Detail of "6852-58-0"
- MSDS Download
- CAS Number:
- 6852-58-0
- Name:
2-Propanamine,2-methyl-N-(phenylmethylene)-
- Molecular Structure:
- Formula:
- C11H15N
- Molecular Weight:
- 161.24
- Synonyms:
- Ethylamine,N-benzylidene-1,1-dimethyl- (6CI,7CI,8CI);2-Methyl-N-(phenylmethylene)-2-propanamine;Benzaldehyde tert-butylimine;Benzylidene-tert-butylamine;N-Benzylidene tert-butylamine;N-Benzylidene-1,1-dimethylethylamine;N-Benzylidene-N-tert-butylamine;N-Benzylidene-N-tert-butylimine;N-Benzylidene-tert-butylamine;N-t-Butylbenzylideneimine;N-tert-Butylbenzylideneamine;N-tert-Butylbenzylimine;
- Density:
- 0.85 g/cm3
- Melting Point:
- -30 ºC
- Boiling Point:
- 231.8 °C at 760 mmHg
- Flash Point:
- 85.6 °C
- Hazard Symbols:
Xn,
Xi- Risk Codes:
- 22-36/37/38-40-42/43
- Safety:
- 26-36 Details
2-Propanamine,2-methyl-N-(phenylmethylene)-
Xn,Xi
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Reference
- Nitriles and thioamides of fused ring pyridine derivatives
- Nitriles and thioamides of fused ring pyridine derivatives. Shepherd, Robin Gerald (Wyeth, John, and Brother Ltd., UK). Brit. UK Pat. Appl. GB 2116553 A1 28 Sep 1983, 5 pp. (English). (United Kingdom). CODEN: BAXXDU. CLASS: IC: C07D215-48. APPLICATION: GB 83-6456 9 Mar 1983.Several reagents with their cas registry numbers 83246-81-5 and 6852-58-0 are used here. PRIORITY: GB 82-7051 11 Mar 1982. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Fused ring pyridinecarbonitriles and thiocarboxamides I [R1-R5 = H, C1-6 (un)substituted alkyl, C4-6 (un)substituted cycloalkyl, C7-12 (un)substituted aralkyl; R1R2, R2R3 = 5-7 ring; R4, R5 = C1-6 alkoxy;R6 = cyano; n = 1-3] were prepd. from metal derivs. of the starting compds., e.g. 8-lithio-5,6,7,8-tetrahydroquinoline, prepd. by treating the starting compd. with LiN(CMe3)CHPh(CH2)3Me. Thus, treating PhCH:NCMe3 with BuLi gave the Li amide deriv. to which was added 5,6,7,8,-tetrahydro-4-methylquinoline, followed by addn. of (Me2CH)2NCN to give I (R1 = R2 = R4 = R5 = H, R3 = Me, R6 = cyano; n = 2). Addnl. obtained was I (R6 = CSNH2) from an analogous reaction with Me3SiNCS. .