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| CAS No.: | 6705-03-9 |
|---|---|
| Name: | 2-Amino-5-methoxybenzoic acid |
| Article Data: | 47 |
| Molecular Structure: | |
|
|
|
| Formula: | C8H9NO3 |
| Molecular Weight: | 167.164 |
| Synonyms: | Anthranilicacid, 5-methoxy- (4CI);m-Anisic acid, 6-amino- (6CI,7CI,8CI);5-Methoxy-2-aminobenzoic acid;5-Methoxyanthranilic acid;6-Amino-m-anisic acid;NSC 126996; |
| Density: | 1.303 g/cm3 |
| Melting Point: | 148-152 °C |
| Boiling Point: | 349.9 °C at 760 mmHg |
| Flash Point: | 165.4 °C |
| Appearance: | white to light yellow crystal powder |
| Hazard Symbols: |
 Xn,  Xi
|
| Risk Codes: | 22-36/37/38-20/21/22 |
| Safety: | 26-36/37/39-36 |
| PSA: | 72.55000 |
| LogP: | 1.55680 |
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| Conditions | Yield |
|---|---|
| With hydrogen; palladium on activated charcoal In methanol at 20℃; for 24h; | 100% |
| With hydrogen; palladium on activated charcoal In methanol at 20℃; for 24h; | 100% |
| With 5%-palladium/activated carbon; hydrogen In methanol under 775.743 Torr; for 15h; Inert atmosphere; | 100% |
| Conditions | Yield |
|---|---|
| With lithium hydroxide In tetrahydrofuran; methanol; water at 20℃; | 99% |
| Conditions | Yield |
|---|---|
| Stage #1: 5-methoxylindole With bromamine B; sodium hydroxide; palladium dichloride In water; acetonitrile at 60℃; for 3.33333h; pH=12; Stage #2: In water Acidic conditions; | 96% |
| With ruthenium trichloride; osmium(VIII) oxide; bromamine B; sodium hydroxide In water; acetonitrile at 39.84℃; for 4.5h; | 96% |
- 100174-55-8
5,5′-dimethoxyindigo
- 6705-03-9
2-Amino-5-methoxybenzoic acid
| Conditions | Yield |
|---|---|
| Stage #1: 5,5′-dimethoxyindigo With bromamine B; sodium hydroxide; palladium dichloride In water; acetonitrile at 60℃; for 2.16667h; pH=12; Stage #2: In water Acidic conditions; | 96% |
- 180690-91-9
2-(3,3-Dimethyl-ureido)-5-methoxy-benzoic acid methyl ester
- 6705-03-9
2-Amino-5-methoxybenzoic acid
| Conditions | Yield |
|---|---|
| With hydrogenchloride at 100℃; for 24h; | 89% |
| Conditions | Yield |
|---|---|
| With sulfuric acid Behandeln des erhaltenen 5-Methoxy-isatins mit wss. Natronlauge und wss. Wasserstoffperoxid; |
- 101351-28-4
6-methoxy-3-(4-methoxy-phenyl)-1H-quinazoline-2,4-dione
- 6705-03-9
2-Amino-5-methoxybenzoic acid
| Conditions | Yield |
|---|---|
| With sodium hydroxide |
| Conditions | Yield |
|---|---|
| With potassium hydroxide Hydrolysis; |
- 38985-80-7
2-(acetylamino)-5-methoxybenzoic acid
- 6705-03-9
2-Amino-5-methoxybenzoic acid
| Conditions | Yield |
|---|---|
| With hydrogenchloride | |
| With sodium hydroxide |
- 201230-82-2
carbon monoxide
- 79069-37-7
1-(acetamino)-2-bromo-4-methoxybenzene
- 6705-03-9
2-Amino-5-methoxybenzoic acid
| Conditions | Yield |
|---|---|
| With sodium hydroxide; tributyl-amine; water; triphenylphosphine; bis-triphenylphosphine-palladium(II) chloride 1) 110-125 deg C, 2-3 atm, 7 h, 2) H2O, EtOH, 95 deg C, 18 h; Yield given. Multistep reaction; |
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Chemistry
IUPAC Name: 2-Amino-5-methoxybenzoic acid
Molecular Formula: C8H9NO3
Molecular Weight: 167.162g/mol
Density: 1.303 g/cm3
Melting Point: 150-152°C
Boiling Point: 349.9 °C at 760 mmHg
Flash Point: 165.4 °C
Freely Rotating Bonds: 3
Polar Surface Area: 38.77Å2
Index of Refraction: 1.603
Molar Refractivity: 44.09 cm3
Molar Volume: 128.2 cm3
Polarizability: 17.48 ×10-24 cm3
Surface Tension: 56.6 dyne/cm
Enthalpy of Vaporization: 62.73 kJ/mol
Vapour Pressure: 1.71E-05 mmHg at 25°C
2-Amino-5-methoxybenzoic acid ,its Cas Register Number is 6705-03-9.The chemical synonyms of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) are 2-Amino-5-methoxybenzoic acid ; 5-Methoxyanthranilic acid ; 5-Methoxyanththranillic acid ; 2-Amino-5-methoxylbenzoic acid ; 2-Amino-5-MethoxybenzoicAcid98% ; 2-Amino-5-Methoxybenzoic .Product categories of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) are Aromatic Carboxylic acids, amides, anilides,anhydrides & salts ; Carboxylic acids ; Phenyls & phenyl-het ; Organic acids ; Carboxylic acids ; Phenyls & phenyl-het ; Aromatic amino acids ; Peptide synthesis ; Unnatural amino acid derivatives .The molecular structure of 2-Amino-5-methoxybenzoic acid (CAS No.6705-03-9) is 
.
Uses
It is used in organic synthesis.
Safety Profile
Hazard Codes: 
Xn,Xi
Xn: Harmful
Xi: Irritant
Risk Statements: 22-36/37/38-20/21/22
22: Harmful if swallowed
36/37/38: Irritating to eyes, respiratory system and skin
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 26-36/37/39-36
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
36/37/39: Wear suitable protective clothing, gloves and eye/face protection