CAS No.6935-27-9,2-Benzylaminopyridine Suppliers

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Basic Information

Molecular Structure:
CAS No.:	6935-27-9
Name:	2-Benzylaminopyridine
Article Data:	178

Formula:	C₁₂H₁₂N₂
Molecular Weight:	184.241
Synonyms:	Pyridine,2-(benzylamino)- (6CI,7CI,8CI);2-(Benzylamino)pyridine;N-Benzyl-2-aminopyridine;N-Benzyl-2-pyridinamine;N-Benzylpyridine-2-amine;NSC 59833;
EINECS:	230-060-5
Density:	1.131 g/cm³
Melting Point:	95-97 °C(lit.)
Boiling Point:	321.8 °C at 760 mmHg
Flash Point:	148.4 °C
Appearance:	white to off-white powder
Hazard Symbols:	Xn
Risk Codes:	22-37/38-41
Safety:	26-39
PSA:	24.92000
LogP:	2.76670

Synthetic route

: 504-29-0
2-aminopyridine

: 100-51-6
benzyl alcohol

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With dichloro-[1,3-bis(4-tert-butylbenzyl)perhydrobenzimidazol-2-ylidene](p-cymene)ruthenium(II); potassium tert-butylate at 120℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique; Sealed tube;	100%
With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h;	99%
With potassium tert-butylate; copper diacetate In 1,4-dioxane at 130℃; for 24h; Inert atmosphere;	99%

: 109-09-1
2-chloropyridine

: 100-46-9
benzylamine

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With sodium t-butanolate In toluene at 100 - 110℃; for 24h; Buchwald-Hartwig amination; Inert atmosphere; Sealed vial;	99%
With potassium phosphate In dimethyl sulfoxide at 80℃; UV-irradiation;	95%
With copper(l) iodide; C14H16N2O; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; Sealed tube;	93%

: 5029-67-4
2-iodopyridine

: 100-46-9
benzylamine

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;	99%
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 25℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry;	93%
With tetra(n-butyl)ammonium hydroxide; copper(II) sulfate In water at 80℃; for 24h; Schlenk technique; Sealed tube; Inert atmosphere;	80%
With tetramethyl ammoniumhydroxide; ethyl 2-oxocyclohexane carboxylate; copper(l) chloride In dimethyl sulfoxide at 80℃; for 24h; Inert atmosphere;	72%

: 1883-96-1, 82299-15-8, 88785-73-3
N-benzylidenepyridin-2-amine

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With Triethoxysilane; [bis(2,6-diisopropylaniline)acenaphthene]Fe(η6-toluene) at 70℃; for 18h; Schlenk technique; Inert atmosphere; Glovebox; Sealed tube;	98%
With (4-Ph)Triaz(NHPiPr2)2Mn(CO)2Br; potassium tert-butylate; hydrogen In tetrahydrofuran at 50℃; under 15001.5 Torr; for 4h; Glovebox; Autoclave; Sealed tube; chemoselective reaction;	92%
With sodium tetrahydroborate In tetrahydrofuran at 25℃; for 4h;	40%
With sodium tetrahydroborate In methanol for 5h; Cooling;	19.09 g
With [MnBr(CO)3(2-(diphenylphosphinoamino)pyridine)]; potassium tert-butylate; hydrogen In ethanol at 80℃; for 48h; Autoclave;	50.7 mg

: 1444866-70-9
methyl benzylpyridin-2-ylcarbamate

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With water; sodium hydroxide In methanol for 3h; Reflux;	98%

: 442513-39-5
benzyl-pyridin-2-yl-carbamic acid tert-butyl ester

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With trifluoroacetic acid In dichloromethane; water	97%
With trifluoroacetic acid In dichloromethane; water at 25℃;

: 109-04-6
2-bromo-pyridine

: 100-46-9
benzylamine

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With dibenzylphosphoramidous acid 1,1'-binaphthyl-2,2'-diyl ester; caesium carbonate; copper(I) bromide In N,N-dimethyl-formamide at 90℃; for 36h;	97%
With copper(l) iodide; 1-tetralone oxime; potassium hydroxide In water at 65℃; for 18h; Sealed tube; Inert atmosphere; Green chemistry;	95%
With cesium acetate; copper In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;	92%

: 1335111-43-7
N-benzyl-N-(pyridin-2-yl)hydroxylamine

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With palladium 10% on activated carbon; hydrogen In methanol at 20℃; under 760.051 Torr; for 0.5h; Inert atmosphere;	97%

: 15009-91-3
2-nitropyridine

: 100-51-6
benzyl alcohol

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With [RuCl(CO)(PPh3)(PNS-Me)]; potassium hydroxide In toluene at 100℃; for 12h;	96%
With bis(5-chlorosalicylidene)hydrazone binuclear copper(I) complex; potassium hydroxide In toluene at 100℃; for 18h;	80%
With aluminum (III) chloride; water In acetonitrile at 20℃; Irradiation;	50%

: 504-29-0
2-aminopyridine

: 100-52-7
benzaldehyde

: 6935-27-9
N-benzylpyridin-2-amine

Conditions

Conditions	Yield
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; silver trifluoromethanesulfonate In dichloromethane at 20℃; for 2h;	93%
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate In neat (no solvent) at 150℃; for 0.25h;	92%
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; thiourea In toluene at 70℃; for 24h;	91%

Total:80 Page 1 of 3 1 2 3 Next>>

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Chemistry

IUPAC Name: N-benzylpyridin-2-amine
Molecular Formula: C₁₂H₁₂N₂
Molecular Weight: 184.2371g/mol
Appearance: white to off-white powder
EINECS: 230-060-5
Density: 1.131 g/cm³
Melting Point: 94°C to 98°C
Boiling Point: 116-131°C(0.6 mmHg),321.8 °C at 760 mmHg
Flash Point: 148.4 °C
Freely Rotating Bonds: 2
Polar Surface Area: 16.13 Å²
Index of Refraction: 1.636
Molar Refractivity: 58.44 cm³
Molar Volume: 162.8 cm³
Polarizability: 23.16 ×10^-24cm³
Surface Tension: 49.7 dyne/cm
Enthalpy of Vaporization: 56.36 kJ/mol
Vapour Pressure: 0.000291 mmHg at 25°C
The chemical synonyms of 2-Benzylaminopyridine (6935-27-9) are Benzyl-pyridin-2-yl-amine ; Aurora ka-4160 ; Alpha-benzylaminopyridine ; 2-Benzylaminopyridine ; n-Benzyl-2-pyridylamine ; n-Benzylpyridin-2-amine ; n-(2-pyridyl)Benzylamine ; n-(Phenylmethyl)-2-pyridinamine .Product categories of 2-Benzylaminopyridine (6935-27-9) are Pyridines derivates ; C9 to C46 ; Heterocyclic Building Blocks and Pyridines .The molecular structure of 2-Benzylaminopyridine (6935-27-9) is.

Uses

It can be used as pharmaceutical intermediate.

Safety Profile

Hazard Codes: Xn,Xi
Xn: Harmful
Xi: Irritant
Risk Statements: 22-37/38-41-40-36/37/38-20/21/22
22: Harmful if swallowed
40: Limited evidence of a carcinogenic effect
41: Risk of serious damage to eyes
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
37/38: Irritating to respiratory system and skin
36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements; 26-39-36-22
22: Do not breathe dust
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
39: Wear eye/face protection