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617-65-2

Basic Information
CAS No.: 617-65-2
Name: DL-Glutamic acid
Article Data: 285
Molecular Structure:
Molecular Structure of 617-65-2 (DL-Glutamic acid)
Formula: C5H9NO4
Molecular Weight: 147.131
Synonyms: DL-Glutamicacid;Glutamic acid, DL- (8CI);glutamic acid;DL-Glu;NSC 206301;NSC 9967;(±)-Glutamic Acid;4-Amino-1,5-pentandioic acid;α-Aminoglutaric Acid;aminoglutaric acid;
EINECS: 210-522-2
Density: 1.41 g/cm3
Melting Point: 194 °C
Boiling Point: 333.783 °C at 760 mmHg
Flash Point: 155.667 °C
Appearance: White crystaline or crystaline powder
PSA: 100.62000
LogP: -0.03660
Synthetic route
1199-01-5

2-phenylazlactone

292638-85-8

acrylic acid methyl ester

617-65-2

Glutamic acid

Conditions
ConditionsYield
Stage #1: 2-phenylazlactone; acrylic acid methyl ester With cerium(III) chloride; sodium iodide In 1,4-dioxane; water at 20℃; for 9h; Michael addition;
Stage #2: With sulfuric acid In water for 0.75h; Heating; Further stages.;
83%
328-50-7

α-ketoglutaric acid

A

617-65-2

Glutamic acid

B

2889-31-8

2-hydroxyglutaric acid

Conditions
ConditionsYield
With [Ir(III)Cp*(bpy)(OH2)](SO4); ammonium formate In water at 80℃; for 6h; pH=6.5;A 70%
B 19 % Spectr.
64-18-6

formic acid

56512-51-7

2-amino-3-butenoic acid

A

617-65-2

Glutamic acid

B

6667-60-3

2-amino-3-methylbutanedioic acid

Conditions
ConditionsYield
With hydrogen; oxygen In water for 2.5h;A 3%
B 40%
328-50-7

α-ketoglutaric acid

617-65-2

Glutamic acid

Conditions
ConditionsYield
With iron sulfide; ammonium carbonate In water at 100℃; for 144h;15%
With water; ammonium chloride; zinc sulfide; sodium hydroxide; sodium sulfite In water at 30℃; for 10h; pH=9; Inert atmosphere;7.4%
With ethylenediaminetetraacetic acid; cetyltrimethylammonium chloride; N-Phenylglycine; DPL at 30℃; Product distribution; potassium phosphate buffer (pH 7.8); variation of incubation time, pH and DPL concentration;
4344-84-7, 21461-84-7, 53558-93-3, 83829-70-3

5-oxo-tetrahydro-furan-2-carboxylic acid

617-65-2

Glutamic acid

Conditions
ConditionsYield
beim aufeinanderfolgenden Behandeln mit wss. NH3 <250grad> und mit wss. HCl;
Multi-step reaction with 2 steps
1: hydrogen bromide
View Scheme
64-17-5

ethanol

33646-32-1

methyl 2-benzamido-3-chloro-propanoate

996-82-7

sodium diethylmalonate

617-65-2

Glutamic acid

Conditions
ConditionsYield
Hydrolyse des Reaktionsprodukts mit Salzsaeure; N-benzoyl-β-chloro-methyl ester;
56-85-9

L-glutamine

617-65-2

Glutamic acid

6893-26-1

D-Glutamic acid

617-65-2

Glutamic acid

Conditions
ConditionsYield
With barium dihydroxide at 160℃;
With barium dihydroxide; water at 160 - 170℃;
6893-26-1

D-Glutamic acid

A

617-65-2

Glutamic acid

B

149-87-1

Pyroglutamic acid

Conditions
ConditionsYield
With barium dihydroxide at 160 - 170℃; unter Druck;
56-86-0

L-glutamic acid

617-65-2

Glutamic acid

Conditions
ConditionsYield
With hydrogenchloride at 160 - 170℃;
With barium dihydroxide; water
at 220℃; Kochen der gebildeten (+-)-5-Oxo-pyrrolidin-carbonsaeure-(2) mit 6n-HCl;
With hydrogenchloride; ethanethiol at 110℃; Rate constant; various times;
With mercaptoethyl alcohol; Tris-HCl buffer; Chitopearl immobilized glutamate racemase In water at 40℃; pH=8; Racemization;
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    Product Name: DL-Glutamic acid Synonyms: (R,S)-2-Amino-pentanedioicacid;DL-Glu;NSC 206301;NSC 9967;DL-Glu-OH;DL-Glutamic Acid;dl-glutamic;dl-glutamicaci CAS: 617-65-2 MF: C5H9NO4 MW: 147.13 EINECS: 210-522-2 Product Categories: alpha-Amino Ac

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    Name:DL-Glutamic acid Type: Biological products CAS:617-65-2 Purity:98% Appearance:White powder Storage:Sealed storage Packing Specification:1kg, 5kg, 10kg,25kg Molecular Formula:C5H9NO4 Molecular Weight:147.13 Application:Biological industry

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Reported in EPA TSCA Inventory.

Specification

The Glutamicacid, with the CAS registry number 617-65-2 and EINECS registry number 210-522-2, has the IUPAC name of 2-aminopentanedioic acid, and it is also known as glutamic acid. It belongs to the following product categories: alpha-Amino Acids; Amino Acids; Biochemistry. And the molecular formula of the chemical is C5H9NO4. What's more, it is always used in the industries of food, biochemistry and ferment.

The Glutamicacid is also abbreviated as Glu or E which is one of the 20 proteinogenic amino acids. It is an important neurotransmitter that plays a key role in long-term potentiation and is important for learning and memory. It occur naturally in many foods, and it is a non-essential amino acid.

The characteristics of Glutamicacid are as followings: (1)# of Rule of 5 Violations: 0; (2)ACD/BCF (pH 5.5): 1; (3)ACD/BCF (pH 7.4): 1; (4)ACD/KOC (pH 5.5): 1; (5)ACD/KOC (pH 7.4): 1; (6)#H bond acceptors: 5; (7)#H bond donors: 4; (8)#Freely Rotating Bonds: 5; (9)Polar Surface Area: 100.62 Å2; (10)Index of Refraction: 1.522; (11)Molar Refractivity: 31.836 cm3; (12)Molar Volume: 104.375 cm3; (13)Polarizability: 12.621×10-24cm3; (14)Surface Tension: 69.243 dyne/cm; (15)Density: 1.41 g/cm3; (16)Flash Point: 155.667 °C; (17)Enthalpy of Vaporization: 63.385 kJ/mol; (18)Boiling Point: 333.783 °C at 760 mmHg; (19)Vapour Pressure: 0 mmHg at 25°C. 

Uses of Glutamicacid: It can react with benzenesulfonyl chloride to produce N-benzenesulfonyl-glutamic acid. And the yield is about 92%.  

You can still convert the following datas into molecular structure:
(1)SMILES: C(CC(=O)O)C(C(=O)O)N
(2)InChI: InChI=1/C5H9NO4/c6-3(5(9)10)1-2-4(7)8/h3H,1-2,6H2,(H,7,8)(H,9,10)
(3)InChIKey: WHUUTDBJXJRKMK-UHFFFAOYAD

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
human TDLo oral 71mg/kg (71mg/kg) BEHAVIORAL: HEADACHE Science. Vol. 163, Pg. 826, 1969.