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| CAS No.: | 6757-06-8 |
|---|---|
| Name: | Cytidine 5'-monophosphate disodium salt |
| Article Data: | 1 |
| Molecular Structure: | |
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|
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| Formula: | C9H12N3Na2O8P |
| Molecular Weight: | 367.163 |
| Synonyms: | 5'-Cytidylicacid, disodium salt (7CI,8CI,9CI);5'-CMP disodium salt;CMP disodium salt;Cytidine 5'-monophosphate sodium;Cytidine monophosphate disodium salt;Disodium 5'-CMP;Disodium 5'-cytidylate;Disodium CMP;Disodium cytidine 5'-monophosphate;Disodium cytidine5'-phosphate;NSC 20259;Sodium 5'-cytidylate; |
| EINECS: | 229-819-3 |
| Density: | 2.15g/cm3 |
| Melting Point: | 300 °C |
| Boiling Point: | 678.1oC at 760 mmHg |
| Flash Point: | 363.9oC |
| Appearance: | White crystalline powder |
| Hazard Symbols: | Xn,Xi |
| Risk Codes: | 20/21/22-36/37/38 |
| Safety: | 24/25 |
| PSA: | 192.83000 |
| LogP: | -0.98840 |
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- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
- 6757-06-8
cytidine-5'-monophosphate disodium salt
| Conditions | Yield |
|---|---|
| With water; zinc(II) cation pH=5.5; |
| Conditions | Yield |
|---|---|
| In ethanol at 40℃; | 76% |
| Conditions | Yield |
|---|---|
| In methanol for 0.5h; pH=4; | 75% |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
- 7732-18-5
water
- 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene
| Conditions | Yield |
|---|---|
| Stage #1: cobalt(II) nitrate hexahydrate; cytidine-5'-monophosphate disodium salt; water for 0.5h; Stage #2: trans-1,2-bis(4-pyridyl)ethylene With nitric acid In ethanol at 20℃; for 0.5h; pH=5; | 72% |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
- 7732-18-5
water
- 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene
| Conditions | Yield |
|---|---|
| Stage #1: manganese(II) perchlorate hexahydrate; cytidine-5'-monophosphate disodium salt; water for 0.5h; Stage #2: trans-1,2-bis(4-pyridyl)ethylene With sodium hydroxide In ethanol at 20℃; for 0.5h; pH=6; | 68% |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
- 7732-18-5
water
- 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene
| Conditions | Yield |
|---|---|
| Stage #1: manganese(II) perchlorate hexahydrate; cytidine-5'-monophosphate disodium salt; water for 0.5h; Stage #2: trans-1,2-bis(4-pyridyl)ethylene With sodium hydroxide In ethanol at 20℃; for 0.5h; pH=7; | 68% |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
| Conditions | Yield |
|---|---|
| With 3-chloro-benzenecarboperoxoic acid In methanol at 0 - 20℃; for 24.25h; | 42% |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
| Conditions | Yield |
|---|---|
| In water soln. of nucleotide (pH=7) is added dropwise to a soln. of amino acid chromium complex, soln. is placed in a thermostated bath at 50°C with const. stirring for 8 h; soln. is concd. to 5 ml, chromy. (Sephadex), addn. of ethanol to the first (blue) fraction, further evapn., ppt. is vac. dried (P4O10); elem. anal.; |
- 6757-06-8
cytidine-5'-monophosphate disodium salt
| Conditions | Yield |
|---|---|
| In water soln. of nucleotide (pH approx. 7) is added dropwise to a soln. of amino acid chromium complex (pH 3.9-4.2), mixt. is maintained at 50°C with const. stirring for 1.5-2.5 h; ppt. is filtered off, washed with cold water and vac. dried (P4O10); elem. anal.; |
- 14240-29-0, 14301-97-4, 59109-96-5, 66653-37-0
trans-{CrCl2(C2H4(NH2)2)2}Cl
- 6757-06-8
cytidine-5'-monophosphate disodium salt
| Conditions | Yield |
|---|---|
| In water aq. soln. of Cr compd. mixed with aq. soln. of org. compd. (mole ratio Cr : org. compd. = 1 : 1); soln. heated at ca. 55 °C for 5-7 h; soln. concd. at 50 °C and passed through a colomn; ethanol addedto eluate; resulting ppt. filtered, washed (EtOH), and dried over silica gel; elem. anal.; |
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Chemistry
Molecular Structure of Cytidine 5'-monophosphate disodium salt (CAS NO.6757-06-8):
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IUPAC Name: disodium [(2R,3S,4R,5R)-5-(4-amino-2-oxopyrimidin-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl phosphate
Empirical Formula: C9H12N3Na2O8P
Molecular Weight: 367.1602
H bond acceptors: 11
H bond donors: 4
Freely Rotating Bonds: 10
Polar Surface Area: 162.95Å2
EINECS: 229-819-3
Melting point: 300 °C
Product Categories: Amino Acids;Biochemistry;Nucleosides, Nucleotides & Related Reagents;Nucleotides and their analogs;Nucleic acids
InChI
InChI=1/C9H14N3O8P.2Na/c10-5-1-2-12(9(15)11-5)8-7(14)6(13)4(20-8)3-19-21(16,17)18;;/h1-2,4,6-8,13-14H,3H2,(H2,10,11,15)(H2,16,17,18);;/q;2*+1/p-2/t4-,6-,7-,8-;;/m1../s1
Smiles
n1([C@H]2[C@@H]([C@H](O)[C@H](O2)COP(=O)([O-])[O-])O)c(nc(cc1)N)=O.[Na+].[Na+]
Safety Profile
Hazard Codes: 
Xn,
Xi
Risk Statements: 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-37/39-36-26
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S37/39:Wear suitable gloves and eye/face protection.
S36:Wear suitable protective clothing.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
F: 1-10
Specification
Cytidine 5'-monophosphate disodium salt , with CAS number of 6757-06-8, can be called 5'-CMP disodium salt ; CMP disodium salt ; Cytidine 5'MP, disodium salt ; Cytidine monophosphate disodium salt ; Disodium 5'-CMP ; Disodium CMP ; Disodium cytidine 5'-monophosphate ; Disodium cytidine 5'-phosphate . It is a white crystalline powder.