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| CAS No.: | 67564-91-4 |
|---|---|
| Name: | Fenpropimorph |
| Article Data: | 10 |
| Molecular Structure: | |
|
|
|
| Formula: | C20H33 N O |
| Molecular Weight: | 303.488 |
| Synonyms: | Morpholine,4-[3-[4-(1,1-dimethylethyl)phenyl]-2-methylpropyl]-2,6-dimethyl-, cis-; BAS42100F; Corbel; Fenpropimorph; Forbel 750; Mistral;cis-4-[3-(4-tert-Butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine |
| EINECS: | 266-719-9 |
| Density: | 0.928 g/cm3 |
| Melting Point: | 25°C |
| Boiling Point: | 392.7 °C at 760 mmHg |
| Flash Point: | 115.6 °C |
| Solubility: | 4.32mg/L at 20℃ |
| Hazard Symbols: |
 
|
| Risk Codes: | R22;R38;R51/53;R63 |
| Safety: | 36/37-46-61 |
| Transport Information: | UN 3082 |
| PSA: | 12.47000 |
| LogP: | 4.20980 |
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- 141-91-3
2,6-dimethyl morpholine
- 80-54-6
lilial
- 67564-91-4
cis-4-<3-(4-tert-butylphenyl)-2-methylpropyl>-2,6-dimethylmorpholine
| Conditions | Yield |
|---|---|
| With formic acid; triethylamine In water; tert-butyl alcohol at 100℃; for 14h; | 81% |
- 594-36-5
2-methyl-2-butylchloride
A
- 78613-35-1
amorolfine
B
- 67564-91-4
cis-4-<3-(4-tert-butylphenyl)-2-methylpropyl>-2,6-dimethylmorpholine
| Conditions | Yield |
|---|---|
| Stage #1: (2R,6S)-2,6-dimethyl-4-(2-methyl-3-phenylpropyl)morpholine hydrochloride With iron(III) chloride In dichloromethane Stage #2: 2-methyl-2-butylchloride In dichloromethane at -52 - -20℃; Stage #3: With sodium hydroxide; water Product distribution / selectivity; more than 3 stages; | A n/a B 0.14% |
- 80-54-6
lilial
- 67564-91-4
cis-4-<3-(4-tert-butylphenyl)-2-methylpropyl>-2,6-dimethylmorpholine
| Conditions | Yield |
|---|---|
| With hydrogen; palladium on kanthal In isopropyl alcohol at 80℃; under 4500.45 Torr; for 5 - 15h; Product distribution / selectivity; | |
| With hydrogen; palladium on activated charcoal at 60 - 120℃; under 4500.45 - 10501.1 Torr; for 5 - 12h; Product distribution / selectivity; | |
| With hydrogen; palladium on kanthal at 60 - 120℃; under 4500.45 - 10501.1 Torr; for 5 - 6h; Product distribution / selectivity; Neat (no solvent); |
- 922734-43-8
(2R,6S)-2,6-dimethyl-4-(2-methyl-3-phenylpropyl)morpholine hydrochloride
- 594-36-5
2-methyl-2-butylchloride
A
- 78613-35-1
amorolfine
B
- 67564-91-4
cis-4-<3-(4-tert-butylphenyl)-2-methylpropyl>-2,6-dimethylmorpholine
| Conditions | Yield |
|---|---|
| Stage #1: (2R,6S)-2,6-dimethyl-4-(2-methyl-3-phenylpropyl)morpholine hydrochloride; Friedel-Craft catalyst In dichloromethane Stage #2: 2-methyl-2-butylchloride In dichloromethane at -52 - -20℃; Product distribution / selectivity; Friedel Crafts Alkylation; |
- 67564-91-4
cis-4-<3-(4-tert-butylphenyl)-2-methylpropyl>-2,6-dimethylmorpholine
| Conditions | Yield |
|---|---|
| With water; iodine; sodium hydrogencarbonate at 20℃; for 4h; chemoselective reaction; | 55% |
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- Total:28 Page 1 of 1 1
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Chemistry
Product Name: cis-Fenpropimorph (CAS NO.67564-91-4)
Molecular Formula: C20H33NO
Molecular Weight: 303.48212g/mol
Mol File: 67564-91-4.mol
Einecs: 266-719-9
Boiling point: 392.7 °C at 760 mmHg
Flash Point: 115.6 °C
Density: 0.928 g/cm3
Surface Tension: 30.8 dyne/cm
Enthalpy of Vaporization: 64.25 kJ/mol
Vapour Pressure: 2.25E-06 mmHg at 25°C
XLogP3-AA: 5.2
H-Bond Donor: 0
H-Bond Acceptor: 2
Product Categories: Alpha sort; E-GAlphabetic; F;FA - FLPesticides; Fungicides; Morpholines; Pesticides and Metabolites
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | 5980mg/kg (5980mg/kg) | Pesticide Manual. Vol. 9, Pg. 379, 1991. | |
| rat | LC50 | inhalation | 2900mg/m3/4H (2900mg/m3) | Pesticide Manual. Vol. 9, Pg. 379, 1991. | |
| rat | LD50 | oral | 3gm/kg (3000mg/kg) | Pesticide Manual. Vol. 9, Pg. 379, 1991. | |
| rat | LD50 | skin | 4200mg/kg (4200mg/kg) | Pesticide Manual. Vol. 9, Pg. 379, 1991. |
Safety Profile
Safety Information of cis-Fenpropimorph (CAS NO.67564-91-4):
Hazard Codes: N.gif){kind=small}
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Risk Statements: 22-38-51/53-63
22: Harmful if swallowed
38: Irritating to the skin
51: Toxic to aquatic organisms
53: May cause long-term adverse effects in the aquatic environment
63: Possible risk of harm to the unborn child
Safety Statements: 36/37-46-61
36: Wear suitable protective clothing
37: Wear suitable gloves
46: If swallowed, seek medical advice immediately and show this container or label
61: Avoid release to the environment. Refer to special instructions safety data sheet
Specification
cis-Fenpropimorph ,its CAS NO. is 67564-91-4,the synonyms is Fenpropimorph pestanal 250 mg ; 2,6-Dimethyl-4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)-morpholinc ; cis-2,6-Dimethyl-4-(3-(4-(1,1-dimethylethyl)phenyl)-2-methylpropyl)morpholin ; cis-4-[3-(P-tert-butylphenyl)-2-methylpropyl]-2,6-dimethylmorpholine ; Fenpropimorph(100ug/mlintoluene) ; Corbel[r] ; Mistral[r] .