Detail of > 73279-04-6
- CAS Number:
- 73279-04-6
- Name:
Phenol,3-(1-piperidinylmethyl)-
- Superlist Name:
- 3-(1-Piperidinylmethyl)phenol
- Formula:
- C12H17NO
- Molecular Structure:
- Synonyms:
- m-Cresol, a-piperidino- (6CI);3-(1-Piperidinylmethyl)phenol;3-(Piperidinomethyl)phenol;AH 25227;N-(3-Hydroxyphenylmethyl)piperidine;m-(Piperidinomethyl)phenol;a-Piperidino-m-cresol;
- Molecular Weight:
- 191.27
- Density:
- 1.097 g/cm3
- Melting Point:
- 137-138 °C
- Boiling Point:
- 308.1 °C at 760 mmHg
- Flash Point:
- 145.7 °C
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Reference
- Tertiary amines
- Tertiary amines. Iriuchijima, Shinobu; Shimozono, Koji (Denki Kagaku Kogyo K. K.In this study， 73279-04-6 and 4530-44-3 are also used., Japan). Jpn. Kokai Tokkyo Koho JP 61172854 A2 4 Aug 1986 Showa, 5 pp. (Japan) CODEN: JKXXAF. CLASS: ICM: C07C091-30. ICS: C07C089-00; C07D295-08. APPLICATION: JP 85-13562 29 Jan 1985. DOCUMENT TYPE: Patent CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Section cross-reference(s): 1 Tertiary amines I (R, R1 = alkyl; RNR1 may be a ring), useful as raw materials for pharmaceuticals, were prepd. by deacylation of phenol esters II (R2 = alkyl, Ph) to phenols III followed by reaction with RR1NH. Thus, a mixt. contg. 73% II (R2 = Me) (from reaction of m-(acetoxy)toluene with Cl2) was hydrolyzed with 5N NaOH and then treated with piperidine to give 75% I (RNR1 = piperidino). .
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