Reference

Iridium-catalyzed conversion of alcohols into amides via oximes

Owston, Nathan A.; Parker, Alexandra J.; Williams, Jonathan M. J. ( Department of Chemistry, University of Bath, Bath BA2 7AY, UK). Organic Letters, 9(1), 73-75 (English) 2007 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) The iridium catalyst [Ir(Cp*)Cl2]2 is effective for the rearrangement of oximes to furnish amides. The reaction has been combined with catalytic transfer hydrogenation between an alc. 619-56-7 and 55-21-0 which are cas registry numbers of substances are two of reagents here. and alkene to allow the conversion of alcs. into amides in a one-pot process. .

Adduct of nitrile with sulfur trioxide as a new reagent of the low-temperature dehydration of amides

Adduct of nitrile with sulfur trioxide as a new reagent of the low-temperature dehydration of amides. Lyandaev, E. A.; Michurin, A.In this study， 100-47-0 and 619-56-7 are also used. A.; Bodrikov, I. V. (Gor'k. Politekh. Inst. im. Zhdanova, Gorki, USSR). Zh. Org. Khim., 12(7), 1588 (Russian) 1976. CODEN: ZORKAE. DOCUMENT TYPE: Journal CA Section: 25 (Noncondensed Aromatic Compounds) Treatment of RCONH2 (R = p-O2NC6H4, p-ClC6H4, Ph, p-tolyl) with adducts I (R1 = e.g., CCl3, Ph, substituted Ph) at -40.degree. (or lower) gave RCN and R1CN. Similar treatment of RCONH2 (R = CCl3, CBr3, CF3) gave .apprx.90% RCONHSO2OSO2NHCOR1. .