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634-93-5

Basic Information
CAS No.: 634-93-5
Name: 2,4,6-Trichloroaniline
Article Data: 72
Molecular Structure:
Molecular Structure of 634-93-5 (2,4,6-Trichloroaniline)
Formula: C6H4Cl3N
Molecular Weight: 196.463
Synonyms: Aniline,2,4,6-trichloro- (6CI,7CI,8CI);2,4,6-Trichloraniline;2,4,6-Trichlorobenzenamine;2,4,6-Trichlorophenylamine;
EINECS: 211-219-8
Density: 1.54 g/cm3
Melting Point: 75 °C
Boiling Point: 258.4 °C at 760 mmHg
Flash Point: 110.1 °C
Solubility: <0.1 g/100 mL at 21.5℃
Appearance: White Crystal
Hazard Symbols: ToxicT; DangerousN
Risk Codes: 23/24/25-33-50/53
Safety: 28-36/37-45-60-61
Transport Information: UN 2811 6.1/PG 2
PSA: 26.02000
LogP: 3.81020
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  • High purity 2,4,6-Trichlorobenzenamine

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Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The IUPAC name of this chemical is 2,4,6-Trichloroaniline. With the CAS registry number 634-93-5 and EINECS registry number 211-219-8, it is also named as Benzenamine,2,4,6-trichloro-. In addition, the molecular formula is C6H4Cl3N and the molecular weight is 196.46. It is a kind of fine purple fibres and belongs to the classes of Alpha Sort; Amines; Aromatics Pesticides Metabolites; Chemical Class; Q-ZAlphabetic; TP-TZ.

Physical properties about this chemical are: (1)ACD/LogP: 3.74; (2)ACD/LogD (pH 5.5): 3.74; (3)ACD/LogD (pH 7.4): 3.74; (4)ACD/BCF (pH 5.5): 409.15; (5)ACD/BCF (pH 7.4): 409.15; (6)ACD/KOC (pH 5.5): 2577.45; (7)ACD/KOC (pH 7.4): 2577.46; (8)#H bond acceptors: 1; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 1; (11)Polar Surface Area: 3.24 Å2; (12)Index of Refraction: 1.626; (13)Molar Refractivity: 45.17 cm3; (14)Molar Volume: 127.5 cm3; (15)Polarizability: 17.9 ×10-24cm3; (16)Surface Tension: 50.8 dyne/cm; (17)Density: 1.54 g/cm3; (18)Flash Point: 110.1 °C; (19)Enthalpy of Vaporization: 49.6 kJ/mol; (20)Boiling Point: 258.4 °C at 760 mmHg; (21)Vapour Pressure: 0.0137 mmHg at 25°C.

Preparation of 2,4,6-Trichloroaniline: it can be prepared by aniline. This reaction will need reagents NaBiO3 and ZnCl2 and solvent acetic acid. The reaction time is 0.5 hour at reaction temperature of 20 °C. The yield is about 72%.

2,4,6-Trichloroaniline can be prepared by aniline

Uses of 2,4,6-Trichloroaniline: it can be used in organic synthesis. And it can react with acetic acid anhydride to get N-(2,4,6-trichloro-phenyl)-diacetamide. This reaction will need reagent CH3SO3H. The yield is about 96% by heating.

2,4,6-Trichloroaniline can react with acetic acid anhydride to get N-(2,4,6-trichloro-phenyl)-diacetamide

When you are using this chemical, please be cautious about it as the following:
This chemical has danger of cumulative effects.And it is toxic by inhalation, in contact with skin and if swallowed. Moreover, it is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing and gloves. If it contact with your skin, wash it immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). This material and its container must be disposed of as hazardous waste. In addition, you should avoid release to the environment and you can refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: Clc1cc(Cl)cc(Cl)c1N
(2)InChI: InChI=1/C6H4Cl3N/c7-3-1-4(8)6(10)5(9)2-3/h1-2H,10H2
(3)InChIKey: NATVSFWWYVJTAZ-UHFFFAOYAL

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 800mg/kg (800mg/kg)   Office of Toxic Substances Report. Vol. OTS,
mouse LD50 oral 1180mg/kg (1180mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 86, 1990.
rat LD50 intraperitoneal 800mg/kg (800mg/kg)   Office of Toxic Substances Report. Vol. OTS,
rat LD50 oral 2400mg/kg (2400mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 55(6), Pg. 86, 1990.