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Detail of "642-98-8"

  • CAS Number:
  • 642-98-8
  • Name:
  • D-(?)-Ribonic acid

  • Molecular Structure:
  • Molecular Weight:
  • 166.1293
  • Synonyms:
  • RIBONIC ACID;D-()-Ribonic acid

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Reference

D-Ribonic acid g-lactone
D-Ribonic acid g-lactone. A convenient, large-scale preparation of ribonolactone. Pudlo, Jeffrey S.; Townsend, Leroy B. (Coll. Lit., Arts Sci., Univ. Michigan, Ann Arbor, MI 48109-1065, USA). Nucleic Acid Chem., Volume 4, 51-3. Edited by: Townsend, Leroy B.; Tipson, R. Stuart. Wiley: New York, N. Y. (English) 1991. CODEN: 39GCA6. DOCUMENT TYPE: Conference CA Section: 33 (Carbohydrates) A convenient oxidn. of D-ribose with Br2 in aq. Na2CO3 gave title compd. in 63% yield.
D-Ribonolactone
D-Ribonolactone. Sturc, Antonin (Czech.). Czech. CS 222096 B 15 Jul 1985, 2 pp. (Czechoslovakia) CODEN: CZXXA9.Some commonly used reagents like 642-98-8 and 28060-81-3 are used in this experiment. CLASS: IC: C07C059-105. APPLICATION: CS 82-794 4 Feb 1982. DOCUMENT TYPE: Patent CA Section: 33 (Carbohydrates) Lactonization of D-ribonic acid (I) from a partially concd. aq. soln. and subsequent electroredn. of the D-ribonolactone (II) obtained gave ribose. Thus, an aq. I soln. was concd.. in vacuo at 60° to 8% H2O, the sirup was kept 1 day, adjusted to ~17% II, 4% (NH4)3PO4, and pH 3,3, and reduced over a Hg cathode at 800 A/m2 and 12° to give 30% current yield of D-ribose. .
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