Detail of "67772-77-4"

CAS Number:
67772-77-4
Name:
7-Oxabicyclo[4.1.0]hept-3-en-2-one,5-hydroxy-3-methyl-, (1R,5S,6R)-
Molecular Structure:
Formula:
C7H8 O3
Molecular Weight:
140.1366
Synonyms:
7-Oxabicyclo[4.1.0]hept-3-en-2-one,5-hydroxy-3-methyl-, [1R-(1a,5a,6a)]-; (+)-Epiepoformin; Epiepoformin
Density:
1.387 g/cm³
Boiling Point:
329.2 °C at 760 mmHg
Flash Point:
145.9 °C

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Total synthesis of (+)-epiepoformin and (-)-phyllostine: Total synthesis of (+)-epiepoformin and (-)-phyllostine. Okamura, Hiroaki; Shimizu, Hideki; Yamashita, Naomi; Iwagawa, Tetsuo; Nakatani, Munehiro (Faculty of Science, Department of Chemistry and Bioscience, Kagoshima University, Kagoshima 890-0065, Japan).Chemicals with cas numbers 142449-87-4 and 67772-77-4 also play role. Tetrahedron, 59(51), 10159-10164 (English) 2003 Elsevier Science B.V. CODEN: TETRAB. ISSN: 0040-4020. DOCUMENT TYPE: Journal CA Section: 26 (Biomolecules and Their Synthetic Analogs) An efficient asym. total synthesis of naturally occurring cyclohexeneoxides, (+)-epiepoformin (I) and (-)-phyllostine (II) has been achieved. Since (-)-theobroxide (III) was derived from the same precursor of (+)-epiepoformin (II), the formal total synthesis of (-)-theobroxide (III) has also been achieved. .