Detail of "6832-87-7"

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CAS Number:
6832-87-7
Name:
Benzenamine,2-bromo-N-methyl-
Superlist Name:
2-Bromo-N-methylaniline
Molecular Structure:
Formula:
C₇H₈BrN
Molecular Weight:
186.05
Synonyms:
Aniline,o-bromo-N-methyl- (7CI,8CI);1-Bromo-2-(methylamino)benzene;2-Bromo-N-methylaniline;N-Methyl-2-bromoaniline;NSC 338420;o-Bromo-N-methylaniline;2-bromo-N-methylbenzenamine;
Density:
1.487 g/cm³
Boiling Point:
243.6 °C at 760 mmHg
Flash Point:
101.1 °C
Hazard Symbols:
Xn
Risk Codes:
22
Safety:
37/39 Details

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Synthesis of o-halophenoxy, o-halophenylthio and o-halomethylanilino derivatives of Group IVb and Vb elements: Synthesis of o-halophenoxy, o-halophenylthio and o-halomethylanilino derivatives of Group IVb and Vb elements. Heinicke, J.; Nietzschmann, E.; Tzschach, A. (Sekt. Chem., Martin-Luther-Univ. Halle-Wittenberg, Halle/Saale, Ger. Dem.Several reagents with their cas registry numbers 84998-62-9 and 6832-87-7 are used here. Rep.). J. Prakt. Chem., 325(3), 511-16 (German) 1983. CODEN: JPCEAO. ISSN: 0021-8383. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) The reaction of o-XC6H4ZH (X = Cl, Br; Z = O, S, NMe) with ClMRn, Me2NMRn, or HOSnR3 gave 16-88% o-XC6H4ZMRn (M = P, As, Si, Sn; R = Me, Et, Ph, Bu, NMe2, etc.; n = 2, 3). Thus, o-ClC6H4OH and ClSiMe2CH2Cl with Et3N in pentane gave 67% o-ClC6H4OSiMe2CH2Cl. .

Highly efficient bromination of aromatic compounds using 3-methylimidazolium tribromide as reagent/solvent: Highly efficient bromination of aromatic compounds using 3-methylimidazolium tribromide as reagent/solvent. Chiappe, Cinzia; Leandri, Elsa; Pieraccini, Daniela (Dipartimento di Chimica Bioorganica e Biofarmacia, Pisa 56127, Italy). 98-86-2 and 6832-87-7 are cas registry numbers. These chemicals are also mentioned in this article. Chemical Communications (Cambridge, United Kingdom), (22), 2536-2537 (English) 2004 Royal Society of Chemistry. CODEN: CHCOFS. ISSN: 1359-7345. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) 3-Methylimidazolium tribromide proves to be an alternative highly efficient reagent/solvent for the halogenation of non-activated arom. compds. .