=small}
N: Dangerous for the environment .gif){kind=small}
Risk Statements : 45: May cause cancer
22: Harmful if swallowed
51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68: Possible risk of irreversible effects
Safety Statements : 53: Avoid exposure - obtain special instruction before use
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR : 2811
HazardClass : 6.1(b)
PackingGroup : III
Standards and Recommendations
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (2,4-diaminoanisole) Reduce to lowest feasible level
Specification
2,4-Diaminoanisole (615-05-4) is a colorless solid and mainly used as a component of hair & fur dye formulations. It is incompatible with strong oxidizers.