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74087-85-7

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Basic Information
CAS No.: 74087-85-7
Name: dimethyldioxirane
Article Data: 84
Molecular Structure:
Molecular Structure of 74087-85-7 (dimethyldioxirane)
Formula: C3H6 O2
Molecular Weight: 74.0794
Synonyms: 3,3-Dimethyl-1,2-dioxirane;3,3-Dimethyldioxirane; DMDO; Dimethyldioxirane
Density: 1.004g/cm3
Boiling Point: -21.6±23.0 °C(Predicted)
PSA: 25.06000
LogP: 0.68430
Synthetic route
421-50-1

1,1,1-trifluoro-2-propanone

A

115464-59-0

methyltrifluoromethyldioxirane

B

74087-85-7

3,3-dimethyldioxirane

Conditions
ConditionsYield
With potassium sulfate; potassium hydrogensulfate; potassium peroxomonosulfate; edetate disodium; sodium hydrogencarbonate In water at -20℃; under 650 - 700 Torr;A 6%
B n/a
67-64-1

acetone

74087-85-7

3,3-dimethyldioxirane

Conditions
ConditionsYield
With potassium hydroxide; potassium sulfate; potassium hydrogensulfate; oxone; sodium hydrogencarbonate In water at 5 - 10℃; for 0.05h; pH=7.4;5%
With oxone; sodium hydrogencarbonate In water at 0 - 25℃; under 75.0075 - 750.075 Torr; for 0.716667 - 0.766667h; Product distribution / selectivity;3.8%
With caro's acid; [[(phosphonomethyl)imino]bis[(ethylenenitrilo)bis(methylene)]]tetrakisphosphonic acid sodium salt; sodium hydrogencarbonate at 10 - 25℃; Rate constant; Mechanism; other ketones; var. pH;
563-79-1

2,3-Dimethyl-2-butene

A

5076-20-0

2,3-dimethyl-2,3-epoxybutane

B

50-00-0

formaldehyd

C

75-97-8

3,3-dimethyl-butan-2-one

D

74087-85-7

3,3-dimethyldioxirane

E

116-09-6

hydroxy-2-propanone

F

67-64-1

acetone

Conditions
ConditionsYield
With ozone at -254.16 - -238.16℃; for 19h; Irradiation; Inert atmosphere;
74087-85-7

3,3-dimethyldioxirane

<6S,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

C32H54O8Si

Conditions
ConditionsYield
In dichloromethane; acetone at 0℃;100%
74087-85-7

3,3-dimethyldioxirane

<6R,8R(1'S,2'S,3'R),9R,10R,11R>-11-(benzyloxy)-8-<4-((tert-butyldimethylsilyl)oxy)-2-methoxy-1,3-dimethylbutyl>-10-<(methoxymethyl)oxy>-9-methyl-1,7-dioxaspiro<5.5>undec-2-ene

C32H54O8Si

Conditions
ConditionsYield
In dichloromethane; acetone at 0℃;100%
74087-85-7

3,3-dimethyldioxirane

90-04-0

2-methoxy-phenylamine

91-23-6

2-Nitroanisole

Conditions
ConditionsYield
With potassium hydroxide; disodium hydrogenphosphate; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; acetone other substituted anilines;100%
34557-72-7, 32195-55-4

(5,10,15,20-tetraphenylporphyrinato)manganese(III) chloride

74087-85-7

3,3-dimethyldioxirane

76077-77-5

{Mn(O)(tetraphenylporphyrin(2-))}

Conditions
ConditionsYield
In acetone Kinetics; oxidn. of the Mn compd. in abs. acetone at 0°C;100%
81567-13-7

iron(II) meso-tetramesitylporphyrin

74087-85-7

3,3-dimethyldioxirane

93085-16-6

(5,10,15,20-tetramesitylporphyrinato)oxoiron(IV)

Conditions
ConditionsYield
In acetone byproducts: (CH3)2CO; oxidn. of the Fe compd. in abs. acetone at -10°C with dimethyldioxirane;100%
74087-85-7

3,3-dimethyldioxirane

Nitrite

Nitrate

Conditions
ConditionsYield
In water; acetonitrile Kinetics; 25.6+/-0.1°C, 0. 5 h, phosphate buffer (pH 7.4); followed by HPLC;100%
31004-82-7

manganese(II) 5,10,15,20-tetraphenylporphyrinate

74087-85-7

3,3-dimethyldioxirane

76077-77-5

{Mn(O)(tetraphenylporphyrin(2-))}

Conditions
ConditionsYield
In acetone byproducts: (CH3)2CO; oxidn. of the Mn compd. in abs. acetone at -50°C with dimethyldioxirane and allowing the soln. to warm to -20°C;100%
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    Dimethyldioxirane(DMD)

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  • Dimethyldioxirane

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    74087-85-7

    Dimethyldioxirane

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    Business Type:Trading Company

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    74087-85-7

    Dioxirane, dimethyl-

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    74087-85-7

    Dimethyldioxirane CAS NO.74087-85-7

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     China (Mainland)  |  Contact Details

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  • Dimethyldioxirane CAS NO.74087-85-7

  • Casno:

    74087-85-7

    Dimethyldioxirane CAS NO.74087-85-7

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    Dimethyldioxirane CAS NO.74087-85-7Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:Delivery by EMS, DHL, FEDEX, UPS, TNT

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  • Dimethyldioxirane CAS NO.74087-85-7

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    74087-85-7

    Dimethyldioxirane CAS NO.74087-85-7

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    We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    Address:Jiaojiang District, Taizhou, Zhejiang, China.

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  • Dimethyldioxirane CAS NO.74087-85-7

  • Casno:

    74087-85-7

    Dimethyldioxirane CAS NO.74087-85-7

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    Dimethyldioxirane CAS NO.74087-85-7Appearance:off-white fine crystalline powder Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By cou

    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-025-52181296

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  • 74087-85-7

  • Casno:

    74087-85-7

    74087-85-7

    Min.Order: 0

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    Dimethyldioxirane CAS NO.74087-85-7 Application:intermediates

    We are Hebei minshang biotechnology co. LTD., mainly deal in pharmaceutical intermediates and various chemicals. We are manufacturers and have our own factory. Products & Usage Ph

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

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