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Detail of "7433-79-6"

  • CAS Number:
  • 7433-79-6
  • Name:
  • Naphthalene,2-(methylthio)-

  • Molecular Structure:
  • Formula:
  • C11H10S
  • Molecular Weight:
  • 174.2621
  • Synonyms:
  • Sulfide,methyl 2-naphthyl (6CI,7CI);2-(Methylthio)naphthalene;2-Naphthyl methylsulfide;Methyl 2-naphthyl sulfide;2-(methylsulfanyl)naphthalene;2-methylthionaphthalene;Methyl 2-naphthyl sulfide;naphthalene, 2-(methylthio)-;
  • Density:
  • 1.12 g/cm3
  • Boiling Point:
  • 303.7 °C at 760 mmHg
  • Flash Point:
  • 133 °C

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CAS No.7433-79-6 Naphthalene,2-(methylthio)-

2-(METHYLTHIO)NAPHTHALANE

Supplier:Carbone scientific [ United Kingdom]

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CAS No.7433-79-6 Naphthalene,2-(methylthio)-

1.1 gram in stock of Specs ID AB-131/42000802.

Supplier:SPECS [ Netherlands]

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Reference

Synthesis of chiral sulfoxides by asymmetric oxidation
Synthesis of chiral sulfoxides by asymmetric oxidation. Kagan, Henri B. (Lab. Synth. Asymetrique, Univ. Paris-Sud, Orsay 91405, Fr.).There are some reagents like 7133-37-1 is used in this study. Phosphorus Sulfur, 27(1-2), 127-32 (English) 1986. CODEN: PREEDF. ISSN: 0308-664X. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) The main chem. and enzymic methods of asym. oxidn. of sulfides were reviewed. Chiral sulfoxides were prepd. using Me3COOH in the presence of a chiral Ti complex. The best enantiomeric excess amounted to 95% in the prepn. of cyclopropyl Ph sulfoxide (I). Thus, to a chiral complex from Ti(OCHMe2)4, (R,R)-di-Et tartrate, and H2O in CH2Cl2 was added cyclopropyl Ph sulfide and Me3COOH to give 73% I. .
Asymmetric oxidation of sulfides to sulfoxides by organic hydroperoxides with optically active Schiff base-oxovanadium(IV) catalysts
Asymmetric oxidation of sulfides to sulfoxides by organic hydroperoxides with optically active Schiff base-oxovanadium(IV) catalysts. Nakajima, Kiyohiko; Kojima, Masaaki; Fujita, Junnosuke (Fac. Sci., Nagoya Univ., Nagoya 464, Japan). Chem. Lett., (9), 1483-6 (English) 1986.In this article, certain chemicals are used. One of their cas registry numbers is 7433-79-6 CODEN: CMLTAG. ISSN: 0366-7022. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) The asym. oxidn. of sulfides into the corresponding sulfoxides was achieved with org. hydroperoxides in the presence of a catalytic amt. of optically active Schiff base-oxovanadium(IV) complexes; in most cases the enantiomeric excess ranged between 20 and 40%. .
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