Detail of "6221-95-0"

CAS Number:
6221-95-0
Name:
1-Tetradecanol,1-propanoate
Molecular Structure:
Formula:
C₁₇H₃₄O₂
Molecular Weight:
270.45
Synonyms:
1-Tetradecanol,propanoate (9CI);1-Tetradecanol, propionate (7CI,8CI);Myristyl propionate;Tetradecyl propanoate;Tetradecyl propionate;n-Tetradecyl propionate;
EINECS:
228-300-9
Density:
0.865 g/cm³
Boiling Point:
319.9 °C at 760 mmHg
Flash Point:
148.8 °C

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Conversion of olefins to esters: Conversion of olefins to esters.Some chemicals with cas registry numbers like 6221-95-0 and 7789-67-5 are also used. Schmerling, Louis (UOP Inc., USA). U.S. US 4009203 22 Feb 1977, 5 pp. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C07C067-04. NCL: 260497000R. APPLICATION: US 75-544595 27 Jan 1975. DOCUMENT TYPE: Patent CA Section: 23 (Aliphatic Compounds) Section cross-reference(s): 24 Olefins were converted to esters by treating the olefins with carboxylic acids in the presence of a catalyst comprising the reaction product of Sn halide with a carboxylic acid. Thus, EtCO2H was heated with SnCl4 at 85-140.degree. for 6 h and the resultant EtCO2SnCl3 was used as a catalyst for the reaction of EtCO2H with 7-tetradecene at elevated temp. and pressure to give a product contg. tetradecyl propionate and tetradecyl chloride; the ratio of ester to chloride from this reaction was higher than from the reaction catalyzed by SnCl4 alone. Four more esters including cyclohexyl propionate were similarly prepd. .