Detail of "7284-37-9"

CAS Number:
7284-37-9
Name:
b-D-Glucopyranosylamine
Superlist Name:
beta-D-Glucopyranosylamine
Molecular Structure:
Formula:
C₆H₁₃NO₅
Molecular Weight:
179.17
Synonyms:
Glucopyranosylamine(6CI,7CI);Glucopyranosylamine, b-D- (8CI);1-Amino-1-deoxy-b-D-glucopyranose;1-Amino-1-deoxy-b-D-glucose;b-D-Glucosylamine;
Density:
1.563 g/cm³
Boiling Point:
416.4 °C at 760 mmHg
Flash Point:
205.6 °C

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In vitro synthesis of hemoglobin AIc: In vitro synthesis of hemoglobin AIc. Flueckiger, R.; Winterhalter, K. H. (Friedrich Miescher-Inst., Basel, Switz.). FEBS Lett., 71(2), 356-60 (English) 1976. CODEN: FEBLAL. DOCUMENT TYPE: Journal CA Section: 6 (General Biochemistry) Section cross-reference(s): 14 When purified normal human Hb was incubated with labeled glucose, a labeled product was produced which had properties identical to those of Hb AIc, and the glucose was shown to be added at the N terminus. This was independent of the N-terminal sequence and was apparently a nonenzymic reaction. The structure of the N-terminal product most consistent with the chem. properties of Hb AIc (e.g., NaBH4 redn. and spectra) was that of an N-glycoside in equil. with a Schiff base. Expts. in which D-glucose-2-3H or D-glucose-5-3H were incubated with erythrocytes showed the intracellular occurrence of an Amadori rearrangement of the initial glucosylated Hb product (Schiff base form) to produce a 1-amino-1-deoxy-2-keto deriv. of glucose with a 5-membered ring. The significance of this nonenzymic Hb glucosylation for diabetes, in which higher than normal Hb AIc concns. are present, is indicated.Except for chemicals metioned above, 9034-51-9 and 7284-37-9 are also used. .