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CAS No.6207-45-0 α-D-Glucopyranoside, 2-propen-1-yl2,3,4,6-tetrakis-O-(phenylmethyl)-

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Supplier:Carbosynth Limited [ United Kingdom]

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Reference

Towards glycosyl inositol mimics: stereoselective synthesis of C-a-glucosyl-inositol derivatives via Diels-Alder reactions
Towards glycosyl inositol mimics: stereoselective synthesis of C-a-glucosyl-inositol derivatives via Diels-Alder reactions. Jacques, Francis; Dupeyroux, Herve; Joly, Jean-Pierre; Chapleur, Yves (Lab. Methodolotie, Univ.Chemicals with cas numbers 6207-45-0 and 186651-21-8 also play role. Henri Poincare, Vandoeuvre F-54506, Fr.). Tetrahedron Letters, 38(1), 73-76 (English) 1997 Elsevier. CODEN: TELEAY. ISSN: 0040-4039. DOCUMENT TYPE: Journal CA Section: 33 (Carbohydrates) The C-glucopyranosidyl-linked acrylate pentafluorophenyl ester I (Bn = benzyl, Pfp = pentafluorophenyl) is an efficient chiral dienophile for asym. Diels-Alder reactions with E-1-acetoxy-1,3-butadiene to give C-a-glucosylcyclitol derivs., e.g. II, with excellent regioselectivity but fair diastereoselectivity. .
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