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62-76-0

Basic Information
CAS No.: 62-76-0
Name: Sodium oxalate
Article Data: 167
Molecular Structure:
Molecular Structure of 62-76-0 (Sodium oxalate)
Formula: C2Na2O4
Molecular Weight: 133.999
Synonyms: Ethanedioicacid, disodium salt (9CI);Oxalic acid, disodium salt (8CI);Sodium oxalate(6CI,7CI);CSN 1;Disodium oxalate;Ethanedioic acid,sodium salt (1:2);
EINECS: 200-550-3
Density: 2.34 g/cm3
Melting Point: 250-270 °C
Boiling Point: 365.1 °C at 760 mmHg
Flash Point: 188.8 °C
Solubility: 37 g/L (20 °C) in water
Appearance: white crystalline powder
Hazard Symbols: HarmfulXn
Risk Codes: 21/22-34
Safety: 24/25-45-36/37/39-26-36
Transport Information: UN 3282
PSA: 80.26000
LogP: -3.51380
Synthetic route
141-53-7

sodium formate

62-76-0

sodium oxalate

Conditions
ConditionsYield
With sodium hydride at 390℃; for 0.166667h; Reagent/catalyst; Time; Inert atmosphere; Glovebox; Calcination;99%
sodium hydroxide at 340 °C in the presence of NaOH;;94.2%
sodium hydroxide at 340 °C in the presence of NaOH;;94.2%
124-38-9

carbon dioxide

C45H63Cu3N6S(1-)*C10H20NaO5(1+)

A

C45H63Cu3N6S

B

62-76-0

sodium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior;A 95%
B n/a
124-38-9

carbon dioxide

C45H63Cu3N6Se(1-)*C10H20NaO5(1+)

A

C45H63Cu3N6Se

B

62-76-0

sodium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior;A n/a
B 95%
124-38-9

carbon dioxide

C45H63Cu3N6S(1-)*Na(1+)*3C4H8O

A

C45H63Cu3N6S

B

62-76-0

sodium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior;A 95%
B n/a
124-38-9

carbon dioxide

C45H63Cu3N6Se(1-)*Na(1+)*3C4H8O

A

C45H63Cu3N6Se

B

62-76-0

sodium oxalate

Conditions
ConditionsYield
In benzene-d6 at -80℃; for 0.5h; Catalytic behavior;A n/a
B 95%
141-53-7

sodium formate

1310-73-2

sodium hydroxide

62-76-0

sodium oxalate

Conditions
ConditionsYield
In neat (no solvent) passing a vigorous stream of high purity H2 through melting NaHCO2 containing 3% NaOH at 260-320°C for 1-1.5h; solidification;;93%
In neat (no solvent) passing a vigorous stream of high purity H2 through melting NaHCO2 containing 3% NaOH at 260-320°C for 1-1.5h; solidification;;93%
141-53-7

sodium formate

A

62-76-0

sodium oxalate

B

497-19-8

sodium carbonate

Conditions
ConditionsYield
sodium hydroxide In solid byproducts: H2; with NaOH (1:0.05) in N2 atmosphere, the heating rate 6 deg/min;A 92%
B n/a
In solid thermal decomposition of sodium formate in H2 atmosphere (TG at 435 :degree.C, the heating rate 6 deg/min;A 35%
B n/a
In solid thermal decomposition of sodium formate in CO atmosphere (TG at438 °C), the heating rate 6 deg/min;A 34%
B n/a
16940-66-2

sodium tetrahydroborate

141-53-7

sodium formate

A

62-76-0

sodium oxalate

B

497-19-8

sodium carbonate

Conditions
ConditionsYield
In solid reaction of sodium formate with NaBH4 (1:0.05) in N2 atmosphere, the heating rate 6 deg/min;A 88%
B n/a
In solid reaction of sodium formate with NaBH4 (1:1) in N2 atmosphere, the heating rate 6 deg/min;A 0%
B n/a

ammonium oxalate

7647-14-5

sodium chloride

62-76-0

sodium oxalate

Conditions
ConditionsYield
In water at 100°C; filtration of boiling soln.; pptn.;; pure product on washing with boiling H2O; product obtained by pptn. during cooling the filtrate to 20°C contains (NH4)2C2O4;;81.2%
In water at 100°C; filtration of boiling soln.; pptn.;; pure product on washing with boiling H2O; product obtained by pptn. during cooling the filtrate to 20°C contains (NH4)2C2O4;;81.2%
89-65-6

isoascorbic acid

A

62-76-0

sodium oxalate

B

15667-21-7

D-erythronolactone

Conditions
ConditionsYield
With dihydrogen peroxide; sodium carbonate 1) 17 deg C, 5 min; 2) 40 deg C, 30 min;A n/a
B 67.5%
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    Synonyms: Disodium OxalateChemical Name: Sodium Oxalate CAS No.: 62-76-0 Relative molecular mass:134.00 Molecular Formula: Na2C2O4 Disodium oxalate CAS NO.62-76-0 M.F:C2Na2O4 MW:134 Appearance:off-white powder Disodium oxalate

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Chemistry

The Molecular Structure of Sodium Oxalate (CAS NO.62-76-0):

 

Empirical Formula: C2Na2O4
Molecular Weight: 133.9985 
IUPAC Name: disodium oxalate  
Appearance: white crystalline powder
Product Categories: By Reference Material;Reference Material Potassium iodateVolumetric Solutions;S - Z;S - ZTitration;Salt Solutions;Solution containers (VOLPAC);Volumetric Solutions
Nominal Mass: 134 Da
Average Mass: 133.9985 Da
Monoisotopic Mass: 133.959198 Da 
Flash Point: 188.8 °C
Enthalpy of Vaporization: 67.15 kJ/mol
Boiling Point: 365.1 °C at 760 mmHg
Vapour Pressure: 2.51E-06 mmHg at 25°C 
Storage temp: Store at RT.
Water Solubility: 37 g/L (20 ºC)
Sensitive: Hygroscopic 
Stability: Stability Stable; hygroscopic. Incompatible with strong oxidizing agents.
InChI
InChI=1/C2H2O4.2Na/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);;/q;2*+1/p-2
Smiles
C(C(=O)[O-])(=O)[O-].[Na+].[Na+] 
Synonyms: Ethanedioic acid, disodium salt ; EINECS 200-550-3 ; Natriumoxalat ; Natriumoxalat [German] ; Oxalic acid, disodium salt ; Stavelan sodny ; Stavelan sodny [Czech] ; UNII-7U0V68LT9X ; Ethanedioic acid, sodium salt (1:2) ; Oxalic acid, disodium salt (8CI)  

Uses

 Sodium Oxalate (CAS NO.62-76-0) may be used as a primary standard agent for standardizing potassium permanganate (KMnO4) solutions, it's also used as a  finishing agent of both fabric and tanning.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LDLo subcutaneous 100mg/kg (100mg/kg)   "Beitrage zur Toxikologie des Athylenoxyds und der Glykole, Dissertation," Hofbauer, A., Pharmakologischen Institut der Universitat Wurzburg, Fed. Rep. Ger., 1933Vol. -, Pg. -, 1933.
human LDLo intravenous 17mg/kg (17mg/kg) BEHAVIORAL: COMA

CARDIAC: ARRHYTHMIAS (INCLUDING CHANGES IN CONDUCTION)

KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED
Medecine Legale et Dommage Corporel. Vol. 4, Pg. 178, 1971.
mouse LD50 intraperitoneal 155mg/kg (155mg/kg)   Acta Biologica et Medica Germanica. Vol. 6, Pg. 498, 1961.
mouse LD50 oral 5094mg/kg (5094mg/kg)   EHP, Environmental Health Perspectives. Vol. 106(Suppl,
mouse LDLo subcutaneous 100mg/kg (100mg/kg)   Archives Internationales de Pharmacodynamie et de Therapie. Vol. 8, Pg. 255, 1901.
rat LD50 oral 11160mg/kg (11160mg/kg)   EHP, Environmental Health Perspectives. Vol. 106(Suppl,

Safety Profile

Hazard Codes: HarmfulXn
Risk Statements: 21/22-34 
R20/21: Harmful by inhalation and in contact with skin
R34: Causes burns
Safety Statements: 24/25-45-36/37/39-26-36 
S24/25: Avoid contact with skin and eyes
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36: Wear suitable protective clothing
RIDADR: 3282
WGK Germany: 1
RTECS: KI1750000
TSCA: No
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 2971100

Specification

 Sodium oxalate is a sodium salt of oxalic acid which can act as a reducing agent. Disodium oxalate is frequently referred to as sodium oxalate . The polyatomic ion of oxalate has a negative two charge, there can be no other compound consisting solely of sodium and oxalate other than disodium oxalate . Therefore, the prefix "di" is often dropped.