CAS No.700-58-3,2-Adamantanone Suppliers,MSDS download

Products Categories

Pharmaceutical (133)
Organic Chemicals (50)
Others (20)
Plant Extract (11)
Reagent (9)
Materials (5)

Basic Information

Molecular Structure:
CAS No.:	700-58-3
Name:	2-Adamantanone
Article Data:	338

Formula:	C₁₀H₁₄O
Molecular Weight:	150.221
Synonyms:	Tricyclo[3.3.1.13,7]decanone;2-Oxoadamantane;tricyclo[3.3.1.1(3,7)]decan-2-one;2-Adamantantanone;Tricyclo(3,3,1,13,7)decanone;adamantan-2-one;Adamantanone;Tricyclo(3.3.1.13,7)decanone (9CI);Tricyclo(3.3.1.1(sup 3,7))decanone;Tricyclo(3.3.1.13,7)decan-2-one;
EINECS:	211-847-2
Density:	1.105 g/cm³
Melting Point:	256-258 °C (subl.)(lit.)
Boiling Point:	246.7 °C at 760 mmHg
Flash Point:	95.7 °C
Solubility:	methanol: 0.1 g/mL, clear
Appearance:	white to off-white crystalline powder
Hazard Symbols:	Xi
Risk Codes:	52-36/37/38
Safety:	22-24/25-36-26
PSA:	17.07000
LogP:	2.01160

Synthetic route

: 700-57-2
1-adamantanol

: 700-58-3
2-Adamantanone

Conditions

Conditions	Yield
With ferric nitrate; barium(II) chloride at 90℃; for 0.666667h;	100%
With ruthenium trichloride; iodobenzene; potassium peroxomonosulfate In water; acetonitrile at 20℃; for 0.8h;	100%
With ruthenium trichloride; iodobenzene; potassium peroxymonosulfate In water; acetonitrile at 20℃; for 0.8h; Inert atmosphere;	100%

: 281-23-2
adamantane

A: 700-58-3
2-Adamantanone

B: 768-95-6
1-adamanthanol

C: 5001-18-3
1,3-adamantandiol

Conditions

Conditions	Yield
With methyltrifluoromethyldioxirane In dichloromethane at -22℃; for 0.0166667h;	A n/a B n/a C 86%
With 6-chloro-4-trifluoromethyl-1,2,3-benzoxathiazine-2,2-dioxide; urea hydrogen peroxide adduct; bis[3,5-bis(trifluoromethyl)diphenyl] diselenide In 1,2-dichloro-ethane at 22℃; for 95h;	A n/a B 80% C 5%
With tetrabutylammomium bromide; oxygen; N-hydroxyphthalimide In water at 80℃; under 760 Torr; for 6h; Product distribution; further additives, solvents;	A 12% B 60% C 23%

...Expand

: 281-23-2
adamantane

A: 700-58-3
2-Adamantanone

B: 768-95-6
1-adamanthanol

Conditions

Conditions	Yield
With pyridine; bis(acetylacetonate)oxovanadium; dihydrogen peroxide; Hexafluoroacetone In water at 60℃; Catalytic behavior; Temperature; Reagent/catalyst;	A 70% B n/a
With tetrachloromethane; tetrabutylammomium bromide; water; molybdenum hexacarbonyl at 140℃; for 13h; Inert atmosphere;	A 66% B 34%
With sodium periodate; ruthenium(IV) oxide In tetrachloromethane; water; acetonitrile at 20℃; for 19h;	A 1.6% B 62%

: 4500-12-3
2-adamantanone oxime

: 700-58-3
2-Adamantanone

Conditions

Conditions	Yield
With tris[trinitratocerium(IV)] paraperiodate at 90℃; for 0.25h;	95%
With ruthenium trichloride; toluene-4-sulfonic acid In N,N-dimethyl acetamide; water at 120℃; under 760.051 Torr; for 14h; Inert atmosphere; Green chemistry;	95%
With L-alanin; silica gel; chlorochromic acid In dichloromethane at 20℃; for 9h;	90%
Multi-step reaction with 2 steps 1: 1.) sodium nitrite, AcOH, 2.) NaBH4 / 1.) CH2Cl2, room temperature, 4 h, 2.) EtOH, room temperature, 1 h 2: 33 percent / 1 h / 160 °C View Scheme
With gold(III) tribromide; dimethylglyoxal In ethanol; water at 20℃; for 15h; pH=7;	100 %Spectr.

: adamantane-2-spiro-3′-1′,2′,4′,5′,7′-pentaoxocane

: 95-54-5
1,2-diamino-benzene

A: 700-58-3
2-Adamantanone

B: 2Н,5Н-1,6-(methanedioxymethano)benzo[e][1,2,4,7]dioxadiazocine

Conditions

Conditions	Yield
With samarium(III) nitrate hexahydrate In tetrahydrofuran at 20℃; for 6h; Inert atmosphere;	A n/a B 60%

...Expand

: 281-23-2
adamantane

A: 700-58-3
2-Adamantanone

B: 768-95-6
1-adamanthanol

C: 700-57-2
1-adamantanol

Conditions

Conditions	Yield
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Product distribution;	A n/a B 97% C n/a
With [2,2]bipyridinyl; Ba; trifluoroacetic acid In dichloromethane at 20℃; for 0.0333333h; Yields of byproduct given;	A n/a B 97% C n/a
With ammonium cerium(IV) nitrate; oxygen In acetonitrile for 5h; Ambient temperature; Irradiation;	A 5% B 85% C 5%

...Expand

: 281-23-2
adamantane

A: 700-58-3
2-Adamantanone

B: 768-95-6
1-adamanthanol

C: 700-57-2
1-adamantanol

D: 5001-18-3
1,3-adamantandiol

Conditions

Conditions	Yield
With BaFeO(2.8-x); oxygen at 89.84℃; under 750.075 Torr; for 96h; Catalytic behavior;	A 5% B 48% C 3% D 11%
With oxygen; propionic acid; bis(acetylacetonate)oxovanadium at 120℃; under 760.051 Torr; for 6h; Product distribution / selectivity;	A 5.5% B 31.6% C 3.9% D 7.9%
With methanesulfonic acid; oxygen; propionic acid; bis(acetylacetonate)oxovanadium at 100℃; under 760.051 Torr; for 6h; Product distribution / selectivity;	A 4.2% B 25.1% C 3.9% D 2.4%

...Expand

: 23695-65-0
adamantane-2-thione

: 700-58-3
2-Adamantanone

Conditions

Conditions	Yield
With nitrosonium tetrafluoroborate In dichloromethane for 0.5h; Ambient temperature;	94%
With ozone In diethyl ether at -70℃;	90%
With clay supported cupric nitrate In dichloromethane Ambient temperature;	68%

: 518050-74-3
spiro[adamantan-2,2'-(5'-bromo-5'-methyl-1',3'-dioxolan-4'-one)]

A: spiro[adamantan-2,2'-(5'-methylene-1',3'-dioxolan-4'-one)]

B: 700-58-3
2-Adamantanone

Conditions

Conditions	Yield
With triethylamine In cyclohexane at 0 - 20℃; for 3h;	A 11% B n/a

: spiro[adamantan-2,2'-(5'-methyl-1',3'-dioxolan-4'-one)]

A: 518050-74-3
spiro[adamantan-2,2'-(5'-bromo-5'-methyl-1',3'-dioxolan-4'-one)]

B: 700-58-3
2-Adamantanone

Conditions

Conditions	Yield
With N-Bromosuccinimide In cyclohexane at 80℃; for 3h;	A 8% B n/a

Hot Products

Total:167 Page 1 of 5 1 2 3 4 5 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 700-58-3

Chemistry

IUPAC Name: Adamantan-2-one
Synonyms of 2-Adamantanone (CAS NO.700-58-3): 2-Adamantone ; 2-Oxoadamantane ; Adamantanone ; Tricyclo(3.3.1.13,7)decan-2-one ; Tricyclo(3.3.1.13,7)decanone (9CI)
CAS NO: 700-58-3
Molecular Formula: C₁₀H₁₄O
Molecular Weight: 150.22
Molecular Structure:
EINECS: 211-847-2
H bond acceptors: 1
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 17.07 Å²
Index of Refraction: 1.535
Molar Refractivity: 42.35 cm³
Molar Volume: 135.9 cm³
Surface Tension: 38.6 dyne/cm
Density: 1.105 g/cm³
Flash Point: 95.7 °C
Enthalpy of Vaporization: 48.39 kJ/mol
Boiling Point: 246.7 °C at 760 mmHg
Vapour Pressure: 0.0267 mmHg at 25°C
Melting Point: 256-258 °C (subl.)(lit.)
Solubility: methanol: 0.1 g/mL, clear
Appearance: white to off-white crystalline powder
Product Categories of 2-Adamantanone (CAS NO.700-58-3): Adamantane Derivative;FINE Chemical & INTERMEDIATES;Adamantane derivatives;Adamantanes;Ring Systems;C10;Carbonyl Compounds;Ketones

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	780mg/kg (780mg/kg)		Pharmaceutical Chemistry Journal Vol. 10, Pg. 454, 1976.

Safety Profile

Safety Information about 2-Adamantanone (CAS NO.700-58-3):
Hazard Codes: Irritant Xi
Risk Statements: 52-36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
R52: Harmful to aquatic organisms.
Safety Statements: 22-24/25-36-26
S22: Do not breathe dust.
S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK Germany: 2
RTECS: AU5018000
Hazard Note: Irritant
HS Code: 29142900

Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.