CAS No.6160-65-2,1,1'-ThiocarbonylDiimidazole Suppliers,MSDS download

Products Categories

Pharmaceutical (120)
Organic Chemicals (37)
Others (35)
Reagent (7)
Materials (1)
Catalyst and Auxiliary (1)

Basic Information

Molecular Structure:
CAS No.:	6160-65-2
Name:	1,1'-ThiocarbonylDiimidazole
Article Data:	10

Formula:	C₉H₁₆N₂O
Molecular Weight:	178.217
Synonyms:	1H-Imidazole,1,1'-carbonothioylbis- (9CI);Imidazole, 1,1'-(thiocarbonyl)di- (7CI,8CI);1,1'-(Thiocarbonyl)bis[imidazole];1,1'-(Thiocarbonyl)diimidazole;1-(1H-Imidazol-1-ylcarbothioyl)-1H-imidazole;Diimidazol-1-ylmethanthione;N,N'-Thiocarbonyldiimidazole;NSC 141692;Thiocarbonylbisimidazole;1,1'-Thiocarbonylbis(imidazole);1H-Imidazole, 1,1'-carbonothioylbis-;1,1'-Thiocarbonyldiimidazole;
EINECS:	228-183-4
Density:	1.39 g/cm³
Melting Point:	98-102 °C(lit.)
Boiling Point:	390.8 °C at 760 mmHg
Flash Point:	190.1 °C
Solubility:	decomposes
Appearance:	yellow powder
Hazard Symbols:	Xi
Risk Codes:	22-34
Safety:	22-24/25
PSA:	67.73000
LogP:	0.76090

Synthetic route

: 463-71-8
thiophosgene

: 18156-74-6
1-(Trimethylsilyl)imidazole

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

Conditions

Conditions	Yield
In tetrachloromethane	94%
In benzene a) 0 deg C, 30 min, b) RT, 30 min;

: 288-32-4
1H-imidazole

: 463-71-8
thiophosgene

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 0.5h;

: 69530-93-4
5'-(O-tert-butyldimethylsilyl)adenosine

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 119818-50-7
D-2',3'-O-thiocarbonylene-5'-O-tert-butyldimethylsilyl adenosine

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 3h; Inert atmosphere; Reflux;	100%
In N,N-dimethyl-formamide at 80℃; for 1h;	73.5%

: cis-3,4-bis<(tert-butyldimethylsilyl)ethynyl>-3-cyclobutene-1,2-diol

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: cis-1,2-bis<(tert-butyldimethylsilyl)ethynyl)>-3,4-(thiocarbonyldioxy)-1-cyclobutene

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 0.5h;	100%

: 86263-38-9
Methyl 3,6-Di-O-benzoyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 157553-82-7
C33H27N3O9S

Conditions

Conditions	Yield
In 1,2-dimethoxyethane Heating;	100%

: 78064-61-6
1-Methyl-5'-O-tritylpseudouridine

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 78064-62-7
1-Methyl-2',3'-O-(thionocarbonyl)-5'-O-tritylpseudouridine

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 10h; Ambient temperature;	100%

: 94707-76-3
((1R,6R,7S,8S,9R)-9-Hydroxy-7-trimethylsilanyloxy-2-aza-tricyclo[5.3.1.02,6]undec-8-yl)-acetic acid methyl ester

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 94731-59-6
[(1R,6R,7S,8S,9R)-9-(Imidazole-1-carbothioyloxy)-7-trimethylsilanyloxy-2-aza-tricyclo[5.3.1.02,6]undec-8-yl]-acetic acid methyl ester

Conditions

Conditions	Yield
In tetrahydrofuran at 25℃; for 4h;	100%

: 100021-22-5
(+/-)-(1α,2β,3α,4α,5β)-2-(6-amino-9H-purin-9-yl)-3,4-(dimethylmethylenedioxy)-5-<(phenylmethoxy)methyl>-1-cyclopentanol

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 100021-23-6
(+/-)-(1β,2α,3β,4α,5α)-1-(6-amino-9H-purin-9-yl)-4,5-(dimethylmethylenedioxy)-2-<(1-imidazolylthiocarbonyl)oxy>-3-<(phenylmethoxy)methyl>cyclopentane

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 70℃; for 2h;	100%

: 7304-32-7
2-fluoro-5-nitrobenzoic acid

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 1003-03-8
Cyclopentamine

4-aminobenzoic acid bound to solid support: 4-aminobenzoic acid bound to solid support

: 4-(1-cyclopentyl-6-nitro-4-oxo-2-thioxo-1,4-dihydro-2H-quinazolin-3-yl)-benzoic acid

Conditions

Conditions	Yield
Multistep reaction;	100%

...Expand

: 6160-65-2
1,1'-Thiocarbonyldiimidazole

: 248256-46-4
(1S,2S,3R)-1-hydroxymethyl-2-phenyl-3-(phenylthiomethyl)cyclopropane

: 392656-00-7
Imidazole-1-carbothioic acid O-((1S,2S,3R)-2-phenyl-3-phenylsulfanylmethyl-cyclopropylmethyl) ester

Conditions

Conditions	Yield
In toluene at 50℃; for 1.5h;	100%

Raw Materials

18156-74-6

288-32-4

463-71-8

Downstream Products

621-01-2

Total:173 Page 1 of 5 1 2 3 4 5 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 6160-65-2

Specification

The 1,1'-Thiocarbonyldiimidazole with CAS registry number of 6160-65-2 is also called N,N'-Thiocarbonyldiimidazole. The IUPAC name is di-1H-imidazol-1-ylmethanethione. Its EINECS registry number is 228-183-4. In addition, the formula is C₇H₆N₄S and the molecular weight is 178.21. It is belongs to the classes of Imidazoles; Carbonyldiimidazole Derivatives; Coupling; Synthetic Reagents; Carbonyldiimidazole DerivativesBuilding Blocks; Heterocyclic Building Blocks. It can be prepared by phosgene sulfur and 1-(Trimethylsilyl) imidazole. What's more, it is a kind of yellow powder. It is stable and incompatible with strong oxidizing agents and strong acids. But it is sensitive to air and moisture.

Physical properties about 1,1'-Thiocarbonyldiimidazole are: (1)ACD/LogP: -0.02; (2)ACD/LogD (pH 5.5): -0.02; (3)ACD/LogD (pH 7.4): -0.02; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 23.23; (7)ACD/KOC (pH 7.4): 23.23; (8)#H bond acceptors: 4; (9)Index of Refraction: 1.73; (10)Molar Refractivity: 51.05 cm³; (11)Molar Volume: 127.857 cm³; (12)Polarizability: 20.238 10-24cm³; (13)Surface Tension: 57.1759986877441 dyne/cm; (14)Density: 1.394 g/cm³; (15)Flash Point: 190.141 °C; (16)Enthalpy of Vaporization: 64.031 kJ/mol; (17)Boiling Point: 390.786 °C at 760 mmHg

Uses of 1,1'-Thiocarbonyldiimidazole: it can react with 4,4'-Dimethoxy-benzhydrol to get 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole. This reaction will need reagent tetrahydrofuran. The reaction time is 6 hours by heating and the yield is about 75%.

1,1'-ThiocarbonylDiimidazole can react with 4,4'-Dimethoxy-benzhydrol to get 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole

When you are using this chemical, please be cautious about it as the following:
You should avoid contact with skin and eyes and should not breathe dust.

You can still convert the following datas into molecular structure:
(1)SMILES: S=C(n1cncc1)n2ccnc2
(2)InChI: InChI=1/C7H6N4S/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H
(3)InChIKey: RAFNCPHFRHZCPS-UHFFFAOYAV