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6153-56-6

Basic Information
CAS No.: 6153-56-6
Name: Oxalic acid dihydrate
Article Data: 3
Molecular Structure:
Molecular Structure of 6153-56-6 (Oxalic acid dihydrate)
Formula: C2H6O6
Molecular Weight: 126.066
Synonyms: Ethanedioicacid, dihydrate (9CI);Oxalic acid, dihydrate (8CI);
EINECS: 205-634-3
Density: 1.65 g/cm3
Melting Point: 104-106 °C(lit.)
Boiling Point: 108-109°C
Flash Point: 157°C
Solubility: 138 g/L (20 °C) in water
Appearance: white crystals
Hazard Symbols: HarmfulXn, CorrosiveC
Risk Codes: 21/22
Safety: 24/25
Transport Information: UN 3261 8/PG 3
PSA: 93.06000
LogP: -0.97300
Synthetic route
62-76-0

sodium oxalate

6153-56-6

oxalic acid dihydrate

Conditions
ConditionsYield
With hydrogenchloride; water at 80℃; for 1h; Product distribution / selectivity;56%
cis-{Pt(PMe3)2(OH)2}*nH2O (n=2-3)

cis-{Pt(PMe3)2(OH)2}*nH2O (n=2-3)

6153-56-6

oxalic acid dihydrate

94929-01-8

{Pt(PMe3)2(ox)}

Conditions
ConditionsYield
In not given100%
553-26-4

4,4'-bipyridine

iron(II) bromide hexahydrate

6153-56-6

oxalic acid dihydrate

226401-77-0

(2).infin.[Fe(oxalate)(4,4'-bipyridine)]

Conditions
ConditionsYield
In water byproducts: HBr, H2O; molar ratio Fe:oxalate:bipy:H2O=1:1:1:444, digestion bomb, 170°C,7 d; washing (water, Me2CO), drying in air;99%
553-26-4

4,4'-bipyridine

cobalt(II) bromide hexahydrate

6153-56-6

oxalic acid dihydrate

226401-78-1

(2).infin.[Co(oxalate)(4,4'-bipyridine)]

Conditions
ConditionsYield
In water byproducts: HBr, H2O; molar ratio Co:oxalate:bipy:H2O=1:1:1:444, digestion bomb, 170°C,7 d;99%
7209-38-3

1,4-bis(3-aminopropyl)piperazine

iron(III) chloride hexahydrate

86119-84-8, 7664-38-2

phosphoric acid

6153-56-6

oxalic acid dihydrate

H3NC3H6NHC4H8NHC3H6NH3(4+)*3Fe(3+)*2C2O4(2-)*3HPO4(2-)*PO4(3-)*100H2O=C10H28N4[Fe3(C2O4)2(HPO4)3(PO4)(H2O)]*99H2O

Conditions
ConditionsYield
In water High Pressure; mixt. of FeCl3*6H2O, H2C2O4*2H2O, H3PO4, 1,4-bis(3-aminopropyl)piperazine, and water (pH 4.6) heated at 120°C for 3 d in Teflon-lined stainless-steel Parr acid digestion bomb, slow cooling at 5°C/h to room temp.;99%
65-23-6

5-hydroxy-6-methyl-3,4-pyridinedimethanol

11113-50-1

boric acid

6153-56-6

oxalic acid dihydrate

[B(oxalato)(pyridoxine(-H))]

Conditions
ConditionsYield
In toluene byproducts: H2O; boric acid, pyridoxine and oxalic acid*2H2O in 1:1:1 molar ratio refluxed in toluene during 6 h under continuous sepn. of react. water; filtered; dried at 120°C; elem. anal.;99%
6153-56-6

oxalic acid dihydrate

34851-41-7

tetrabutyl ammonium methoxide

33081-83-3

bis(tetrabutylammonium)oxalate

Conditions
ConditionsYield
In methanol for 4h;98%

indium(III) oxide

86119-84-8, 7664-38-2

phosphoric acid

6153-56-6

oxalic acid dihydrate

110-60-1

1,4-diaminobutane

(1,4-diaminobutane(+2H))0.5*In(HPO4)(H2PO4)(oxalate)0.5

Conditions
ConditionsYield
In water at 150℃; for 168h; Autoclave;95%
6153-56-6

oxalic acid dihydrate

75719-86-7

2,3,4,6-tetra-O-benzyl-1-O-(N-benzyloxycarbonylglycylglycylglycyl)-α-D-glucopyranose

75719-99-2

1-O-(glycylglycylglycyl)-α-D-glucopyranose mono-oxalate

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In 2-methoxy-ethanol; acetic acid for 24h;92%
6153-56-6

oxalic acid dihydrate

75719-88-9

2,3,4,6-tetra-O-benzyl-1-O-(N-benzyloxycarbonyl-L-phenylalanylglycylglycyl)-β-D-glucopyranose

75720-06-8

1-O-(L-phenylalanylglycylglycyl)-β-D-glucopyranose mono-oxalate

Conditions
ConditionsYield
With hydrogen; palladium on activated charcoal In 2-methoxy-ethanol; acetic acid for 20h;92%
Raw Materials
62-76-0
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    Chemical Name: Oxalic Acid Synonym: Oxalic acid dehydrate; Ethanedioic Acid; Oxalic acid anhydrous; Anhydrous Oxalic Acid. Ethanedionic acid; Oxalic acid anhydrous; Refined Oxalic Acid; Anhydrous Oxalic Acid; ethanedioic acid; ethanedioate CAS NO.

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Chemistry

Molecular structure of Ethanedioic acid, dihydrate (CAS NO.6153-56-6) is:

Product Name: Ethanedioic acid, dihydrate
CAS Registry Number: 6153-56-6
IUPAC Name: oxalic acid dihydrate
Molecular Weight: 126.06544 [g/mol]
Molecular Formula: C2H6O6
H-Bond Donor: 4
H-Bond Acceptor: 6 
EINECS: 205-634-3
Melting Point: 104-106 °C(lit.)
Water Solubility: 138 g/L (20 °C)
Sublimation: 157 °C 
Density: 1.65 g/cm3
Flash Point: 188.8 °C
Enthalpy of Vaporization: 67.15 kJ/mol
Boiling Point: 365.1 °C at 760 mmHg
Vapour Pressure: 2.51E-06 mmHg at 25°C
Stability: Stable. Incompatible with bases, acid chlorides, steel, silver, silver compounds, moisture. Avoid contact with metals. 
Product Categories: Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Uses

 Ethanedioic acid, dihydrate (CAS NO.6153-56-6) can be used in wood bleaching and brightener, stain remover.

Safety Profile

Safty information about Ethanedioic acid, dihydrate (CAS NO.6153-56-6) is:
Hazard Codes: HarmfulXn, CorrosiveC
Risk Statements: 21/22 
R21/22:Harmful in contact with skin and if swallowed.
Safety Statements: 24/25 
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 3261 8/PG 3
WGK Germany: 1
RTECS: RO2450000
HazardClass: 8
PackingGroup: III
HS Code: 29171100

Specification

 Ethanedioic acid, dihydrate , its cas register number is 6153-56-6. It also can be called Dicarbolic acid dihydrate ; Ethanedioic acid dihydrate .It is a white crystals.